Category: Cleaning & Maintenance

Articles about removing pesticide residue and disposing of rinsate from horizontal boom sprayers

  • Testing the Effectiveness of Sprayer Rinsing Methods using Dicamba

    Testing the Effectiveness of Sprayer Rinsing Methods using Dicamba

    This work was performed with Mike Cowbrough, Weed Management Specialist (Field Crops) with OMAFA.

    The unprecedented number of dicamba drift complaints in the United States has proven to be a polarizing issue in the agriculture community. The debate continues as to the relative influence of contributing factors.

    The sensitivity of soybeans to trace amounts of dicamba has been known for more than 50 years (Wax et al. 1969). Research has shown that less than 0.2% of the highest recommended use rate can cause a 10% yield loss in non dicamba-tolerant soybean (Robinson et al., 2013). Many horticulture and ornamental crops are equally sensitive to low doses of dicamba.

    Relative volumes of Callisto (33% field rate), Roundup (6% field rate) and Xtend (0.16% field rate) known to cause 10% yield loss in conventional soybean.

    The inherent volatility of the active, and its subsequent potential for off-target movement, is also well known. Research has shown that XtendiMax, Engenia and FeXapan are far less volatile than their predecessors. However, research has also shown that there is some degree of volatilization for 36 hours following application, peaking 6-12 hours after treatment (Mueler, 2017). Studies by Jacobson et al. (2014) showed dicamba present in the air 60-72 hours after treatment.

    While sensitivity and volatility are suspected of being the primary culprits, there are other factors that contributed to the estimated 3.6 million acres of soybean reported damaged in the United States in 2017 (Bradley, 2017):

    • inappropriate sprayer set-up,
    • physical drift,
    • the use of older dicamba chemistries, and
    • contamination of filling or spray equipment (aka carry-over)

    The Experiment

    In 2017, we decided to learn more about sprayer contamination. The following is a summary of the labelled cleaning protocol. It’s noted that rinsate disposal must comply with local regulations:

    1. Drain sprayer immediately after use.
    2. Flush all inner surfaces with water.
    3. Fill sprayer with an ammonia-based solution and soak overnight.
    4. Concurrently, remove and soak strainers, screens and nozzles.
    5. Circulate solution for 15 minutes and flush through the boom for one minute.
    6. Drain sprayer, replace strainers, screens and nozzles, and flush once more with water.

    This thorough protocol is not unique to dicamba, and historically has not been followed by sprayer operators. Instead, operators choose cleaning methods that reflect the risk of damage and the time and effort required to clean the sprayer. The majority flush with water, may or may not perform serial rinses and may or may not address dead end plumbing. Where possible, operators schedule sprays that present the least potential for carry-over damage (e.g. moving into corn following soybean). There is no way to know for certain that the sprayer is sufficiently cleaned.

    Sprayer

    Our research sprayer had a tank capacity of 60 L and was calibrated to deliver a spray volume of 15 gallons per acre. RoundUp Xtend was added at the highest labeled rate of 2 L/acre (consisting of glyphosate at 1,200 gae/ha and dicamba at 600 gae/ha). We reserved the solution for reuse by collecting spray in jugs.

    Rinses

    Serial rinse

    On a typical sprayer, the capacity of the clean water tank is ~10% that of the product tank. To perform a triple rinse, the operator introduces 1/3 of that volume to the product tank through a washdown nozzle, circulates for 10 minutes, and then sprays the product tank empty. This is repeated two more times to empty the clean water tank.

    Our intent was to scale the process in the same ratio using the research sprayer. That would mean using a 6 L volume of clean water to represent 10% of the 60 L product tank. It follows that we would have to perform three, 2 L rinses.

    However, that was insufficient volume to engage the pump and still provide enough rinsate to spray in our trials. We calculated the minimum required volume to be 8 L per rinse. We circulated for 5 minutes through a washdown nozzle. Following our third rinse, we noted that the rinsate still smelled of dicamba, and elected to run a fourth 8 L rinse. Rinsate was collected from multiple nozzles spaced evenly along the boom.

    We then opened the suction filter and the two line filters and poured the remaining solution into a bucket. We topped the volume up to 8 L with clean water and scrubbed the filters with a brush.

    Continuous rinse

    The continuous rinse process continually introduces clean water via the washdown nozzle via a dedicated pump. Concurrently, the product pump sprays from the nozzles and circulates via the agitation/bypass line. We used 32 L of clean water (a volume equivalent to that used in the serial rinse) and collected rinsate in four, 8 L volumes.

    Rinsate was collected from multiple nozzles spaced evenly along the boom. We then opened the suction filter and the two line filters and poured the remaining solution into a bucket. We topped the volume up to 8 L with clean water and scrubbed the filters with a brush.

    Continuous rinse using 1% ammonia solution

    We followed the continuous rinse process, as previously described, in order to collect the filter residue.

    Possible artifacts

    The limitations involved in scaling down introduce two potential artifacts to this experiment. First, the ratio of clean water to product volume is high compared to typical practices for both rinses. We estimate the volume remaining in the sprayer when “empty” did not exceed 4 L.

    Second, continuous rinsing was sampled in batches, which means the fourth and final volume collected represents an average of the active remaining in the system rather than the final concentration. As such, it would likely be more concentrated than what truly remained in the sprayer.

