This 2023 article is based on work performed by Mike Schryver, BASF Technical Service Specialist.
Nitrogen is an essential nutrient required throughout a plant’s lifecycle. It is commonly applied to corn in either a granular form as urea or in a liquid form as urea-ammonium nitrate (UAN). Depending on soil type and precipitation, significant amounts of nitrogen can be lost to leaching, denitrification and volatilization as N2O (a greenhouse gas). Learn more about nitrogen in soil in this excellent overview by University of Minnesota Extension.
With the 2020 announcement of Canada’s Strengthened Climate Plan, Ontario is committed to a 30% reduction of 2020 N2O emission levels by 2030. Adding urease and nitrification inhibitors (aka stabilizers) to nitrogen fertilizer applications is an environmentally sustainable practice that reduces nitrogen losses and improves yield.
Another essential plant nutrient, Sulphur, is applied in liquid-form as ammonium thiosulphate (ATS). Primarily used to increase corn yields, high rates (approx. >10% by volume) of ATS can also inhibit urease and nitrification, albeit not as well as other nitrogen stabilizing options.
In the pursuit of productivity, UAN and ATS are often combined to serve as an herbicide carrier in corn weed-and-feed applications. However, liquid fertilizers are dense solutions that contain charged ions and exhibit a reduced capacity for solubilizing pesticides. This complicates the tank mixing process. When micronutrients like sulfur are added to nitrogen-based formulations, physical incompatibilities can arise that cause uneven applications and can even clog sprayers.
Given the known compatibility issues, questions have been raised about the best way to introduce urease and nitrification inhibitors to tank mixes of UAN, ATS and herbicide. Specifically:
Stabilizer Compatibility: What is the impact of adding nitrogen stabilizers to UAN carriers containing leading corn herbicides formulated as emulsifiable concentrates (EC) or suspension concentrates (SC)?
Mixing Order: When UAN and ATS are premixed, does their ratio, or the addition of nitrogen stabilizer affect tank mix compatibility with herbicides?
To answer these questions, we performed a series of jar tests.
Method
300 ml jars with magnetic stir bars were mixed to reflect a 10 gpa application. UAN was chilled to approx. -5°C and herbicides were added at 2x the labelled rate to simulate a worse-case scenario. Nitrogen stabilizer was added at a ratio per manufacturer’s instructions. Products were introduced at 1 minute intervals to provide sufficient time for solubilization. Jars were left to rest for at least 1 hour after mixing, and then agitated to simulate interrupted spray jobs. The solution was then poured through a 100 mesh screen to simulate a worst case scenario for sprayers that typical employ 50 mesh filters.
Herbicides
Fertilizer carriers
Stabilizers
Leading EC Herbicide
UAN: 28%
eNtrench NXTGEN (Corteva)
Leading SC Herbicide
ATS: 12-0-0-26% SU
Anvol (Koch)
Tribune (Koch)
Agrotain (Koch)
Neon Surface (NexusBioAg)
SylLock plus (Sylvite)
Excelis Maxx (Timac)
Table 1 Herbicides, carriers and stabilizers used in the study
Results
Stabilizer Compatibility
EC herbicides have active ingredients that are soluble in water and include immiscible solvents. When added at 2x label rate to chilled UAN, followed by a stabilizer, agitation created an acceptable suspension (Figure 1). The EC separated to the top of the mixture following an hour rest but was easily reintegrated. There was no appreciable residue left behind when poured through a 100 mesh screen.
Figure 1 UAN + EC Herbicide + Stabilizer after 1 hour rest. Image A is a control with no stabilizer and image B is the same control after agitation. The arrow indicates where ECs separate at the top of each jar. All products resuspended with agitation.
SC herbicides have active ingredients that are water insoluble, but stable in an aqueous environment. When added at 2x label rate to chilled UAN, followed by a stabilizer, agitation created an acceptable suspension (Figure 2). The SC flocculated and formed a sediment at the bottom of the mixture following an hour rest but was easily reintegrated. There was no appreciable residue left behind when poured through a 100 mesh screen.
