Category: Cleaning & Maintenance

All hort articles on sprayer cleaning and maintenance.

  • Biobeds for Pesticide Waste Disposal

    Biobeds for Pesticide Waste Disposal

    One of the most challenging aspects of a spray operation is the disposal of leftovers or rinsate containing pesticides. Let’s be honest, too much of it is drained onto the ground in a corner of the yard or the field. Nobody’s happy about that, nobody’s proud of it, but what are the alternatives?

    Waste disposal is a skeleton in the closet of the pesticide industry. One of the problems is the time-consuming nature of sprayer cleaning, and the lack of clear guidelines on product labels that pass the buck.  Too often, the applicator is asked to “act in accordance with provincial or state guidelines”, which is essentially a dead end.

    Figure 1: Sprayer fill station

    At Sprayers101.com, we’ve tried to tackle the problem by finding ways to generate less waste (Express End Caps, Accu-Volume), by disposing of the rinsate by spraying it out, or by installing an efficient continuous rinsing system. We’d now like to talk about another component, biobeds.

    What is a biobed?

    Simply put, a biobed is a place where it’s safe and acceptable to dump dilute pesticide waste. First implemented in Sweden about 20 years ago, a biobed typically consists of a 1-m deep pit measuring about 3 m x 6 m or so. The pit is filled with a biomix, a mixture of cereal straw, compost or peat, and soil. The biomix, when properly prepared, acts to absorb a large amount of moisture, adsorb the pesticide molecules, and provide an environment in which microbes break down the residues.

    Figure 2: Canada’s first commercial biobed installation at Indian Head, SK, 2009 (Source: Murray Belyk, Bayer CropScience (retired)).

    The effluent from a properly constructed biobed system contains 90 to 99% less pesticide than what was introduced, depending on the pesticide.

    Biobeds have been extensively studied and are now found throughout Europe and many parts of Central and South America. Canada currently has 6 research biobed sites in the West, and a further 17 in Quebec. The systems have been researched by Agriculture & Agri-Food Canada (AAFC) in recent years, with promising results.

    Figure 3: European biobed installations, 2016 (Source: Jens Husby, Biobeds.org).

    Figure 4: Global biobed installations, 2016 (Source: Jens Husby, Biobeds.org).

    Constructing a biobed

    There are many possible variations of biobeds, some relatively simple and others engineered to address certain specific needs. A great deal of creativity can be used to customize a biobed for any operation.

    A simple biobed

    The following is a variation of the simplest biobeds, and these are the types first tested by AAFC in Saskatoon and Indian Head, Saskatchewan about 10 years ago. This design is based on the biobeds established in Sweden and the UK, and is a good way to learn about the system.

    Note that this biobed has an impermeable liner, so it’s a closed system. Excess water that leaches to the bottom must be removed and cycled back to the top of the biobed.

    • Create the biomix by blending two parts, by volume, chopped cereal straw or wood chips (not cedar), one part mature plant-sourced compost or peat and one part relatively coarse-textured soil (for optimal drainage). Add water as necessary as if making compost. Allow to sit for four to six weeks.

    Figure 5: Biomix preparation.

    • During this waiting time, the biomix will warm and form a white-mold complex. This is the microbial basis for its ability to break down pesticide residues. White mold will be visible on the cellulose portions of the biomix.

    Figure 6: white mold (Source: AAFC).

    • Identify a well-drained site easily accessible by spray equipment. Avoid low spots as water management becomes problematic.

    Figure 7: Site selection and/or biobed covering are essential to avoid waterlogging (Source: Murray Belyk, Bayer CropScience (retired)).

    • Dig a pit sized to suit your requirements. As a rule of thumb, 1 m3 can process about 1000 L of liquid in a season. Rainfall is included in this amount.

    Figure 8: A nice looking pit.

    • Line the pit with a geomembrane liner. 40 mil is plenty thick; any thicker and it gets hard to handle. Include a raised berm at the edge.

    Figure 9: Liner creates a closed system that will require a way to remove leached water.

    • Install weeping tile at bottom of pit, and extend it to ground level. This will be useful to determine water status and remove water if necessary.

