Category: Cleaning & Maintenance

Articles about removing pesticide residue and disposing of rinsate from horizontal boom sprayers

  • Diluting 20,000-Fold with a 30 Gallon Remaining Volume in a 1,200 Gallon Tank

    Diluting 20,000-Fold with a 30 Gallon Remaining Volume in a 1,200 Gallon Tank

    (This short article is an addendum to this article)

    Our goal in this example is to dilute by a factor of 20,000.

    The maximum amount of dilution possible with a 1,200 gallon tank and a 30 gallon remainder is 1200/30=40.

    The formulae:

    Dilution per Rinse = final dilution ^(1/# of rinses)

    Rinse Volume = (dilution per rinse * remaining volume) – remaining volume

    • One rinse diluting by 20,000 – impossible with a 1,200 gallon tank (max achievable is 40-fold);
    • Two sequential rinses, each diluting by a factor of 20,000^(1/2) = 141. Also impossible with a 1,200 gallon tank;
    • Three sequential rinses, each diluting by a factor of 20,000^(1/3) = 27. A volume of 780 gallons can do this  (27*30)-30=780 gallons. For three rinses, the total volume is 2,340 gallons.
    • Four sequential rinses, each diluting by a factor of 20,000^(1/4) = 12. A volume of 330 gallons can do this, for a total volume of 1,320 gallons;
    • Five sequential rinses, each diluting by a factor of 20,000^(1/5) = 7. A volume of 180 gallons can do this, for a total volume of 900 gallons;
    • Six sequential rinses, each diluting by a factor of 20,000^(1/6) = 5.2. A volume of 126 gallons can do this, for a total volume of 757 gallons.

    Second, let’s assume the operator is prepared to prime the boom where it doesn’t harm soybeans. Now the first new product tank takes care of the last dilution, lowering the cleanout dilution requirement by 1,200/30 = a factor of 40. Now the cleanout dilution requirement is only 20,000/40 = 500.

    • One 1,200 gallon tank rinse can only achieve 40-fold dilution.
    • Two rinses, each diluting by 500^(1/2) = 22. Rinse volumes of 640 gallons are sufficient, for a total of 1,280 gallons.
    • Three sequential rinses, each diluting by a factor of 500^(1/3) = 7.9. A volume of 210 gallons can do this, for a total volume of 630 gallons;
    • Four sequential rinses, each diluting by a factor of 500^(1/4) = 4.7. A volume of 112 gallons can do this, for a total volume of 448 gallons.
  • How Clean is Clean?

    How Clean is Clean?

    One of the more perplexing questions in tank cleanout is knowing when the cleaning process is good enough to prevent harm. This question is especially relevant to producers that grow canola and use Group 2 herbicide products, or grow soybeans and use dicamba on some of their area. In both of these examples, crops can be extremely sensitive to very small residues.

    When does an applicator know that the cleaning job was good enough? In about two weeks! There is no easy way to tell, except to be precautionary.

    A bit of math can help put us in the ballpark. First, we need to know the tolerance of a crop to the herbicide, preferably expressed as a proportion of the tank mix to be cleaned. Let’s use dicamba as an example. It’s been reported that non-dicamba tolerant soybeans can show leaf-cupping symptoms from dicamba at rates as low as 1/20,000 of the label rate.

    Recall that sprayer cleanout is really two separate processes that we’ve written about here, here, and here. The first is dilution of the remaining volume in the system. The second is decontaminating specific sprayer components (filters, boom ends, hoses). We’ll focus on dilution in this article.

    If you’re diluting, the second piece of information you need is how much liquid is left in the sprayer when you start cleaning. All sprayers have a certain amount of liquid left in the tank and associated plumbing after the tank is empty. The sump, the suction line feeding the pump, and the lines returning to the tank via agitation or sparge are most common. Even when the pump no longer draws liquid, those lines retain some volume of product. This volume can’t be pushed out to the boom, most of it goes back to the tank.

    The volume of this “remaining liquid” is likely somewhere between three and thirty US gallons.

    The remainder volume depends on the sprayer, and also how the tank is emptied. Some applicators simply spray until the solution pump pressure drops, others choose to drain the remaining liquid from a sump valve. When draining, product should be captured in pails rather than allowing it on the ground where it will harm the soil and possibly make its way into runoff.