    Application

    Rinsate was applied to glyphosate tolerant soybean on 30” rows. Rinsate was applied at 20 gpa using a handboom with AIXR 11002 nozzles. Ontario locations were Ridgetown, Elora, Winchester and Woodstock.

    Results

    Crop Injury

    Regardless of rinse procedure, crop injury was greatest after the first rinse cycle and diminished after each subsequent cycle (Table 1). The first half of the continuous rinse procedure caused greater injury than the serial rinse, but injury was equivalent for the final half. Crop injury was less when rinsate was applied to soybeans at an early vegetative stage (V2) compared to when rinsate was applied to soybeans at later vegetative stages (V5-V6) or the early reproductive stage (R1).

    Table 1: Visual Injury (%) of soybean 14 days after the application of rinsate that was collected from two different sprayer cleanout procedures.

    TreatmentEloraRidgetownWinchesterWoodstock
    % Visual Injury at 14 days after application
    Crop stage at applicationV5V2V6R1
    Weed-Free Control0000
    RU Xtend100100100100
    Serial Rinse # 110075100100
    Continuous Rinse # 1 (25% water)10095100100
    Serial Rinse # 275659090
    Continuous Rinse # 2 (50% water)85709595
    Serial Rinse # 355506075
    Continuous Rinse  # 3 (75% water)55506075
    Serial Rinse # 425102535
    Continuous Rinse # 4 (100% water)25102535
    Filters – Serial Rinse15301025
    Filters – Continuous Rinse15301025
    Filters – Continuous with 1% ammonia25452035

    We were surprised to observe dicamba injury even in the final stages of both rinse procedures. This reinforces how sensitive soybeans are to low doses of dicamba and demonstrates the importance of following the labelled water – ammonia – water sequence.

    When comparing damage from filter residue (following a continuous rinse) the rinsate extracted using a 1% ammonia solution was more injurious than rinsate from plain water. Cundiff et al. (2017) found no difference between the use of water or water-and-ammonia when cleaning out a sprayer. We speculate that the ammonia was more effective at removing dicamba from the sprayer, or it increased the residue’s potency.

    Soybean yield

    Yield losses appeared to mirror visual injury; as dicamba injury decreased, so did soybean yield loss. Yield losses were observed following application of all rinsate treatments, which is understandable given that dicamba injury also occurred following the application of all rinsate treatments.

    Yield losses were greater in the first half of the continuous rinse protocol, but were par with the serial rinse for the second half (Table 2). Yield losses were observed following the application of rinsate collected from filters, demonstrating the importance of following a thorough sprayer decontamination that addresses dead-end plumbing, filters and nozzles.

    Table 2: Yield (% of weed-free control) of soybean following the application of rinsate that was collected from two different sprayer cleanout procedures.

    TreatmentEloraRidgetownWinchesterAverage
    Yield (% of weed-free control)
    Crop Stage at applicationV5V2V6V2-V6
    Weed-Free Control100100100100
    RU Xtend0000
    Serial Rinse # 1044115
    Continuous Rinse # 1 (25% water)01304
    Serial Rinse # 233651036
    Continuous Rinse # 2 (50% water)2261328
    Serial Rinse # 374896676
    Continuous Rinse  # 3 (75% water)72895776
    Serial Rinse # 486968689
    Continuous Rinse # 4 (100% water)86978289
    Filters – Serial Rinse939610096
    Filters – Continuous Rinse87979593
    Filters – Continuous with 1% ammonia79859285

    Other observations

    1- Dicamba injury delayed soybean maturity and date of harvest by over 14 days at the Elora site. Delayed maturity was observed at the Winchester locations as well.

    2- Heavy rainfall shortly after the application of rinsate at the Winchester location caused water ponding. Since dicamba is very water soluble, crop injury and yield loss was higher in areas in the trial where water ponded after application.

    3- Dicamba injury appeared to accentuate other stress symptoms at the Elora site, specifically potash deficiency. In the absence of dicamba injury, soybean plants did not exhibit potash deficiency symptoms.

    Take Home

    • Continuous rinsing was as effective as four low-volume rinses.
    • Plots sprayed with the cleanest water rinsate (both protocols) averaged 11% lower yields than unsprayed plots.
    • Filter rinsate (following continuous rinse with water) resulted in an average 7% yield loss.
    • Filter rinsate (following continuous rinse with 1% ammonia) resulted in an average 15% yield loss.