Figure 2 UAN + SC Herbicide + Stabilizer after 1 hour rest. Image A is control with no stabilizer and image B is the same control after agitation. The arrow indicates where SCs settled, as depicted in the inset images showing the bottoms of each jar. All products resuspended with agitation.
Best Practices
Contact manufacturers and conduct a jar test to confirm compatibility
Ensure thorough agitation (with or without a stabilizer, and especially after tank has settled)
Components may separate to the top (ECs) or settle on the bottom (SCs)
Mixing Order
Mixing order was tested using chilled UAN, ATS, and EC herbicide. It is well known that ATS should be added last in the tank mix order, and mixes that include a higher load of ATS relative to UAN exacerbate tank mix issues.
This is seen in the following video where we combine 203 ml of chilled UAN, 30 ml of SC corn herbicide and 68 ml of ATS. On the left, UAN, then herbicide, then ATS mixes perfectly. However, when we start with UAN, then add ATS (which represents premixed fertilizer) then the herbicide does not suspend, and prolonged agitation does not improve the situation. The video is shown at 2x speed.
We then added a nitrogen stabilizer to the series to see if it could correct the tank mix issue arising from adding ATS immediately after UAN. This replicates the situation an operator would face when purchasing UAN and ATS premixed. We also reduced the ratio of UAN to ATS from 3:1, to 5:1 to 8:1 to establish a threshold ratio that alleviated tank mix issues (Figure 3). All solutions were poured through 100 mesh screens to capture residue (Figure 4).
Figure 3 SC Herbicide and stabilizer added to UAN and ATS premixed at different ratios. Agitated after 1 hour and poured through 100 mesh screens (inset images).Figure 4 Pouring EC jar test solutions through 100 mesh screens
Best Practices
Contact manufacturers and conduct a jar test to confirm compatibility
ATS must be added after the herbicide (EC or SC). The stabilizer can be added last, but preferably ATS is the last ingredient in the tank.
Adding stabilizer will not reverse a tank mix error arising from adding ATS prior to the herbicide.
The higher the concentration of ATS, the higher the risk of incompatibility. A 5:1 ratio of UAN to ATS failed while a ratio of 8:1 succeeded. The threshold is likely 7:1.
It’s common advice: Test your water before using it as a spray carrier. You dutifully sample the well or dugout and await lab results. And what comes back is a whole lot of numbers. How to make sense of it all?
Three examples of water test results conducted by labs in Canada
All three of these tests report a large number of properties and identify specific minerals and other solutes. Which ones are important in spraying? Here is the order in which I look at the numbers.
Conductivity: This property is usually expressed as micro Siemens per cm (µS/cm) and simply identifies how many ionic solutes are in a sample (watch for alternate units such as mS/cm and convert if necessary). It doesn’t differentiate between any minerals or other molecules, and therefore has limited information. But it does tell us if there is a large or small issue with water quality. If conductivity is below 500 µS/cm, the water is probably good for spraying. If the value is around 1000 to 2000, further investigation is necessary. Some water samples return conductivity of more than 10,000 µS/cm, and it’s important to identify which salts are causing that problem.
Note that Total Dissolved Solids (TDS) are often listed, and these are related to conductivity. A common way to get TDS is to multiply conductivity by 0.65. The conversion factor depends on which salts are dissolved but the bottom line is that TDS and conductivity are closely related.
Bicarbonate: Bicarbonates are HCO3 and their concentration is measured in milligrams per Litre (mg/L), which is the same as parts per million (ppm). Bicarbonates can antagonize Group 1 modes of action and the common threshold is 500 ppm. Research at NDSU has shown that Urea -Ammonium-Nitrate (UAN or 28-0-0 liquid fertilizer) can reduce bicarbonate antagonism in some Group 1 herbicides.
Bicarbonates are negatively charged and are associated with a positive ion, often the hard water cations sodium (Na), calcium (Ca) or magnesium (Mg). As such, waters that are high in bicarbonates are often also hard.
Total Hardness (calculated): This is one of the important parameters. Hardness antagonizes most weak acid herbicides, most importantly glyphosate and g;ufosinate, and also ties up surfactants and emulsifiers which can result in problems with mixing and compatibility. Hardness is caused by metal cations, in order of strength these are iron (Fe++), magnesium (Mg++), calcium (Ca++), sodium (Na+), and potassium (K+). Of these, Mg and Ca are typically most abundant, although some water is high in Na.