    It’s always preferable to spray the tank empty in a field.

    As we’ll see below, a low remaining volume greatly improves the efficiency of the dilution process. It’s a sprayer feature that should be considered at purchase.

    The table below has some sample calculations. Note that the paired cases (1&2, 3&4, 6&7) all use the same total water volume, but compare a single vs triple rinse of three different remaining volumes.

    Comparing Case 1 to Case 3 or Case 6, (remaining volumes of 10, 20, and 50, respectively), it’s clear that minimizing the remaining volume is important.

    It’s also striking that the same amount of clean water, subdivided into three smaller repeat batches (Case 2, 4 and 7), is much more powerful than using single batches with the same total clean water amounts.

    Reducing the size of each batch even further and increasing the number of batches (Case 5) approaches what a properly executed continuous rinse can do.

    Is it necessary to dilute to the level that’s safe for the next crop? Not always. The next product in the tank acts to dilute the remainder once again, possibly by a factor of 100, depending on the remaining volume and the tank size (Case 8). The material in the boom, however, won’t be diluted by this additional volume, and therefore may harm the crop unless it is first sprayed out elsewhere, especially when section ends are not drained and rinsed.

    This is where a recirculating boom is valuable, providing an opportunity to charge the boom without spraying. The penalty is that the boom volume is then returned to the tank in the process, increasing the amount that needs to be diluted.

    Let’s return to the dicamba example with a 20,000-fold dilution requirement and a 1,200 gallon tank. We’ll consider two examples. In the first, the operator wants to prime the boom in the soybean field without any harm to the dicamba-susceptible beans. A 20,000-fold dilution is needed.

    We’ve looked at five options that each assume a remaining volume of 10 gallons. Note that our goal is the same – dilute by a factor of 20,000.

    The formulae:

    Dilution per Rinse = final dilution ^(1/# of rinses)

    Rinse Volume = (dilution per rinse * remaining volume) – remaining volume

    The maximum amount of dilution possible with a 1,200 gallon tank and a 10 gallon remainder is 120 (see Row 8, Table above).

    • One rinse diluting by 20,000 – impossible with a 1,200 gallon tank (max achievable is 120-fold);
    • Two sequential rinses each diluting by a factor of 20,000^(1/2) = 141. Also impossible with a 1,200 gallon tank;
    • Three sequential rinses, each diluting by a factor of 20,000^(1/3) = 27. A volume of 260 gallons can do this  (27*10)-10=260 gallons. For three rinses, the total volume is 780 gallons.
    • Four sequential rinses, each diluting by a factor of 20,000^(1/4) = 12. A volume of 110 gallons can do this, for a total volume of 440 gallons;
    • Five sequential rinses, each diluting by a factor of 20,000^(1/5) = 7. A volume of 60 gallons can do this, for a total volume of 300 gallons.

    The first two examples don’t work because the tank isn’t big enough. But the three remaining examples all work equally well, they just consume different amounts of clean water.

    If that doesn’t seem like a lot of work, then repeat this calculation with a 30 gallon remainder volume, common on many sprayers. Short on time? We did it for you here.

    Second, let’s assume the operator is prepared to prime the boom where it doesn’t harm soybeans. Now the first new product tank takes care of the last dilution, lowering the cleanout dilution requirement by 1,200/10 = a factor of 120. Now the cleanout dilution requirement is only 20,000/120 = 166.

    • One 1,200 gallon tank rinse can only achieve 120-fold dilution.
    • Two rinses, each diluting by 166^(1/2) = 13. Rinse volumes of 120 gallons are sufficient, for a total of 240 gallons.
    • Three sequential rinses, each diluting by a factor of 166^(1/3) = 6. A volume of 50 gallons can do this, for a total volume of 150 gallons.

    The math is simple, and can be done using the formula in the first table, or this app:

    The hard part is knowing what the remaining volume is. It would be very useful for a manufacturer to provide this information.