    Citations

    • Bradley, K. 2017. “A Final Report on Dicamba-injured Soybean Acres”. University of Missouri Integrated Pest Management online. https://ipm.missouri.edu/IPCM/2017/10/final_report_dicamba_injured_soybean/
    • Cundiff, G.T., Reynolds, D.B. and T.C. Mueller. 2017. Evaluation of dicamba persistence among various agricultural hose types and cleanout procedures using soybean (Glycine max) as a bio-indicator. Weed Science. 65(2), pp. 305-316.
    • Jacobson, B., Urbanczyk-Wochniak, E., Mueth., M.G., Riter, L.S., Sall, J.H., South, S. and Carver, L. 2014. “Field Volatility of Dicamba Formulation MON 119096 Following a Post-Emerge Applciation Under Field Conditions in Texas”. Monsanto Report Number MSL0027193.
    • Mueller, T. 2017. “Effect of adding Roundup PowerMax to Engenia on vapor losses under field conditions” (Presentation).
    • Robinson, A.P., Simpson, D.M. and W.G. Johnson. 2013. Response of glyphosate-tolerant soybean yield components to dicamba. Weed Science. 61(4), pp. 526-536.
    • Wax, L.M., Knuth L.A., and Slife F.W. 1969. Response of soybean to 2,4-D, dicamba, and picloram. Weed Sci 17, pp. 388-393.
  • Plumbing Projects That Make Spraying Easier and Safer

    Plumbing Projects That Make Spraying Easier and Safer

    Some of our biggest struggles in spraying involve the start and end of each spray day.

    When starting a new field after the sprayer is cleaned, we need to prime the boom. If it’s full of water, that water has to be purged and the question is always for how long and where to do this (pro tip at bottom of article).

    At the end of the day, we should ideally clean the sprayer. During that process, we may struggle with waste disposal, including large rinsate amounts, and course, the uncertainty of whether the job is actually done (since clean water looks exactly the same as contaminated water).

    If not cleaning the entire sprayer plumbing, we should at least rinse the boom, even if we’re returning to the same product the following day. It can prevent future problems.

    These tasks are complicated by the increasingly convoluted plumbing featured on modern sprayers. Ask someone to explain their sprayer’s plumbing system to you one day. It’s a long story! A bright spot is the well-engineered, compact, and accessible Agrifac system.

    Fortunately, virtually any sprayer can be modified to suit your needs. Let’s talk about a few ideas for a winter project:

    1. Boom flush. It’s good practice to flush clean water through your boom at the end of spraying even if the main tank remains full of product. Some sprayers have an air purge system to eliminate liquid from the plumbing and that is a great feature. A water flush should follow that purge so that any residual pesticide is diluted and removed before it can dry on and become hard to remove later.  First you’ll need a clean water tank on the sprayer (150 gal is enough). Second, plumb a feed so that this clean tank can be the sole source of the water supplied to the solution pump. Select this source, shut return lines down or off, and pump clean water through boom.  Sprayers that have an auto-rinse cycle will likely be able to draw clean water, but may not be able to push it to the boom, directing it to the wash-down nozzles instead. Check to see what’s possible, and make the changes you need.
    2. Clean water pump. Installing a second pump dedicated to the clean water tank has several advantages. We’ve talked about continuous rinsing before, here, and here, as a way to dilute the tank remainder faster. It requires installation of a second pump dedicated to clean water. Additionally, give this pump the option to deliver water to the boom, not just the wash-down nozzles. Now it can be used to rinse water through the boom. The main challenge is to obtain a pump capacity that can match the needs of the boom and/or the wash-down nozzles.
    3. Boom ends. We’ve mentioned this part of the boom many times. Boom ends must be flushed regularly to get rid of product and possibly debris that gets stuck there. A simple way to achieve this is to use the Express Nozzle Body End Caps from Hypro. These bleed air continuously, and also prevent accumulation of dead-end contamination. They do need to be flushed, and this can be done by pulling a plug or rotating the turret to an open (no nozzle ) position.
    1. Recirculating boom. This is a significant change, but worth considering. Conventional plumbed booms are separated into five to 13 sections. Each has two ends at which the spray stops and where air and contamination can accumulate (see point #3). Each section feed has a shutoff valve.  Once the spray mixture leaves the pump and bypass valve, it is committed to leaving the sprayer.  In a recirculating boom, the boom becomes a part of the tank and the liquid can return to the tank if desired. Spray is pressurized at one or both ends, and valve positions determine its flow. Sectional control is achieved with individual nozzle shutoff, air or electric.
      1. Three advantages:
        (a) the boom can be primed with new product without spraying. The surplus goes back to the tank.
        (b) the boom can be flushed with water without spraying while material is still in tank, and without spilling anything on the ground. Again, the surplus goes back to the tank.
        (c)  high resolution sectional control with individual nozzle shutoff is a byproduct of this design. Fast response, high res, saves money.
    2. Steel lines. Steel cleans easier than plastic, and this material makes a lot of sense for booms. But it also makes sense for the boom feeds, currently handled by black rubber hose.  This hose is a literal black box. We can’t see inside it, and we don’t know if and where potential contamination resides. It has considerable surface area. Consider replacing portions of your feed lines with steel. The boom is the obvious candidate. Aside from easier cleanout, it also helps with faster nozzle shutoff because it doesn’t expand with pressure.

    A word about dumping the tank on the ground. It’s a bad practice for many reasons. Let’s examine just one of those. When you spray a product at 10 gpa, you actually cover each square meter with about 10 mL, or 1/3 oz, of spray mix. When you flush your boom ends on the ground, you’re probably dropping 2 or 3 gallons in the same area. That’s 1000 times the label rate at each boom end, 10 to 26 times per boom. If you dump your tank remainder and all the hoses, say 20 or 30 gallons, that’s 10,000 times the label rate if it covers 1 sq meter. That’s leaching, runoff, residual potential, and not a good story.

    Many of the changes we outlined above help prevent that from being necessary.