The Total Hardness (ppm) reported in water tests is done by taking the most common two cations, calcium and magnesium, and using this formula: 2.497*Ca + 4.118*Mg. Note that some tests report hardness in Grains per Gallon, in this case, multiply grains by 17.1 to get ppm.
While this calculation usually gives an accurate prediction of hardness, you may need to have a look at iron and sodium as well. Iron is less common, but some well waters are high in sodium or potassium. These minerals are not captured in the Total Hardness measurement. A water test low in Total Hardness may still be high in sodium, these are typically the samples with high conductivity.
The threshold for Total Hardness depends on the herbicide, its rate, and the water volume. The most common quoted values are 350 ppm for the lower rates of glyphosate (1/2 L/acre equivalent), and 700 ppm for the higher rates. Lower water volumes increase the concentration of herbicide, and reduce the impact of water hardness or bicabonates.
pH: This parameter is a bit over-rated because it is later affected by the herbicide and adjuvant dissolved in it. There is usually no concern with pH between 6 and 8, and water is rarely outside this range. It is best not to change the pH of water unless it is required on the label for mixing, because some products require low, and others require high pH for optimum solubility. Compatibility is an ever greater concern as our tank mix complexity increases.
Water Conditioners
The most common water conditioner is ammonium sulphate [AMS, (NH4)2 SO4]. In its pure form (21-0-0-24), a concentration of 1% to 2% w/v (8 to 17 lbs AMS/100 US gallons of spray water) solves most hard water and bicarbonate issues. Be cautious of using too much AMS (>3%), when added at high concentrations to some herbicides it can burn crops.
Research has shown that AMS works in two ways: The sulphate ion binds with hard water cations, forming an insoluble precipitate that prevents the antagonistic cations from binding to, and inhibiting, the herbicide. The ammonium ion has been shown to improve cellular uptake by weak ion herbicides.
Some product labels call for UAN as an adjuvant. UAN contributes ammonium, but not sulphate ions. As a result, while it may improve herbicide performance, it does not remove antagonizing cations from the mixture.
Acids have been used to combat hard water. Most common herbicides are weak acids, and the acid constituent, usually a carboxilic acid, has a unique pKa. The pKa is the pH at which half the molecules are protonated (contain a hydrogen atom, resulting in an uncharged acid constituent) and the other half are not protonated (negatively charged). If the spray mixture has a pH below the pKa, the weak acid herbicides become protonated. This means the herbicide becomes less water-soluble, but also that it has less chance of interacting with a hard water cation. Acids that work in this way are less effective at ameliorating the effect of hard water than AMS.
A small group of acids that includes citric acid and sufphuric acid can sequester or bind with hard water cations. But they do not contribute the ammonium ion that assists in weak acid herbicide uptake.
If your water is questionable for spraying, there are four common choices:
Select a different well or dugout
If the problem is barbonates or hardness, treat water with a conditioner such as Ammonium Sulphate (AMS), available in pure form as 21-0-0-24. Some acids (citric, sulfuric) can form conjugate bases with hard water cations, removing them from solution. But the associated significant lowering of pH should be treated with an abundance of caution as it may affect solubility of some pesticides.
Reduce water volumes or increase herbicide rates.
Use a municipal treated water source or invest in a reverse-osmosis (RO) system. RO is neither cheap nor fast and requires additional investment in storage, and a way to deal with solute-enriched waste water. But it may be the best option for some.
An Ammonium Sulphate calculator, originally developed by Winfield United using data from NDSU, can be downloaded here:
Much of this article is based on a session and tradeshow I attended at the 2026 Drone End-User Conference in Kansas City. I want to acknowledge the insightful information provided by the three session speakers, as well as the ~200 audience members that asked honest questions and shared their experiences. The speakers were Mr. Chase Plumer (Owner, ProBuilt Fabrication/ProDrone Spraying & Seeding, Seymour, IN), Mr. Klaytin Hunsinger (Owner, Hunsinger Ag Solutions, Rossville, IL) and Mr. Kyle Albertson (Owner, Albertson Drone Service LLC, Benton County IN).