    Figure 10: Weeping tile to collect excess water.

    • Cover weeping tile with pea gravel and a silt trap. This serves to make leached water freely available for removal.

    Figure 11: Pea gravel over weeping tile.

    • Fill pit with biomix, anticipating significant settling. Top up as necessary over next few weeks. Use extra biomix to create a slope away from berm.

    Figure 12: Filled biobed.

    • Establish a bromegrass cover by transplanting or sodding. This is an important way to remove excess water via evapotranspiration.

    Figure 13: Early sod growth on biobed at Indian Head, SK.

    • Introduce pesticide waste to biobed, managing moisture content to avoid waterlogging.

    Figure 14:  Pesticide waste entering biobed via drip irrigation.

    Introduction of pesticide waste to the biobed

    Moving pesticide waste from the sprayer to the biobed should be easy and trouble free. A simple pad built beside biobeds, either sealed with concrete or asphalt, or with a hardy geomembrane liner, works well. The sprayer is cleaned on this pad and rinsate flows into a drain. A sump pump lifts the rinsate to a storage tank from which it is introduced via gravity or pumped drip irrigation.

    Figure 15: Biobed system in Simpson, SK. Rinsate from sprayer is collected in a sump, which is pumped to the black storage tank in background. Rinsate is introduced into biobed (blue tub) as needed (Brian Caldwell in foreground, left, Larry Braul, right).

    When not in use, the sump drains freely to dispose of rain water.

    Others choose to pump or dump rinsate directly into a holding tank, from where it can be pumped onto the biobed.

    Figure 16: Holding tank at biobed in Outlook, SK.

    Some European systems include driving supports on the biobed so the sprayer can be parked directly over top.

    Figure 17: Steel beams can allow (light) sprayer access (Source: Eskil Nilsson via Biobeds.org).

    A two-stage biobed

    The same basic building principles apply as in the original simple biobed. However, instead of reintroducing the effluent to the top of the biomix as it collects on the bottom, it is instead pumped onto a second biobed. This biobed then degrades any remaining product. This system is more efficient at degrading persistent products, and allows for better water management.

    Figure 18: Two-stage biobed system at Outlook, SK.

    The principle has proven effective, helping degrade more difficult pesticides to acceptable levels.

    Above-ground biobeds

    One of the problems with below-ground biobeds in wet climates is the difficulty managing water. Above-ground biobeds can address this issue by eliminating the possibility of surface runoff being added to the biomix. Adding a rain cover would also be easier and more effective.

    Above-ground biobeds can be edged with plywood, or placed entirely into plastic tanks whose tops have been removed.

    Figure 19: Above ground biobed installation with plastic tub.

    One potential problem with above-ground biobeds is the later spring warming of this installation compared to below-ground types. Cold temperature reduces the effectiveness of biobeds due to the reliance on microbial activity. Heat tape has been tested by AAFC and shown to be very effective at warming the biomix and stimulating initial microbial activity. Passive solar systems have also been studied but are more difficult to install.

    Figure 20: Heat tape (Source: AAFC).

    Figure 21: Passive solar biomix heating system.

    Phytobac and Biofilters

    European designs have utilized plastic containers to form of various designs, including the commercial “Phytobac” systems from France and developed with the support of Bayer CropScience.

    Sequential biofilters have also been implemented. The leachate simply migrates through the biomix into the next container below. Eventually, adjacent biofilters containing plants act to remove the moisture.

    Figure 22: Phytobac installation, cross-section.

    Figure 23: Biofilter installation in Belgium (Source: Inge Mestdagh via Biobeds.org).

    Biomix longevity

    Swedish and UK research has suggested that biobeds require minimal maintenance aside from water management in closed systems. Biomix will settle over time and may need to be topped up. After five to eight years of use, it has been recommended to remove biomix and distribute it over a field with a manure spreader.

    Canadian research results

    Extensive analysis of pesticide degradation in five biobeds across Western Canada was conducted as part of a three-year study led by AAFC. Between eight and 51 products were analyzed per site, including herbicides, fungicides, and insecticides. Their results showed that single biobeds could remove about 90% of the introduced pesticide, and two in sequence usually removed more than 98%.