    Pro Tip: To find out how much water your plumbing (from the pump to the boom ends) holds, do this: After cleaning with water and before spraying an EC formulation (white milky appearance in tank, some crop oils are ECs) reset your sprayed gallons on your rate controller. Start spraying and watch for the last nozzle on your furthest and longest section to spray white. Stop spraying and check your sprayed gallons. That’s your volume. No matter the size of nozzle or application volume, it stays constant. To be sure the boom is primed with a new mix, spray until those gallons are reached and you’re set.

  • Storing Pesticide Mix Overnight

    Storing Pesticide Mix Overnight

    Not being able to finish a tank due to weather or any other reason happens to just about everyone. Is it OK to simply leave the sprayer as is, and resume spraying later after some agitation?

    In many cases, the answer is yes. Most pesticide mixtures are stable in short term storage. On resuming spraying, an agitation could be all that’s needed to get back to where you started a day or so earlier.

    But there are three important exceptions.

    When the active ingredient is formulated as a suspension. Suspensions are typically wettable powders and flowables, and rely on a clay carrier to distribute the active in the tank. Because clay is denser than water, these formulations settle out quickly after agitation stops. Sure, they can be brought back into suspension with vigorous agitation. But in lines and booms, boom ends and screens, dislodging a settled clay carrier is much more difficult. It’s also hard to tell if the cleaning has been successful because the problem spots are hidden.

    The best solution is to flush the spray boom with water before materials can settle and lodge. A visual inspection where access is possible, such as strainer bowls and boom ends, is part of the process to ensure the formulated product has been removed.

    Learn to identify which formulations are suspensions. There’s lots of jargon out there. Look for terms such as DC, DF, DG, DS, F, Gr, SP. Even EC formulations are suspensions (oil in water) and require agitation.

    When the active ingredient is chemically unstable. Some pesticides can degrade in the tank, usually due to alkaline (high pH) hydrolysis. The effect is very pesticide specific, but in general, insecticides (particularly organophosphates and carbamates) are more susceptible than other pesticides. This fact sheet by Michigan State University describes the impact of pH on a the half-life of a large number of pesticides.

    Note that in the examples in the MSU fact sheets, pesticide half lives are typically days and weeks, and only rarely hours. Also note that while high pH is most often problematic, low pH can lead to faster breakdown in a small number of products.

    Ensuring tank mix stability requires a pH meter or paper, and possibly a pH modifier such as citric acid. But do your research first! Here’s an article on pH and water quality.

    When the tank previously contained a product known to harm the current crop. This situation is most common and most difficult to address. Some examples from western Canada are Group 2 modes of action sprayed prior to a canola crop. Why are Group 2 products implicated?  Many are formulated as dry products on a clay base, and these can settle in boom ends, adhere to tank walls, or get stuck on screens. Their solubility is pH dependent, as we explain in this article.

    Canola is particularly sensitive to this mode of action, and the most common canola herbicides, Liberty and glyphosate, are formulated with strong detergents that act as tank cleaners.

    Even when applicators think that their tank is clean, they can’t actually be sure and can’t do much about it at that stage. The stripping of tiny amounts of residue off the tank walls, filter screens, or plumbing, can happen during a mid-day stop or an overnight break.  Applicators eventually find out that this happened, usually about two weeks after spraying.

    Our advice is:

    After spraying a herbicide to which a subsequent crop may be sensitive, with the classic case being a Group 2 and moving to canola, be extra diligent with cleaning and pay attention to the tank walls, all screens, and boom ends.

    The best way to solve issues is to avoid them in the first place. If the weather looks unsettled and may interrupt your spray operation, consider mixing smaller batches that can be sprayed out completely even if conditions change quickly. This allows you to rinse the tank and spray water through the boom, thus avoiding a contamination problem developing overnight.

    If that’s not possible, at least do not let a tank mix sit in the boom overnight. Instead, use your clean water tank to push water through the boom prior to storage and double check the screens. The following day, prime the boom with your tank mix as usual and resume spraying the crop.

    If you’re not sure that your sprayer can draw from the clean water tank and push through the booms (the wash-down nozzles are, after all, the intended destination for that water), decipher your system and add the necessary valves that make this possible.

    A useful design that helps flush and prime a boom quickly is the recirculating boom offered by some aftermarket boom manufacturers. These booms are also more common on European sprayers. A nice feature of such designs is that the tank contents can be pumped through the entire boom assembly without actually spraying. This ensures that the boom is primed without any soil contamination. It also dilutes whatever residue there may be in the boom plumbing with the entire tank, likely reducing its concentration enough to be of little concern.

    An additional feature of recirculating booms is that many offer stainless steel tubing throughout most of their feed and return length, minimizing the black rubber hose products that often adsorb, and later release, herbicide contamination.

    Even if a wholesale boom or sprayer change is impractical, consider switching to steel boom lines and tanks tank to minimize residue carryover.

    As is often the case in the spraying business, prevention is easier and less costly than solving a big problem later. Spray mix storage is one of those examples where a small amount of extra effort at the beginning can pay big dividends later.

  • Three Features that Should be Standard on all Sprayers

    Three Features that Should be Standard on all Sprayers

    One of my main activities in the winter is public speaking. Attending producer meetings gives me the privilege of meeting many farmers, learning about their operations, and sharing my research results.