    In the meantime, you can estimate on your own. Add water with surfactant to your tank, and spray it empty. While spraying, turn the agitation on and off to fill and activate the sparge, if equipped. Once the tank is empty and the spray pressure drops, stop and drain the sump into pails. Ensure that the pump suction line and the pressure line up to and including the agitation and sparge lines also drain. Disconnect these if necessary. If there is a filter housing in this circuit, remove it as well.  Avoid collecting liquid from the pressure line beyond where the the agitation or sparge split off, as this will be pushed out to the boom.

    An alternative is to estimate the length of hose in this circuit, using the following table as a guide:

    And remember, diluting the remaining liquid is only one part of a cleaning process.

  • Testing the Effectiveness of Sprayer Rinsing Methods using Dicamba

    Testing the Effectiveness of Sprayer Rinsing Methods using Dicamba

    This work was performed with Mike Cowbrough, Weed Management Specialist (Field Crops) with OMAFA.

    The unprecedented number of dicamba drift complaints in the United States has proven to be a polarizing issue in the agriculture community. The debate continues as to the relative influence of contributing factors.

    The sensitivity of soybeans to trace amounts of dicamba has been known for more than 50 years (Wax et al. 1969). Research has shown that less than 0.2% of the highest recommended use rate can cause a 10% yield loss in non dicamba-tolerant soybean (Robinson et al., 2013). Many horticulture and ornamental crops are equally sensitive to low doses of dicamba.

    Relative volumes of Callisto (33% field rate), Roundup (6% field rate) and Xtend (0.16% field rate) known to cause 10% yield loss in conventional soybean.

    The inherent volatility of the active, and its subsequent potential for off-target movement, is also well known. Research has shown that XtendiMax, Engenia and FeXapan are far less volatile than their predecessors. However, research has also shown that there is some degree of volatilization for 36 hours following application, peaking 6-12 hours after treatment (Mueler, 2017). Studies by Jacobson et al. (2014) showed dicamba present in the air 60-72 hours after treatment.

    While sensitivity and volatility are suspected of being the primary culprits, there are other factors that contributed to the estimated 3.6 million acres of soybean reported damaged in the United States in 2017 (Bradley, 2017):

    • inappropriate sprayer set-up,
    • physical drift,
    • the use of older dicamba chemistries, and
    • contamination of filling or spray equipment (aka carry-over)

    The Experiment

    In 2017, we decided to learn more about sprayer contamination. The following is a summary of the labelled cleaning protocol. It’s noted that rinsate disposal must comply with local regulations:

    1. Drain sprayer immediately after use.
    2. Flush all inner surfaces with water.
    3. Fill sprayer with an ammonia-based solution and soak overnight.
    4. Concurrently, remove and soak strainers, screens and nozzles.
    5. Circulate solution for 15 minutes and flush through the boom for one minute.
    6. Drain sprayer, replace strainers, screens and nozzles, and flush once more with water.

    This thorough protocol is not unique to dicamba, and historically has not been followed by sprayer operators. Instead, operators choose cleaning methods that reflect the risk of damage and the time and effort required to clean the sprayer. The majority flush with water, may or may not perform serial rinses and may or may not address dead end plumbing. Where possible, operators schedule sprays that present the least potential for carry-over damage (e.g. moving into corn following soybean). There is no way to know for certain that the sprayer is sufficiently cleaned.

    Sprayer

    Our research sprayer had a tank capacity of 60 L and was calibrated to deliver a spray volume of 15 gallons per acre. RoundUp Xtend was added at the highest labeled rate of 2 L/acre (consisting of glyphosate at 1,200 gae/ha and dicamba at 600 gae/ha). We reserved the solution for reuse by collecting spray in jugs.

    Rinses

    Serial rinse

    On a typical sprayer, the capacity of the clean water tank is ~10% that of the product tank. To perform a triple rinse, the operator introduces 1/3 of that volume to the product tank through a washdown nozzle, circulates for 10 minutes, and then sprays the product tank empty. This is repeated two more times to empty the clean water tank.

    Our intent was to scale the process in the same ratio using the research sprayer. That would mean using a 6 L volume of clean water to represent 10% of the 60 L product tank. It follows that we would have to perform three, 2 L rinses.

    However, that was insufficient volume to engage the pump and still provide enough rinsate to spray in our trials. We calculated the minimum required volume to be 8 L per rinse. We circulated for 5 minutes through a washdown nozzle. Following our third rinse, we noted that the rinsate still smelled of dicamba, and elected to run a fourth 8 L rinse. Rinsate was collected from multiple nozzles spaced evenly along the boom.