    Pesticides that tended not to degrade rapidly were removed to a greater degree in the second biobed.

    In the AAFC studies, three herbicides were more difficult to remove in the tested biobeds: clopyralid (e.g., Lontrel, Stinger), bentazon (Basagran, Storm) and imazethapyr (Pursuit, Arsenal). For these three, roughly 60% was removed in a two-biobed system.

    Concentrated pesticides should not be introduced to a biobed as this will kill the microbial populations.

    Some fungicides were shown to depress microbial populations but only temporarily. Microbial breakdown still occurred.

    Biobed manual

    AAFC has authored a comprehensive manual on biobed operation and installation based on research experience in Canada and elsewhere. It will be available here in late June 2018.

    The future of biobeds

    Research into biobeds remains active around the world. Different substrates for the biomix are being studied to suit local availabilities. Various systems, ranging from simple to highly engineered are being studied. Degradation effectiveness for various influents remains a topic of significant interest. Producer adoption and implementation are being reported.

    Thanks to funded research projects, biobeds are up and working at Canadian institutional sites such as government research centres, and there are opportunities for county and municipal government sites. For biobeds to be a viable option on North American farms, their design needs to remain simple and their integration into established practices needs to be seamless. Producer experience and feedback are essential

    Learn more

    Valuable information on biobeds can be obtained from these two websites:

    Voluntary Initiative (UK industry)

    Biobeds.org (International research)

    Note: Brian Caldwell and I first learned about biobeds from Eskil Nilsson (website) during a visit to Sweden in 2001, and obtained support for initial studies in Saskatoon and Indian Head from the Pest Management Centre as well as Bayer CropScience. Brian took a lead in our creative and technical efforts over many years. Dean Ngombe, under the co-supervision of Diane Knight at the U of S and myself, produced the first M.Sc. thesis, and with significant input from Allan Cessna, the first scientific publications in Canada on biobeds. Thanks for Larry Braul and many collaborators for leading the most recent AAFC study and generously sharing resources, and Erl Svendsen, Bruce Gossen, and Claudia Sheedy for editorial input.

  • Diluting 20,000-Fold with a 30 Gallon Remaining Volume in a 1,200 Gallon Tank

    Diluting 20,000-Fold with a 30 Gallon Remaining Volume in a 1,200 Gallon Tank

    (This short article is an addendum to this article)

    Our goal in this example is to dilute by a factor of 20,000.

    The maximum amount of dilution possible with a 1,200 gallon tank and a 30 gallon remainder is 1200/30=40.

    The formulae:

    Dilution per Rinse = final dilution ^(1/# of rinses)

    Rinse Volume = (dilution per rinse * remaining volume) – remaining volume

    • One rinse diluting by 20,000 – impossible with a 1,200 gallon tank (max achievable is 40-fold);
    • Two sequential rinses, each diluting by a factor of 20,000^(1/2) = 141. Also impossible with a 1,200 gallon tank;
    • Three sequential rinses, each diluting by a factor of 20,000^(1/3) = 27. A volume of 780 gallons can do this  (27*30)-30=780 gallons. For three rinses, the total volume is 2,340 gallons.
    • Four sequential rinses, each diluting by a factor of 20,000^(1/4) = 12. A volume of 330 gallons can do this, for a total volume of 1,320 gallons;
    • Five sequential rinses, each diluting by a factor of 20,000^(1/5) = 7. A volume of 180 gallons can do this, for a total volume of 900 gallons;
    • Six sequential rinses, each diluting by a factor of 20,000^(1/6) = 5.2. A volume of 126 gallons can do this, for a total volume of 757 gallons.

    Second, let’s assume the operator is prepared to prime the boom where it doesn’t harm soybeans. Now the first new product tank takes care of the last dilution, lowering the cleanout dilution requirement by 1,200/30 = a factor of 40. Now the cleanout dilution requirement is only 20,000/40 = 500.