    I enjoy providing practical solutions to problems. But there are three issues that always come up to which I wish I had better answers. Here they are:

    1. The Correct Spray. We’re stuck with compromises in this area. We need small droplets for coverage. We need large droplets for drift control. We need to keep application volumes moderate for productivity. We’ve basically asked the nozzle to shoulder the entire burden of our application needs, seeking a spray that hits all the right notes. Not too fine. Not too coarse. Able to work with fast and variable travel speeds and high, variable boom heights.

    Based on our research in field crops such as wheat, canola, corn, lentils, etc., we can be confident that Coarse, even Very Coarse sprays, coupled with a reasonable water volume, are appropriate for most modes of actions and target situations. These sprays contain enough small droplets for good coverage, and their larger droplets work surprisingly well in most cases. Sure, a finer spray could save some water. And a coarser spray would reduce drift even more. But we need a compromise spray, combined with some lucky weather, to get the job done.

    And yet we usually make spray quality recommendations with caveats, because droplet size alone isn’t enough. Drift is always a possibility, no matter how coarse we go. Coverage is not guaranteed, especially if the canopy is dense. Finer sprays will get deeper into a broadleaf canopy, but then we may have drift or evaporation to deal with.  The nozzle size, volume, and travel speed relationship has to be just right so the spray pressure is in the correct range. And on it goes.

    I’d like to give the overworked nozzle some help. We used to use shrouds to protect fine sprays from drift. Now it’s time to let air assist take over that task.

    Air assist booms can accelerate (i.e., add kinetic energy to) small droplets so they’re less prone to off-target movement. Properly adjusted, air assist can carry these droplets deeper into the canopy and enhance their deposition.

    A good air-assist system allows the user to select the strength and direction of the airblast to match canopy, boom height, and travel speed conditions.

    Air assist is the workhorse of most fruit-tree and vineyard spraying.  It has to be done right to provide all the benefits I mentioned, and certain approaches should be rejected. For example, there are some companies using air assist to promote very fine sprays with very low volumes. That’s the wrong use of the technology, and invites a backlash.

    Instead, we need systems that work with existing spray practice to address some of its classic shortcomings, such as drift management, deposit uniformity, and canopy penetration.

    Let’s see some products. It’s time to bring air-assist to the mainstream of agricultural spraying.

    1. Boom Height, Level, Sway and Yaw Control. Boom height is so fundamental it’s almost boring. We’ve long said that it’s important to set the boom at the right height for proper nozzle overlap and drift control. It was easy with wheeled booms. But over the last 15 years, suspended booms coupled with fast speeds have caused booms to rise again (RISE OF THE BOOMS!).

    Fact is that there are some tasks we’re asking of nozzles that they simply can’t achieve without level, low booms. Drift control is one such thing. Low booms are surprisingly effective at reducing drift, not only because winds are lower closer to the canopy, but also because droplet velocities are faster closer to the nozzle.

    Angled sprays for fusarium headlight control are another thing that is more effective with low booms.

    Spray droplets released from an angled spray soon slow down and get swept back by air resistance and begin to fall vertically, or move with wind currents, reducing their intended benefit. Low booms can prevent that.

    Uniform and low booms also keep deposit variability more manageable. They can save energy needed for air-assist systems. The shorter the path to the target, the less air-velocity will be needed to get it there.

    So how about it? Can we have boom linkages and suspension systems, coupled with sensors and hydraulics, that are stable and maintain 20” above canopy at 16 mph on uneven ground? Can we have systems that do this reliably enough that we’re prepared to invest in, say, expensive nozzle bodies? It’s possible.

    1. Sprayer Cleanout. One of my favourite questions about cleanout is: “When do you know that you’re finished cleaning the sprayer tank and booms?” Inevitably, someone from the back yells: “In two weeks!” And we laugh, knowingly.

    We have a terrible system of sprayer decontamination. It’s a process that is awkward, imperfect, and time consuming, often leading to poor practice. I’ll ask a group of producers what they do with their pesticide waste. The response is silence. I don’t blame them for not telling me that they dump the remainder on the ground somewhere, but I’d rather they didn’t. Sprayer designs don’t help.

    What we need is a system that guarantees results. To start, a tank gauge that is reliably accurate to the nearest gallon would remove some of the filling guesswork and help minimize leftovers.

    We need a remainder volume (volume left in the non-boom plumbing after the pump sucks air) that is known and small, because that remainder can’t be expelled and needs to be diluted. The smaller it is, the easier it is to dilute.

    We need pumps that can run dry, so nobody has to fear spraying the tank out completely.

    We need a wash system that requires little volume and works quickly, like continuous rinsing.

    We need plumbing that is easy to understand and whose inside surfaces do not absorb pesticide, or hide it in corners and dead ends. Perhaps it’s a recirculating system. Perhaps it hasn’t been invented yet.

    We need pesticide formulations that clean up easily. We need an easier way to inspect and clean filters. And we need a safe place to put any waste that can’t be sprayed out in a field.