    We then opened the suction filter and the two line filters and poured the remaining solution into a bucket. We topped the volume up to 8 L with clean water and scrubbed the filters with a brush.

    Continuous rinse

    The continuous rinse process continually introduces clean water via the washdown nozzle via a dedicated pump. Concurrently, the product pump sprays from the nozzles and circulates via the agitation/bypass line. We used 32 L of clean water (a volume equivalent to that used in the serial rinse) and collected rinsate in four, 8 L volumes.

    Rinsate was collected from multiple nozzles spaced evenly along the boom. We then opened the suction filter and the two line filters and poured the remaining solution into a bucket. We topped the volume up to 8 L with clean water and scrubbed the filters with a brush.

    Continuous rinse using 1% ammonia solution

    We followed the continuous rinse process, as previously described, in order to collect the filter residue.

    Possible artifacts

    The limitations involved in scaling down introduce two potential artifacts to this experiment. First, the ratio of clean water to product volume is high compared to typical practices for both rinses. We estimate the volume remaining in the sprayer when “empty” did not exceed 4 L.

    Second, continuous rinsing was sampled in batches, which means the fourth and final volume collected represents an average of the active remaining in the system rather than the final concentration. As such, it would likely be more concentrated than what truly remained in the sprayer.

    Application

    Rinsate was applied to glyphosate tolerant soybean on 30” rows. Rinsate was applied at 20 gpa using a handboom with AIXR 11002 nozzles. Ontario locations were Ridgetown, Elora, Winchester and Woodstock.

    Results

    Crop Injury

    Regardless of rinse procedure, crop injury was greatest after the first rinse cycle and diminished after each subsequent cycle (Table 1). The first half of the continuous rinse procedure caused greater injury than the serial rinse, but injury was equivalent for the final half. Crop injury was less when rinsate was applied to soybeans at an early vegetative stage (V2) compared to when rinsate was applied to soybeans at later vegetative stages (V5-V6) or the early reproductive stage (R1).

    Table 1: Visual Injury (%) of soybean 14 days after the application of rinsate that was collected from two different sprayer cleanout procedures.

    TreatmentEloraRidgetownWinchesterWoodstock
    % Visual Injury at 14 days after application
    Crop stage at applicationV5V2V6R1
    Weed-Free Control0000
    RU Xtend100100100100
    Serial Rinse # 110075100100
    Continuous Rinse # 1 (25% water)10095100100
    Serial Rinse # 275659090
    Continuous Rinse # 2 (50% water)85709595
    Serial Rinse # 355506075
    Continuous Rinse  # 3 (75% water)55506075
    Serial Rinse # 425102535
    Continuous Rinse # 4 (100% water)25102535
    Filters – Serial Rinse15301025
    Filters – Continuous Rinse15301025
    Filters – Continuous with 1% ammonia25452035

    We were surprised to observe dicamba injury even in the final stages of both rinse procedures. This reinforces how sensitive soybeans are to low doses of dicamba and demonstrates the importance of following the labelled water – ammonia – water sequence.

    When comparing damage from filter residue (following a continuous rinse) the rinsate extracted using a 1% ammonia solution was more injurious than rinsate from plain water. Cundiff et al. (2017) found no difference between the use of water or water-and-ammonia when cleaning out a sprayer. We speculate that the ammonia was more effective at removing dicamba from the sprayer, or it increased the residue’s potency.

    Soybean yield

    Yield losses appeared to mirror visual injury; as dicamba injury decreased, so did soybean yield loss. Yield losses were observed following application of all rinsate treatments, which is understandable given that dicamba injury also occurred following the application of all rinsate treatments.

    Yield losses were greater in the first half of the continuous rinse protocol, but were par with the serial rinse for the second half (Table 2). Yield losses were observed following the application of rinsate collected from filters, demonstrating the importance of following a thorough sprayer decontamination that addresses dead-end plumbing, filters and nozzles.

    Table 2: Yield (% of weed-free control) of soybean following the application of rinsate that was collected from two different sprayer cleanout procedures.