Tendering systems
Drone-based crop protection is a rapidly growing industry and operator experience spans from novice to veteran. It follows that tendering systems are not a one-size-fits-all proposition. The best fit will be a configuration that is budget-conscious, reflects the size and nature of the operation, and accounts for future needs.
We can categorize them by their complexity, cost and capacity.
Entry-level tendering system: A starting point
For those just getting started, focus on affordability (lower initial investment) and simplicity (basic components). Examples include skid or truck builds, which are removeable or permanent systems that either rest on a vehicle bed or are built on-and-around the vehicle. This is an operator-friendly system that is small and portable for easy access to diverse fields. It’s the least durable configuration, and not particularly efficient or upgradeable, but it will serve until you know what you really need and how you like to work.
Mid-level tender system: Second year
By year two, you might want a larger and more efficient configuration with additional storage and a few creature comforts to reduce operator fatigue. A truck build might suit, but this is more likely a trailed system that is still capable of being towed by a mid-sized (1/2 to 3/4 tonne) truck. Some operators feel enclosing the trailer reduces efficiency, while others appreciate the security and protection afforded by defined spaces.
A mid level system has some capacity for modification, but isn’t designed to support multiple drones, and likely won’t have enough capacity to store a day’s worth of water, chemical, or fuel. The operator may wish to detach the truck to run for supplies. Or perhaps it makes more sense to run a truck with a skid-mounted tender system that trails a second, mid-level system to divide-and-conquer, or scale up for larger projects.
Beware going too big, too quickly. A 30-foot gooseneck can get caught on hilly terrain, where a 20-foot flat bed with a straight truck might be better suited. Small to mid-size trailers also take less time to set up and tear down. Consider performing site recon before dispatching a mid-level tender system. This is an additional step, but it allows the operator to scope out potential hazards and is ultimately more productive because it prevents tender systems getting stuck or placed in inefficient or unsafe locations. For example, if a client is “plant-out, pick-in”, the fields are hard to service because there’s no way to access them with large vehicles. Pilots become landscapers, spending valuable time clearing an operations area.
High-level tender system: Large scale and Commercial interests
Made for efficiency, the limiting factor of this system is the drone’s productivity. This category is comprised of the largest gooseneck trailers, which may include an upper deck and enclosed areas. It has the highest capacity for water storage, can service multiple drones and has ample storage. Intended for large fields, the size of this unit can make it physically incapable of reaching smaller fields. While a one tonne truck might be able to tow it, an even larger vehicle might be more suitable. It may also be prohibitively inefficient given the time required for setup and teardown. Consider an operator that requires a 15 minute start-up and a 15 minute teardown to spray 250 acres at 50 ac/hr; At $20/ac, that’s roughly $500.00.
Fundamentally, each tendering system has the same function, so they share the same basic components. Here’s an overview of common features and considerations.
Trailer
The trailer is (literally) the foundation of most tendering systems. Operators suggest building for your current budget but planning for future needs as best you can. Trailer size should reflect the nature of the farms you will be servicing and how best to access them. You should also consider the safest and most efficient workflow on and around the trailer before committing to a layout.
Option 1 – Utility trailer
Advantages
Disadvantages
Easy to get on/off
Low ground clearance
Less expensive
Narrow footprint for accessories (e.g. conventional tanks not fitting between wheel wells)
Versatile (use for drones on season, and other tasks off season)
Narrow if planning a top flight deck
May be an insufficient trailer GVWR (Gross Vehicle Weight Rating). This is the maximum allowable total weight of a trailer when fully loaded.
Option 2 – Flatbed gooseneck trailer
Advantages
Disadvantages
More room for accessories
Much heavier. ¾ tonne truck likely not sufficient.
Better ground clearance
Hard to get into tight places (length dependent).
Higher GVWR
Set up / Tear down takes longer
Potential for top flight deck. Typically, 102” wide, so top deck can be about the same.
Option 3 – Enclosed trailer
Advantages
Disadvantages
Protection from weather and elements
Limited clearance for large drones (e.g. 24’ long, 8.5’ wide)
Increased security for equipment
Highest GVWR
Could serve as mobile workspace / office
Most expensive
Cleaner environment for charging batteries, and generators don’t need maintenance (e.g. filters changed) as often.