    I’d like to see a sprayer that can be decontaminated in 10 minutes without the operator leaving the cab, and without any spillage of spray mixture. Clean enough to spray conventional soybeans after a tank of dicamba. Clean enough to spray canola after a tank of tribenuron. I know it’s possible.

    I also know what many of our European readers are thinking right now. Much of what I’ve discussed exists in the EU in some form or another. Why does the North American, and to a lesser extent the Australian market, not have these features?

    Part of the reason is federal standards and regulations. Some European countries test and approve products for remaining tank volume, boom stability, and spray drift, for example. Others have sprayer performance criteria that must be met to be eligible for sale in that country. An increasing number have mandatory sprayer inspection.

    These requirements serve to protect the producer and the environment. They’re an example of useful government actions. Despite, or perhaps because of, stricter rules, the entire EU marketplace is very competitive, with about 75 sprayer manufacturers. Bottom line: producers benefit.

    We need leadership, preferably from a combination of government, industry, and producers, to achieve better sprayer designs. Our market has room for products that make it easier to prevent drift, protect water, and protect yields.

    As they say, a rising tide lifts all boats. And it will certainly make my job easier.

  • Continuous Rinsing should be considered in North America

    Continuous Rinsing should be considered in North America

    Overview

    This article expands on an earlier article: here.

    Before we dive into the details, let’s start with a quick video summary filmed by RealAgriculture at Canada’s Outdoor Farm Show in September, 2016.


    When the pressure drops and the nozzles begin to sputter, the sprayer is considered empty. However, it can still retain a lot of spray solution. Repeated rinses or tank dumps in the same location can lead to accumulation and cause point source contamination.

    In response to unacceptably high levels of environmental pesticide contamination, the European Union published an amendment to their directive regarding machinery for pesticide application (2009/127/EC). Their intention was to raise the standard of equipment design to reduce the standing volume of spray solution, and to improve cleaning practices. In order to comply, sprayer technology and operator practices would have to change. But the the amendment didn’t specify how, or to what level.

    France (2006) and Denmark (2009) legislated that a rinsed sprayer must not have more than 1% or 2%, respectively, of the original tank mix concentration, as sampled at the nozzle. In response, P G Anderson et al. suggested that residual concentrations should be sampled from at least three places on the sprayer. They conducted research (download here) that showed that both field and airblast sprayers can retain 10-15% of the original concentration in the empty/fill valves, boom ends and filters, while rinsate measured 1-2% at the nozzle. They also stated that in order for sprayer designers, operators and authorities to comply with these new rules, someone had to develop a simple but robust method for cleaning sprayers.

    Continuous cleaning

    In a later paper, the author and his team proposed a method called “Continuous cleaning” (download here), which employs a dedicated clean water pump to push spray solution from the tank and out the boom in the field. For comparison, the traditional triple rinse method employs the main pump to dilute the remaining spray solution with clean water in a series of rinses and sprays. You can learn more about point source contamination and rinsing methods in this clear and informative presentation by P. Balsari and P. Marucco (download here) given in 2015 at the University of Turin in Italy.

    The continuous cleaning method isn’t new. In the 1970s some farmers cleaned their sprayers by plumbing a water supply hose into the suction line while spraying out the rinsate. They were on to something, because formal testing in the late 1990s showed that continuous cleaning was more efficient than triple rinsing. Then, from 2005 onward, research by groups such as betterspraying aps, TOPPS, the Julius Kuhn-Institut and AAMS further refined the process for both field and airblast sprayers.

    Anderson et al. made compelling claims about the continuous cleaning method. They stated that a 4,000 L sprayer with a 400 L clean water reservoir would require only 100 L to clean the plumbing as effectively as triple rinsing, which would require the entire 400 L. The remaining 300 L could be used to rinse the exterior and the entire process could take place in the field, in rotating locations. Perhaps most intriguing of all was that it would only take five minutes.

    But, it is important to note that their rinsate samples came from the nozzles, as required by France and Denmark. The issue of higher concentrations in dead-end plumbing is not addressed.

    European adoption

    In anticipation of the regulations, some manufacturers were already developing continuous cleaning kits to upgrade sprayers of all makes, models and ages. In Denmark (and to a lesser extent in France and Germany) these kits were used at workshops to upgrade sprayers. But, the installation process was not always straight-forward.

    Some kits performed better than others and expertise was needed to match the flow rate, tank rinse nozzles and the pump’s power requirements to the sprayers. Depending on the sprayer’s design, it sometimes required trial and error to establish a process of opening and closing valves during rinsing. Independent testing showed that many sprayers were greatly improved,(download here) but others proved incompatible due to the volume or inaccessibility of residual spray mix remaining in the plumbing. Specific cases include dead-ends on boom sections, or exceptionally long return lines on circulating booms

    Defining a fit for North America

    In early 2016, we wrote a preliminary article describing what we knew of the method and it created a lot of interest. We decided to test it our for ourselves in a demo at the Canadian Outdoor Farm Show. But before we describe what we did, let’s clarify a few terms. You may have noted that in Europe the process is called “Continuous cleaning” but moving forward we will refer to the method as “Continuous rinsing”. This is because we feel cleaning a sprayer and rinsing a sprayer are different processes with different objectives.