    • One 1,200 gallon tank rinse can only achieve 40-fold dilution.
    • Two rinses, each diluting by 500^(1/2) = 22. Rinse volumes of 640 gallons are sufficient, for a total of 1,280 gallons.
    • Three sequential rinses, each diluting by a factor of 500^(1/3) = 7.9. A volume of 210 gallons can do this, for a total volume of 630 gallons;
    • Four sequential rinses, each diluting by a factor of 500^(1/4) = 4.7. A volume of 112 gallons can do this, for a total volume of 448 gallons.
  • How Clean is Clean?

    How Clean is Clean?

    One of the more perplexing questions in tank cleanout is knowing when the cleaning process is good enough to prevent harm. This question is especially relevant to producers that grow canola and use Group 2 herbicide products, or grow soybeans and use dicamba on some of their area. In both of these examples, crops can be extremely sensitive to very small residues.

    When does an applicator know that the cleaning job was good enough? In about two weeks! There is no easy way to tell, except to be precautionary.

    A bit of math can help put us in the ballpark. First, we need to know the tolerance of a crop to the herbicide, preferably expressed as a proportion of the tank mix to be cleaned. Let’s use dicamba as an example. It’s been reported that non-dicamba tolerant soybeans can show leaf-cupping symptoms from dicamba at rates as low as 1/20,000 of the label rate.

    Recall that sprayer cleanout is really two separate processes that we’ve written about here, here, and here. The first is dilution of the remaining volume in the system. The second is decontaminating specific sprayer components (filters, boom ends, hoses). We’ll focus on dilution in this article.

    If you’re diluting, the second piece of information you need is how much liquid is left in the sprayer when you start cleaning. All sprayers have a certain amount of liquid left in the tank and associated plumbing after the tank is empty. The sump, the suction line feeding the pump, and the lines returning to the tank via agitation or sparge are most common. Even when the pump no longer draws liquid, those lines retain some volume of product. This volume can’t be pushed out to the boom, most of it goes back to the tank.

    The volume of this “remaining liquid” is likely somewhere between three and thirty US gallons.

    The remainder volume depends on the sprayer, and also how the tank is emptied. Some applicators simply spray until the solution pump pressure drops, others choose to drain the remaining liquid from a sump valve. When draining, product should be captured in pails rather than allowing it on the ground where it will harm the soil and possibly make its way into runoff.

    It’s always preferable to spray the tank empty in a field.

    As we’ll see below, a low remaining volume greatly improves the efficiency of the dilution process. It’s a sprayer feature that should be considered at purchase.

    The table below has some sample calculations. Note that the paired cases (1&2, 3&4, 6&7) all use the same total water volume, but compare a single vs triple rinse of three different remaining volumes.

    Comparing Case 1 to Case 3 or Case 6, (remaining volumes of 10, 20, and 50, respectively), it’s clear that minimizing the remaining volume is important.

    It’s also striking that the same amount of clean water, subdivided into three smaller repeat batches (Case 2, 4 and 7), is much more powerful than using single batches with the same total clean water amounts.

    Reducing the size of each batch even further and increasing the number of batches (Case 5) approaches what a properly executed continuous rinse can do.

    Is it necessary to dilute to the level that’s safe for the next crop? Not always. The next product in the tank acts to dilute the remainder once again, possibly by a factor of 100, depending on the remaining volume and the tank size (Case 8). The material in the boom, however, won’t be diluted by this additional volume, and therefore may harm the crop unless it is first sprayed out elsewhere, especially when section ends are not drained and rinsed.

    This is where a recirculating boom is valuable, providing an opportunity to charge the boom without spraying. The penalty is that the boom volume is then returned to the tank in the process, increasing the amount that needs to be diluted.

    Let’s return to the dicamba example with a 20,000-fold dilution requirement and a 1,200 gallon tank. We’ll consider two examples. In the first, the operator wants to prime the boom in the soybean field without any harm to the dicamba-susceptible beans. A 20,000-fold dilution is needed.

    We’ve looked at five options that each assume a remaining volume of 10 gallons. Note that our goal is the same – dilute by a factor of 20,000.

    The formulae:

    Dilution per Rinse = final dilution ^(1/# of rinses)

    Rinse Volume = (dilution per rinse * remaining volume) – remaining volume

    The maximum amount of dilution possible with a 1,200 gallon tank and a 10 gallon remainder is 120 (see Row 8, Table above).