Can get hot inside, both for people and battery overheating. Airflow on batteries is a necessity, and fans can only cool to ambient. Drone hasn’t got time to cool between fields.
Vehicle
Based on operator discussion, it seems many have a tendency to push their trucks to the limit… or beyond it. One operator uses a ¾ tonne truck to pull a 22-foot trailer with an upper deck. Another uses a 1 tonne (aka tonner) gas F350 which struggles to pull a 30-foot trailer. Others recommended the use of a single axle semi (e.g. a Kodiac or a Kenworth T300), which even used still has ample life left in it, and at ~15 to 17,000.00 USD is cheaper than buying a truck.
Consider that if you run a two-person operation, you may want more than one vehicle. A smaller truck can be employed to run for parts or fuel, or as previously noted can be fitted with a skid mount and a 1,300 gal. poly tank to split up the duty.
Tanks
Tank size(s) will depend on how you choose to operate, how many acres you plan to do in a day, and the weight capacity of your truck and trailer. Again, there is no one solution, so consider the following scenarios before you commit.
If you plan to hot load, perhaps you’ll just mix in a single, large tank. However, if you plan to switch between insecticides, fungicides and herbicides, one or two 100-gallon cone-bottom tanks with wash-down nozzles might make more sense. Then, you can carry clean water separately in a few repurposed IBC’s or go for the efficiency of a single, high-volume poly or stainless tank. Consider the most flexible and efficient arrangement.
Will you have access to water, will you have water tendered, or will you carry enough for the day? Will you fill from a 3-inch connector or suffer the lost time and fill with a garden hose? Will your truck and your trailer handle that weight, and will the vessel(s) fit between the wheel wells? Are the tanks black or shaded to prevent algae and do you have a plan to baffle the volume, so it doesn’t slosh when you drive over uneven terrain? Larger poly tanks (e.g. ~1,000-gallon tanks) have spots molded in to accept baffles, but some operators noted it’s difficult to install them after-market. Slosh suppressors such as floating balls or lengths of poly French drain can help.
Gas-powered pumps (e.g. Drummond or Predator transfer pumps) are relatively cheap, but some claim they have a high failure rate. This not only incurs downtime, but operators must deal with the chemical in the pump and lines during repair.
Electric may be a better choice, if only to avoid the noise and exhaust, and some operators run them continuously to recirculate chemistry when not filling a drone. Consider the horsepower, gallons per hour and head pressure, especially if you are pushing flow to an upper flight deck.
An AMT electric transfer pump on a mid-level tender system.
You should be able to fill a drone in about a minute. Some operators have begun increasing fill line diameter from 1-inch to 1.5-inch but feel 2-inch lines are too heavy to warrant the few seconds saved during filling. This may not be a limitation, however, if they are part of a top flight deck arrangement, and not dragged along the ground.
The auto shutoff function of a fuel-pump-style filler is preferred over a quarter-turn-style. The former contributes to foaming but some operators say that can be mitigated by using an anti-foam adjuvant and it’s less likely to create an overflow situation.
Perhaps a metered flow valve that shuts off once a predesignated volume has been dispensed would be a workable solution. This would preserve speed, but without foaming or potential overflows.
A loose line terminating in a quarter-turn valve fills quickly and with few bubbles, but is ultimately not ideal. It’s prone to causing overflows which increase the potential for operator exposure and cause point source contamination.A reeled hose and a fuel-pump style filler is a better approach. The hose can be recoiled to keep it from being underfoot, and the filler has a back pressure valve that shuts off when the drone is full. There is greater potential for foaming, but some suggest anti-foam adjuvants can help.
Generator
This proved to be a controversial subject at the conference. Many operators were unwilling to promote a single make or model, but the discussion resulted in some general guidance based on personal experiences. Generators will have a peak and a continuous performance rating. Ensure the sum total of all your draws does net exceed the continuous rating.