    “Cleaning” a sprayer is a total decontamination that should be performed when changing chemicals and at the end of every spray day. It requires the use of a detergent and any label-required additive (such as ammonia following the new dicamba products). Perhaps most importantly, it requires the operator to address the dead-end plumbing areas. There is no universally-accepted process, but we describe fairly common protocols for field sprayers here and for airblast sprayers here.

    “Rinsing” is a less intensive process intended to reduce the amount of residue that can build up on, or soak into, sprayer surfaces. Water is brought into contact with most of the plumbing to dilute any solution left in the sprayer, and is then sprayed out in the field. This process should be performed every few loads, or when moving an empty sprayer between fields, or if the operator has (perhaps unwisely) decided not to clean the sprayer at the end of the day because they are spraying the same chemical tomorrow. Often, this is accomplished using the triple rinse process, which we describe here:

    Triple Rinse Process

    1. The pressure drops and nozzles sputter (i.e. spray tank is empty).
    2. If the sprayer has an inductor bowl or loading bypass, and if the operator doesn’t already rinse these systems following filling, the operator will exit the cab, open the valve to clean water reservoir, and use a portion of the clean water to clean these circuits. In some cases, the rinse process can be performed without the operator having to leave the cab.
    3. Sprayers with dead end plumbing on boom section ends warrant special consideration. Spray mix can be harboured in the dead ends and is a significant source of contamination, no matter how much rinsing is performed (see video). Therefore, the first rinse (step 5) should be interrupted before it is complete to allow boom ends to be opened, flushed and closed.
    4. The operator then introduces 1/3 of the clean water reservoir to the spray tank through the rinsing nozzle(s) and circulates for 5 minutes (including the agitation line).
    5. The operator returns to cab, and drives to spray the volume out in the field until the nozzles sputter.
    6. Operator exits the cab and introduces 1/3 of the clean water reservoir to the spray tank through the rinsing nozzle(s) and circulates for 5 minutes (including the agitation line).
    7. The operator returns to cab, and drives to spray the volume out in the field until the nozzles sputter.
    8. Operator exits the cab and introduces 1/3 of the clean water reservoir to the spray tank through the rinsing nozzle(s) and circulates for 5 minutes (including the agitation line).
    9. The operator returns to cab, and drives to spray the volume out in the field until the nozzles sputter.

    The process, illustrated in this field sprayer plumbing animation, takes about 40 minutes and may require the operator to leave the cab multiple times.

    1bt217

    Continuous rinsing requires a second pump to be installed in the system. Rather than performing a serial dilution in three batches, this rinsing essentially pushes spray solution out of the sprayer using clean water. The agitation line creates some dilution since it loops back to the tank, but that small volume is quickly diluted by the process, as below:

    Continuous Rinse Process

    1. Pressure drops and nozzles sputter (i.e. spray tank is empty).
    2. If the sprayer has an inductor bowl or loading bypass, and if the operator doesn’t already rinse these systems following filling, the operator will exit the cab, open the valve to clean water reservoir, and use a portion of the clean water to clean these circuits.
    3. There can be no dead-end plumbing at the end of boom sections for this process to work (e.g. sections terminate with air-aspirating end caps).
    4. The operator returns to cab (if they left), and begins introducing clean water to the tank through the rinsing nozzle(s).
    5. When a small volume has been introduced, the operator engages the agitation line with reduced flow to tank and begins driving and spraying at a rate slightly higher than the clean water pump’s flow rate.
    6. Operator continues to spray until the nozzles sputter.

    The process, illustrated in this field sprayer plumbing animation, takes about 10 minutes and requires the operator to leave the cab once at most.

    1bt23a

    Building a demo system and model

    We worked with HJV Equipment in Alliston, Ontario to build a bench-top model representing a simple, scaled-down sprayer rinse system. Using the model, we planned to compare the effectiveness and the efficiency of triple rinsing to continuous rinsing – and we would do so in front of an audience. HJV felt that to make an appropriate model, we should base it on an installed system. So, they plumbed a working system into a RoGator 700.

    They used two Hypro electric roller pumps (model 4101 N-H) in parallel, plumbed into the clean water reservoir. Anti-backflow valves led the water to the tank rinse nozzles. The system could be engaged from the cab and could be isolated from the existing rinse system, leaving the sprayer’s original system intact and available for when full cleanings were required. The designer/mechanic points out key features in the following video.

    The RoGator 700 has a 700 US gallon tank and a 50 US gallon clean water reservoir. By tapping into an existing compressor, HJV created a means for blowing out the boom with air, greatly reducing the amount of spray solution left in the empty sprayer. Still, the “empty” sprayer would retain about 15 US gallons in the pump, sump and remaining lines. Based on those parameters, we designed and constructed our scaled model. We used 10 L in the main tank and 4.5 L in the clean water reservoir. The lines and sump held about 1.25 L so we felt breaking the 4.5 L of clean water into three 1.5 L volumes was fair.

    In the images that follow you can see the components. Basically we have a spray tank, clean water reservoir, main pump, dedicated clean water pump, the sprayer boom, and some clever anti-backflow and valves to switch the “sprayer” from one method of rinsing to the next.