    • One rinse diluting by 20,000 – impossible with a 1,200 gallon tank (max achievable is 120-fold);
    • Two sequential rinses each diluting by a factor of 20,000^(1/2) = 141. Also impossible with a 1,200 gallon tank;
    • Three sequential rinses, each diluting by a factor of 20,000^(1/3) = 27. A volume of 260 gallons can do this  (27*10)-10=260 gallons. For three rinses, the total volume is 780 gallons.
    • Four sequential rinses, each diluting by a factor of 20,000^(1/4) = 12. A volume of 110 gallons can do this, for a total volume of 440 gallons;
    • Five sequential rinses, each diluting by a factor of 20,000^(1/5) = 7. A volume of 60 gallons can do this, for a total volume of 300 gallons.

    The first two examples don’t work because the tank isn’t big enough. But the three remaining examples all work equally well, they just consume different amounts of clean water.

    If that doesn’t seem like a lot of work, then repeat this calculation with a 30 gallon remainder volume, common on many sprayers. Short on time? We did it for you here.

    Second, let’s assume the operator is prepared to prime the boom where it doesn’t harm soybeans. Now the first new product tank takes care of the last dilution, lowering the cleanout dilution requirement by 1,200/10 = a factor of 120. Now the cleanout dilution requirement is only 20,000/120 = 166.

    • One 1,200 gallon tank rinse can only achieve 120-fold dilution.
    • Two rinses, each diluting by 166^(1/2) = 13. Rinse volumes of 120 gallons are sufficient, for a total of 240 gallons.
    • Three sequential rinses, each diluting by a factor of 166^(1/3) = 6. A volume of 50 gallons can do this, for a total volume of 150 gallons.

    The math is simple, and can be done using the formula in the first table, or this app:

    The hard part is knowing what the remaining volume is. It would be very useful for a manufacturer to provide this information.

    In the meantime, you can estimate on your own. Add water with surfactant to your tank, and spray it empty. While spraying, turn the agitation on and off to fill and activate the sparge, if equipped. Once the tank is empty and the spray pressure drops, stop and drain the sump into pails. Ensure that the pump suction line and the pressure line up to and including the agitation and sparge lines also drain. Disconnect these if necessary. If there is a filter housing in this circuit, remove it as well.  Avoid collecting liquid from the pressure line beyond where the the agitation or sparge split off, as this will be pushed out to the boom.

    An alternative is to estimate the length of hose in this circuit, using the following table as a guide:

    And remember, diluting the remaining liquid is only one part of a cleaning process.

  • Plumbing Projects That Make Spraying Easier and Safer

    Plumbing Projects That Make Spraying Easier and Safer

    Some of our biggest struggles in spraying involve the start and end of each spray day.

    When starting a new field after the sprayer is cleaned, we need to prime the boom. If it’s full of water, that water has to be purged and the question is always for how long and where to do this (pro tip at bottom of article).

    At the end of the day, we should ideally clean the sprayer. During that process, we may struggle with waste disposal, including large rinsate amounts, and course, the uncertainty of whether the job is actually done (since clean water looks exactly the same as contaminated water).

    If not cleaning the entire sprayer plumbing, we should at least rinse the boom, even if we’re returning to the same product the following day. It can prevent future problems.

    These tasks are complicated by the increasingly convoluted plumbing featured on modern sprayers. Ask someone to explain their sprayer’s plumbing system to you one day. It’s a long story! A bright spot is the well-engineered, compact, and accessible Agrifac system.