    TreatmentEloraRidgetownWinchesterAverage
    Yield (% of weed-free control)
    Crop Stage at applicationV5V2V6V2-V6
    Weed-Free Control100100100100
    RU Xtend0000
    Serial Rinse # 1044115
    Continuous Rinse # 1 (25% water)01304
    Serial Rinse # 233651036
    Continuous Rinse # 2 (50% water)2261328
    Serial Rinse # 374896676
    Continuous Rinse  # 3 (75% water)72895776
    Serial Rinse # 486968689
    Continuous Rinse # 4 (100% water)86978289
    Filters – Serial Rinse939610096
    Filters – Continuous Rinse87979593
    Filters – Continuous with 1% ammonia79859285

    Other observations

    1- Dicamba injury delayed soybean maturity and date of harvest by over 14 days at the Elora site. Delayed maturity was observed at the Winchester locations as well.

    2- Heavy rainfall shortly after the application of rinsate at the Winchester location caused water ponding. Since dicamba is very water soluble, crop injury and yield loss was higher in areas in the trial where water ponded after application.

    3- Dicamba injury appeared to accentuate other stress symptoms at the Elora site, specifically potash deficiency. In the absence of dicamba injury, soybean plants did not exhibit potash deficiency symptoms.

    Take Home

    • Continuous rinsing was as effective as four low-volume rinses.
    • Plots sprayed with the cleanest water rinsate (both protocols) averaged 11% lower yields than unsprayed plots.
    • Filter rinsate (following continuous rinse with water) resulted in an average 7% yield loss.
    • Filter rinsate (following continuous rinse with 1% ammonia) resulted in an average 15% yield loss.

    Citations

    • Bradley, K. 2017. “A Final Report on Dicamba-injured Soybean Acres”. University of Missouri Integrated Pest Management online. https://ipm.missouri.edu/IPCM/2017/10/final_report_dicamba_injured_soybean/
    • Cundiff, G.T., Reynolds, D.B. and T.C. Mueller. 2017. Evaluation of dicamba persistence among various agricultural hose types and cleanout procedures using soybean (Glycine max) as a bio-indicator. Weed Science. 65(2), pp. 305-316.
    • Jacobson, B., Urbanczyk-Wochniak, E., Mueth., M.G., Riter, L.S., Sall, J.H., South, S. and Carver, L. 2014. “Field Volatility of Dicamba Formulation MON 119096 Following a Post-Emerge Applciation Under Field Conditions in Texas”. Monsanto Report Number MSL0027193.
    • Mueller, T. 2017. “Effect of adding Roundup PowerMax to Engenia on vapor losses under field conditions” (Presentation).
    • Robinson, A.P., Simpson, D.M. and W.G. Johnson. 2013. Response of glyphosate-tolerant soybean yield components to dicamba. Weed Science. 61(4), pp. 526-536.
    • Wax, L.M., Knuth L.A., and Slife F.W. 1969. Response of soybean to 2,4-D, dicamba, and picloram. Weed Sci 17, pp. 388-393.
  • Plumbing Projects That Make Spraying Easier and Safer

    Plumbing Projects That Make Spraying Easier and Safer

    Some of our biggest struggles in spraying involve the start and end of each spray day.

    When starting a new field after the sprayer is cleaned, we need to prime the boom. If it’s full of water, that water has to be purged and the question is always for how long and where to do this (pro tip at bottom of article).

    At the end of the day, we should ideally clean the sprayer. During that process, we may struggle with waste disposal, including large rinsate amounts, and course, the uncertainty of whether the job is actually done (since clean water looks exactly the same as contaminated water).

    If not cleaning the entire sprayer plumbing, we should at least rinse the boom, even if we’re returning to the same product the following day. It can prevent future problems.

    These tasks are complicated by the increasingly convoluted plumbing featured on modern sprayers. Ask someone to explain their sprayer’s plumbing system to you one day. It’s a long story! A bright spot is the well-engineered, compact, and accessible Agrifac system.