Drones are getting bigger, and the number of electrically powered devices on the trailer is increasing. Smaller operations tend to employ mobile gas generators that produce less than 10 kW. Larger operations reported using 30 kW (or more) diesel standby generators to charge two drones, plus accessories, while ensuring room for future growth.
A mobile gas generator (inverter or not) tends to be the cheaper, lighter alternative, depending on the wattage. They are a good choice for entry level systems and with regular maintenance will last longer, but are still a short-term proposition. Diesel generators tend to be more expensive, but are quieter, more fuel efficient and more reliable. A liquid propane standby generator is yet another option; Generally cheaper than diesel, consideration must be given to the weight and size of what is typically a 250-gallon propane tank.
A few points raised by operators during the discussion:
Most standby generators do not need diesel emission fluid, while mobile generators do.
Many operators prefer the durability of mobile generators over standby generators. The former is built to be moved while the later presents issues with brackets, mounts and stators.
Warranties are advisable for inversion generators, as they are not easily repaired.
Standby gas generators (10 kW continuous / 13 kW surge) may require you to downrate the battery charger, or the heat can trip the breakers. It is not advisable to bypass breakers.
Storage
Storage is often overlooked but can be critical to efficiency. For example, if you plan to spray six, 50-acre farms in a day and it takes 10 minutes for set up and 10 for tear down, that’s two hours gone. Consider what you’ll need and where you’ll need it, and place storage accordingly to minimize downtime. PPE should be located near your flight deck or filling area. You’ll also want to consider carrying spare parts, such as an electronic speed controller, motor, pump and a full set or rotors.
Batteries
Some battery chargers feature water baths, misters or air conditioning, but at bare minimum batteries should charge in the shade and in a ventilated area (e.g. not enclosed in a storage or tool box). One operator vented air from a commercial blower fan to the batteries on the top flight deck.
Connectivity
A hotspot on your cellphone doesn’t always provide reliable service. Satellite internet providers such as Starlink or Xplore (depending on your location) might be a solution. If the controller drops a direct signal to drone, it can bridge to satellite to connect to the SIM card in most drones. Operators that use this system advise it’s best to rent the hardware (if possible) so if something damages it, you get a free replacement. 100 gb of monthly roaming has proven more than enough for most operators.
Mounting solutions vary, but operators noted good experiences with companies such as Veritas Vans, which have a replacement policy. They warn against 3D printed options that tend to be produced using unsuitable filament materials. Operators that use magnetic mounts on their trucks have reported no issues. Some run wire through rear window or sliding door, and others pull the headliner down and run the power cord out through the third brake light.
Operator safety
Lastly but certainly not least, when it comes to the cost-benefit assessment of tender features, safety should always be a priority. Even simple comforts such as folding chairs combat operator fatigue, increase safety and happily also improve overall productivity. We’re none of us getting any younger.
RV awnings, umbrellas, foldable Bimini-style tops or flip-up doors provide shade. Switching to lower-decibel equipment (e.g. inverter gas generators run at about 90 decibels and electric pumps are even quieter), enclosing loud systems, or positioning them far from the filling area, reduce noise and emission exposure. Chemical drift and exposure during filling should be considered, and PPE should be used and stored in convenient locations.
Trailers that feature an upper flight deck sometimes include a central cable to tether belt harnesses. Stationary railings can help prevent falls, while a fold-up version provides clearance when backing the trailer into a shed.
The drones themselves are a hazard. Long flight decks keep landings and lift-offs at a safe distance, and a protected cockpit area improves matters. Decks with pull-out platforms or hydraulic wings can increase the operating area and can be adjusted to account for adjacent roads and the slope of the ground. A short rail around the landing area can prevent a drone from slipping off; A falling drone is expensive, but falling or sliding into an operator is a disaster. The simplest approach might be to operate on the ground.
An enclosed area for operators on a two-platform gooseneck trailer.Kodiak’s retractable flight deck on their skid-mounted system
Take home
The speakers left the session with some summary advice.
Trailer first, equipment second.
Build for today and tomorrow.
Function over form (stability, balance and access over appearance, bearing in mind that if it is a business, it can’t look terrible, either).
Efficiency from day one. Run a stopwatch (when the crew isn’t watching). Find and change the limiting factor, if it’s changeable. The right trailer improves efficiency even before the first acre is sprayed.