    Fortunately, virtually any sprayer can be modified to suit your needs. Let’s talk about a few ideas for a winter project:

    1. Boom flush. It’s good practice to flush clean water through your boom at the end of spraying even if the main tank remains full of product. Some sprayers have an air purge system to eliminate liquid from the plumbing and that is a great feature. A water flush should follow that purge so that any residual pesticide is diluted and removed before it can dry on and become hard to remove later.  First you’ll need a clean water tank on the sprayer (150 gal is enough). Second, plumb a feed so that this clean tank can be the sole source of the water supplied to the solution pump. Select this source, shut return lines down or off, and pump clean water through boom.  Sprayers that have an auto-rinse cycle will likely be able to draw clean water, but may not be able to push it to the boom, directing it to the wash-down nozzles instead. Check to see what’s possible, and make the changes you need.
    2. Clean water pump. Installing a second pump dedicated to the clean water tank has several advantages. We’ve talked about continuous rinsing before, here, and here, as a way to dilute the tank remainder faster. It requires installation of a second pump dedicated to clean water. Additionally, give this pump the option to deliver water to the boom, not just the wash-down nozzles. Now it can be used to rinse water through the boom. The main challenge is to obtain a pump capacity that can match the needs of the boom and/or the wash-down nozzles.
    3. Boom ends. We’ve mentioned this part of the boom many times. Boom ends must be flushed regularly to get rid of product and possibly debris that gets stuck there. A simple way to achieve this is to use the Express Nozzle Body End Caps from Hypro. These bleed air continuously, and also prevent accumulation of dead-end contamination. They do need to be flushed, and this can be done by pulling a plug or rotating the turret to an open (no nozzle ) position.
    1. Recirculating boom. This is a significant change, but worth considering. Conventional plumbed booms are separated into five to 13 sections. Each has two ends at which the spray stops and where air and contamination can accumulate (see point #3). Each section feed has a shutoff valve.  Once the spray mixture leaves the pump and bypass valve, it is committed to leaving the sprayer.  In a recirculating boom, the boom becomes a part of the tank and the liquid can return to the tank if desired. Spray is pressurized at one or both ends, and valve positions determine its flow. Sectional control is achieved with individual nozzle shutoff, air or electric.
      1. Three advantages:
        (a) the boom can be primed with new product without spraying. The surplus goes back to the tank.
        (b) the boom can be flushed with water without spraying while material is still in tank, and without spilling anything on the ground. Again, the surplus goes back to the tank.
        (c)  high resolution sectional control with individual nozzle shutoff is a byproduct of this design. Fast response, high res, saves money.
    2. Steel lines. Steel cleans easier than plastic, and this material makes a lot of sense for booms. But it also makes sense for the boom feeds, currently handled by black rubber hose.  This hose is a literal black box. We can’t see inside it, and we don’t know if and where potential contamination resides. It has considerable surface area. Consider replacing portions of your feed lines with steel. The boom is the obvious candidate. Aside from easier cleanout, it also helps with faster nozzle shutoff because it doesn’t expand with pressure.

    A word about dumping the tank on the ground. It’s a bad practice for many reasons. Let’s examine just one of those. When you spray a product at 10 gpa, you actually cover each square meter with about 10 mL, or 1/3 oz, of spray mix. When you flush your boom ends on the ground, you’re probably dropping 2 or 3 gallons in the same area. That’s 1000 times the label rate at each boom end, 10 to 26 times per boom. If you dump your tank remainder and all the hoses, say 20 or 30 gallons, that’s 10,000 times the label rate if it covers 1 sq meter. That’s leaching, runoff, residual potential, and not a good story.

    Many of the changes we outlined above help prevent that from being necessary.

    Pro Tip: To find out how much water your plumbing (from the pump to the boom ends) holds, do this: After cleaning with water and before spraying an EC formulation (white milky appearance in tank, some crop oils are ECs) reset your sprayed gallons on your rate controller. Start spraying and watch for the last nozzle on your furthest and longest section to spray white. Stop spraying and check your sprayed gallons. That’s your volume. No matter the size of nozzle or application volume, it stays constant. To be sure the boom is primed with a new mix, spray until those gallons are reached and you’re set.

  • Storing Pesticide Mix Overnight

    Storing Pesticide Mix Overnight

    Not being able to finish a tank due to weather or any other reason happens to just about everyone. Is it OK to simply leave the sprayer as is, and resume spraying later after some agitation?

    In many cases, the answer is yes. Most pesticide mixtures are stable in short term storage. On resuming spraying, an agitation could be all that’s needed to get back to where you started a day or so earlier.

    But there are three important exceptions.