    2016_cont_rinse_demo_3
    2016_cont_rinse_demo_1
    2016_cont_rinse_demo_2

    But, we still had to devise a means to measure the effectiveness of the two rinsing systems. UV dye would be difficult to use with a live audience in real time, and food colouring would be too subjective. We decided to use a conductivity meter, which quickly measures the electrical conductivity of a liquid. Using NaCl (table salt) as a readily-dissolved conductor, we calibrated the unit and found we could reliably register table salt in parts per million.

    2016_conductivity

    The demo process

    We ran the demo six times over three days and recorded how long each rinse took and how effective each rinse was in reducing the original concentration. Here’s how we did it:

    Triple Rinse (~4.5 minutes)

    1. Fill the main tank to 10 L.
    2. Introduce 10 cc of salt (and coloured with green food dye) to create our spray mix.
    3. Circulate the solution through the main pump and agitation line to ensure it was completely homogeneous.
    4. Start the system spraying out of the boom.
    5. Draw a sample of the spray mix to serve as our baseline concentration.
    6. When the nozzles began to sputter, the tank was “empty” (duration: 150 seconds).
    7. We drained the boom via valve on the boom-end to simulate “blowing out” the boom. (duration: 5 seconds)
    8. We introduced 1.5 L of clean water through the tank rinse nozzle (duration: 15 seconds).
    9. We circulated the solution through the agitation line. (duration: 30 seconds).
    10. We sprayed the solution out of the boom, drawing a sample of rinsate before the nozzles sputtered (duration: 30 seconds)
    11. Repeat steps 8-10 two more times to represent the other two rinses.

    Continuous Rinse (~1.5 minutes)

    1. Fill the main tank to 10 L.
    2. Introduce 10 cc of salt (and coloured with green food dye) to create our spray mix.
    3. Circulate the solution through the main pump and agitation line to ensure it was completely homogeneous.
    4. Start the system spraying out of the boom.
    5. Draw a sample of the spray mix to serve as our baseline concentration.
    6. When the nozzles began to sputter , the tank was “empty” (duration: 150 seconds).
    7. We drained the boom via valve on the boom-end to simulate “blowing out” the boom. (duration: 5 seconds)
    8. We reduced the agitation flow to a low rate and introduced 1.5 L of clean water through the rinse nozzle using our dedicated pump (duration: 5 seconds)
    9. At the 5 second mark, we started spraying while still introducing clean water.
    10. Samples of rinsate were drawn at regular intervals, with particular attention to collect the last volume fraction as the nozzles were sputtering (duration: 100 seconds)

    Results

    Triple Rinse

    The average starting conductivity for the triple rinse demo was 2,520 µS (n=6). The final sample of rinsate registered a conductivity of 490 µS (n=6) representing a final concentration that was 19.4% of the original. Average time: 4.5 minutes.

    Continuous Rinse

    The average starting conductivity for the continuous rinse demo was 2,145 µS (n=6). The final sample of rinsate registered a conductivity of 342 µS (n=6) representing a final concentration that was 16% of the original. Average time 1.5 minutes.

    We were surprised the model could not reduce the concentration of salt to an acceptable 1-2% level. The Agrimetrix Dilution Calculator App suggests it should have been much better. We suspect the standing volume of the system is higher than we predicted, and we weren’t using enough clean water to dilute it. We may have had better results if we’d used a lower concentration of salt to begin with, and/or a higher volume of clean water. We will continue to tweak the demo model and will update this article as we collect more information. The more stringent research in Europe showed that continuous rinsing is a effective as triple rinsing.

    The most interesting result is that continuous rinsing took 1/3 of the time triple rinsing required (1.5 minutes versus 4.5 minutes). Research in Europe suggested 1/4 of the time as triple rinsing. The difference is likely accounted for by the time the operator used leaving and entering the cab.

    You can see the effectiveness of the process in this AAMS demonstration video. Sure, their demo unit is nicer than the one we built, but our rustic version has charm 🙂 Note the sequence of opening and closing valves to ensure all circuits are rinsed clear of dye.

    Conclusion

    If continuous rinsing is as effective as triple rinsing and can be performed in a fraction of the time with less operator exposure, then we should be modifying our sprayers to support the method. Airblast sprayers and small field sprayers are relatively easy to modify, and can be even be equipped with a spray wand so excess clean can be employed to rinse down the exterior.

    2016_aams_rinse_system

    Larger field sprayers, however, may be more challenging as they do not all lend themselves to the conversion:

    • The clean water pump (hydraulic or electric) must have sufficient power.
    • Matching the pump capacity to the sprayer can be problematic; The clean water pump flow rate must be 30-50% of the boom flow rate.
    • Sprayers with dead-end boom sections or circulating-flow return lines may not be compatible, and those with pneumatic systems to clear the boom of solution are preferred.
    • More sophisticated electronic rate controller systems (e.g. on the larger self-propelled sprayers) may not be compatible.

    And, of course, we must remember that neither triple or continuous rinsing should be seen as a replacement for the sprayer cleaning process. Any drain-able part of the sprayer will still harbour high concentrations of residues (e.g. filters, valves, inductors, bypass lines – any dead-end plumbing). With new stacked chemistries being introduced in North America (some still active when residues register as little as a few parts per million), diligent sprayer sanitation is more important than ever.

    Thanks to Jan Langenakens of aams for his help researching and informing this article.