    Fortunately, virtually any sprayer can be modified to suit your needs. Let’s talk about a few ideas for a winter project:

    1. Boom flush. It’s good practice to flush clean water through your boom at the end of spraying even if the main tank remains full of product. Some sprayers have an air purge system to eliminate liquid from the plumbing and that is a great feature. A water flush should follow that purge so that any residual pesticide is diluted and removed before it can dry on and become hard to remove later.  First you’ll need a clean water tank on the sprayer (150 gal is enough). Second, plumb a feed so that this clean tank can be the sole source of the water supplied to the solution pump. Select this source, shut return lines down or off, and pump clean water through boom.  Sprayers that have an auto-rinse cycle will likely be able to draw clean water, but may not be able to push it to the boom, directing it to the wash-down nozzles instead. Check to see what’s possible, and make the changes you need.
    2. Clean water pump. Installing a second pump dedicated to the clean water tank has several advantages. We’ve talked about continuous rinsing before, here, and here, as a way to dilute the tank remainder faster. It requires installation of a second pump dedicated to clean water. Additionally, give this pump the option to deliver water to the boom, not just the wash-down nozzles. Now it can be used to rinse water through the boom. The main challenge is to obtain a pump capacity that can match the needs of the boom and/or the wash-down nozzles.
    3. Boom ends. We’ve mentioned this part of the boom many times. Boom ends must be flushed regularly to get rid of product and possibly debris that gets stuck there. A simple way to achieve this is to use the Express Nozzle Body End Caps from Hypro. These bleed air continuously, and also prevent accumulation of dead-end contamination. They do need to be flushed, and this can be done by pulling a plug or rotating the turret to an open (no nozzle ) position.
    1. Recirculating boom. This is a significant change, but worth considering. Conventional plumbed booms are separated into five to 13 sections. Each has two ends at which the spray stops and where air and contamination can accumulate (see point #3). Each section feed has a shutoff valve.  Once the spray mixture leaves the pump and bypass valve, it is committed to leaving the sprayer.  In a recirculating boom, the boom becomes a part of the tank and the liquid can return to the tank if desired. Spray is pressurized at one or both ends, and valve positions determine its flow. Sectional control is achieved with individual nozzle shutoff, air or electric.
      1. Three advantages:
        (a) the boom can be primed with new product without spraying. The surplus goes back to the tank.
        (b) the boom can be flushed with water without spraying while material is still in tank, and without spilling anything on the ground. Again, the surplus goes back to the tank.
        (c)  high resolution sectional control with individual nozzle shutoff is a byproduct of this design. Fast response, high res, saves money.
    2. Steel lines. Steel cleans easier than plastic, and this material makes a lot of sense for booms. But it also makes sense for the boom feeds, currently handled by black rubber hose.  This hose is a literal black box. We can’t see inside it, and we don’t know if and where potential contamination resides. It has considerable surface area. Consider replacing portions of your feed lines with steel. The boom is the obvious candidate. Aside from easier cleanout, it also helps with faster nozzle shutoff because it doesn’t expand with pressure.

    A word about dumping the tank on the ground. It’s a bad practice for many reasons. Let’s examine just one of those. When you spray a product at 10 gpa, you actually cover each square meter with about 10 mL, or 1/3 oz, of spray mix. When you flush your boom ends on the ground, you’re probably dropping 2 or 3 gallons in the same area. That’s 1000 times the label rate at each boom end, 10 to 26 times per boom. If you dump your tank remainder and all the hoses, say 20 or 30 gallons, that’s 10,000 times the label rate if it covers 1 sq meter. That’s leaching, runoff, residual potential, and not a good story.

    Many of the changes we outlined above help prevent that from being necessary.

    Pro Tip: To find out how much water your plumbing (from the pump to the boom ends) holds, do this: After cleaning with water and before spraying an EC formulation (white milky appearance in tank, some crop oils are ECs) reset your sprayed gallons on your rate controller. Start spraying and watch for the last nozzle on your furthest and longest section to spray white. Stop spraying and check your sprayed gallons. That’s your volume. No matter the size of nozzle or application volume, it stays constant. To be sure the boom is primed with a new mix, spray until those gallons are reached and you’re set.

  • Storing Pesticide Mix Overnight

    Storing Pesticide Mix Overnight

    Not being able to finish a tank due to weather or any other reason happens to just about everyone. Is it OK to simply leave the sprayer as is, and resume spraying later after some agitation?

    In many cases, the answer is yes. Most pesticide mixtures are stable in short term storage. On resuming spraying, an agitation could be all that’s needed to get back to where you started a day or so earlier.