    When the active ingredient is formulated as a suspension. Suspensions are typically wettable powders and flowables, and rely on a clay carrier to distribute the active in the tank. Because clay is denser than water, these formulations settle out quickly after agitation stops. Sure, they can be brought back into suspension with vigorous agitation. But in lines and booms, boom ends and screens, dislodging a settled clay carrier is much more difficult. It’s also hard to tell if the cleaning has been successful because the problem spots are hidden.

    The best solution is to flush the spray boom with water before materials can settle and lodge. A visual inspection where access is possible, such as strainer bowls and boom ends, is part of the process to ensure the formulated product has been removed.

    Learn to identify which formulations are suspensions. There’s lots of jargon out there. Look for terms such as DC, DF, DG, DS, F, Gr, SP. Even EC formulations are suspensions (oil in water) and require agitation.

    When the active ingredient is chemically unstable. Some pesticides can degrade in the tank, usually due to alkaline (high pH) hydrolysis. The effect is very pesticide specific, but in general, insecticides (particularly organophosphates and carbamates) are more susceptible than other pesticides. This fact sheet by Michigan State University describes the impact of pH on a the half-life of a large number of pesticides.

    Note that in the examples in the MSU fact sheets, pesticide half lives are typically days and weeks, and only rarely hours. Also note that while high pH is most often problematic, low pH can lead to faster breakdown in a small number of products.

    Ensuring tank mix stability requires a pH meter or paper, and possibly a pH modifier such as citric acid. But do your research first! Here’s an article on pH and water quality.

    When the tank previously contained a product known to harm the current crop. This situation is most common and most difficult to address. Some examples from western Canada are Group 2 modes of action sprayed prior to a canola crop. Why are Group 2 products implicated?  Many are formulated as dry products on a clay base, and these can settle in boom ends, adhere to tank walls, or get stuck on screens. Their solubility is pH dependent, as we explain in this article.

    Canola is particularly sensitive to this mode of action, and the most common canola herbicides, Liberty and glyphosate, are formulated with strong detergents that act as tank cleaners.

    Even when applicators think that their tank is clean, they can’t actually be sure and can’t do much about it at that stage. The stripping of tiny amounts of residue off the tank walls, filter screens, or plumbing, can happen during a mid-day stop or an overnight break.  Applicators eventually find out that this happened, usually about two weeks after spraying.

    Our advice is:

    After spraying a herbicide to which a subsequent crop may be sensitive, with the classic case being a Group 2 and moving to canola, be extra diligent with cleaning and pay attention to the tank walls, all screens, and boom ends.

    The best way to solve issues is to avoid them in the first place. If the weather looks unsettled and may interrupt your spray operation, consider mixing smaller batches that can be sprayed out completely even if conditions change quickly. This allows you to rinse the tank and spray water through the boom, thus avoiding a contamination problem developing overnight.

    If that’s not possible, at least do not let a tank mix sit in the boom overnight. Instead, use your clean water tank to push water through the boom prior to storage and double check the screens. The following day, prime the boom with your tank mix as usual and resume spraying the crop.

    If you’re not sure that your sprayer can draw from the clean water tank and push through the booms (the wash-down nozzles are, after all, the intended destination for that water), decipher your system and add the necessary valves that make this possible.

    A useful design that helps flush and prime a boom quickly is the recirculating boom offered by some aftermarket boom manufacturers. These booms are also more common on European sprayers. A nice feature of such designs is that the tank contents can be pumped through the entire boom assembly without actually spraying. This ensures that the boom is primed without any soil contamination. It also dilutes whatever residue there may be in the boom plumbing with the entire tank, likely reducing its concentration enough to be of little concern.

    An additional feature of recirculating booms is that many offer stainless steel tubing throughout most of their feed and return length, minimizing the black rubber hose products that often adsorb, and later release, herbicide contamination.

    Even if a wholesale boom or sprayer change is impractical, consider switching to steel boom lines and tanks tank to minimize residue carryover.

    As is often the case in the spraying business, prevention is easier and less costly than solving a big problem later. Spray mix storage is one of those examples where a small amount of extra effort at the beginning can pay big dividends later.