    But there are three important exceptions.

    When the active ingredient is formulated as a suspension. Suspensions are typically wettable powders and flowables, and rely on a clay carrier to distribute the active in the tank. Because clay is denser than water, these formulations settle out quickly after agitation stops. Sure, they can be brought back into suspension with vigorous agitation. But in lines and booms, boom ends and screens, dislodging a settled clay carrier is much more difficult. It’s also hard to tell if the cleaning has been successful because the problem spots are hidden.

    The best solution is to flush the spray boom with water before materials can settle and lodge. A visual inspection where access is possible, such as strainer bowls and boom ends, is part of the process to ensure the formulated product has been removed.

    Learn to identify which formulations are suspensions. There’s lots of jargon out there. Look for terms such as DC, DF, DG, DS, F, Gr, SP. Even EC formulations are suspensions (oil in water) and require agitation.

    When the active ingredient is chemically unstable. Some pesticides can degrade in the tank, usually due to alkaline (high pH) hydrolysis. The effect is very pesticide specific, but in general, insecticides (particularly organophosphates and carbamates) are more susceptible than other pesticides. This fact sheet by Michigan State University describes the impact of pH on a the half-life of a large number of pesticides.

    Note that in the examples in the MSU fact sheets, pesticide half lives are typically days and weeks, and only rarely hours. Also note that while high pH is most often problematic, low pH can lead to faster breakdown in a small number of products.

    Ensuring tank mix stability requires a pH meter or paper, and possibly a pH modifier such as citric acid. But do your research first! Here’s an article on pH and water quality.

    When the tank previously contained a product known to harm the current crop. This situation is most common and most difficult to address. Some examples from western Canada are Group 2 modes of action sprayed prior to a canola crop. Why are Group 2 products implicated?  Many are formulated as dry products on a clay base, and these can settle in boom ends, adhere to tank walls, or get stuck on screens. Their solubility is pH dependent, as we explain in this article.

    Canola is particularly sensitive to this mode of action, and the most common canola herbicides, Liberty and glyphosate, are formulated with strong detergents that act as tank cleaners.

    Even when applicators think that their tank is clean, they can’t actually be sure and can’t do much about it at that stage. The stripping of tiny amounts of residue off the tank walls, filter screens, or plumbing, can happen during a mid-day stop or an overnight break.  Applicators eventually find out that this happened, usually about two weeks after spraying.

    Our advice is:

    After spraying a herbicide to which a subsequent crop may be sensitive, with the classic case being a Group 2 and moving to canola, be extra diligent with cleaning and pay attention to the tank walls, all screens, and boom ends.

    The best way to solve issues is to avoid them in the first place. If the weather looks unsettled and may interrupt your spray operation, consider mixing smaller batches that can be sprayed out completely even if conditions change quickly. This allows you to rinse the tank and spray water through the boom, thus avoiding a contamination problem developing overnight.

    If that’s not possible, at least do not let a tank mix sit in the boom overnight. Instead, use your clean water tank to push water through the boom prior to storage and double check the screens. The following day, prime the boom with your tank mix as usual and resume spraying the crop.

    If you’re not sure that your sprayer can draw from the clean water tank and push through the booms (the wash-down nozzles are, after all, the intended destination for that water), decipher your system and add the necessary valves that make this possible.

    A useful design that helps flush and prime a boom quickly is the recirculating boom offered by some aftermarket boom manufacturers. These booms are also more common on European sprayers. A nice feature of such designs is that the tank contents can be pumped through the entire boom assembly without actually spraying. This ensures that the boom is primed without any soil contamination. It also dilutes whatever residue there may be in the boom plumbing with the entire tank, likely reducing its concentration enough to be of little concern.

    An additional feature of recirculating booms is that many offer stainless steel tubing throughout most of their feed and return length, minimizing the black rubber hose products that often adsorb, and later release, herbicide contamination.

    Even if a wholesale boom or sprayer change is impractical, consider switching to steel boom lines and tanks tank to minimize residue carryover.

    As is often the case in the spraying business, prevention is easier and less costly than solving a big problem later. Spray mix storage is one of those examples where a small amount of extra effort at the beginning can pay big dividends later.