Thanks to the many speakers, attendees and trades people that contributed to this article. If you want to share pictures and specs for your tender system, let us know! If we get enough interest we’ll publish an article showcasing your tender systems so others can learn from your experience.
Celebrating 10 years of “thinking we’re funny”, Exploding Sprayer Myths is back with a new opening sequence!
Join cheesy game show host Wink Boomwobbly and his unsuspecting contestant Joe Mama as they discuss the factors that influence spray droplet fate. How do wind, travel speed, boom height and droplet size affect your pesticide application? Knowing how droplets respond to these forces makes the difference between coverage and drift. Brush up on your fundamentals in a fun way.
Long-suffering RealAgriculture editor Dr. Jay Strove has also hidden an Easter Egg photo so you can play along! Bonus points if you know where it was taken and who it is.
Thanks to our special guest from the UK, and be sure to stick around for the bloopers.
I work in agricultural extension and I’m always on the lookout for new methods to help me achieve my goals. A big part of my job is to research and teach efficient, effective and safe crop protection practices, so it follows that I have to be able to evaluate the quality of a spray application. Fundamentally, there are two ways to do it:
Wait to see if the pesticide did its job and protected the crop from weeds / bugs / disease.
Don’t wait. Confirm your spray is depositing where you want it before committing to the application.
Three guesses which approach I advocate. So, how do you check spray coverage in a way that’s quick, cheap, easy and informative? Again, there are choices, but rather than simply list them I’ll add a little insight in the form of pros and cons.
Reflects actual, whole-canopy coverage and off-target coverage at same time.
Expensive, hard to find, messy, time-consuming, hard to photograph, not repeatable, leaves unwanted residues (or can’t be used on edibles), may have to take place at night, may fade quickly… or is any of this actually true?
I’ve never been a proponent of spraying dyes because of the reasons I listed in the table. If I already have difficulty convincing a grower to leave the sprayer or tractor cab to place and retrieve water sensitive papers, what are the odds of them mixing a messy and expensive tank of dye and waiting until twilight to see the results?
On the other hand, dyes are compelling. Particularly if we change the perspective a little. What if we consider the use of dyes, not as a tool for a grower, but as a tool for agricultural extension or consultation (really, anyone that wants to research or teach the safe and effective use of crop inputs)? Several of the cons are minimized or even eliminated. Additionally, this new lens reveals several uses for dyes beyond spray coverage. This is not an exhaustive list:
Off-target (primarily drift) evaluation
Dermal exposure / PPE evaluation
Rinsate / sprayer cleanout evaluation
Sprayer loading / point source contamination evaluation
I decided to compare a few of these dyes. I enlisted the help of a local blueberry operation. Being October, all the berries have been picked so we could spray the bushes without any risk to the fruit. Plus the sprayer was clean and the growers were curious to evaluate their spray coverage.
Blueberry in Ontario in October.
Having secured a location, spray equipment, and operator, I needed dyes and some criteria for choosing them. First and foremost, I chose fluorescent dyes that glowed under UV (aka black lights). My thinking was that they would be more interesting in demos, and given that we might be spraying horticultural operations, I didn’t want obvious and persistent stains on the produce. At least not something easily seen in daylight before it broke down and/or was washed away.
My UV dye candidates had to be:
Moderately inexpensive.
Non-toxic (i.e. had an SDS that clearly permitted human exposure, were environmentally friendly and could be sprayed on edible crops).
Readily available in Ontario (e.g. quickly and cheaply shipped from within Canada or perhaps the US).
Available in formats that facilitated small volume batches (anywhere from 50 mL squirt bottles for indoor demos, up to 50 L volumes for field demos).
Clearly visible on plant tissue.
I found five likely prospects for the study. I won’t list prices, but none of them were over $100.00 CAD. Number 3 was a free sample and number 5 was gifted to me by a colleague more than 15 years ago. I looked up the SDS for that last one and was surprised that it was relatively inert. So, I used it.
I also purchased UV lights. When I was bequeathed the phosphor powder it came with heavy, ancient, black lights. They made an unsettling humming noise and required a power source, making them unwieldly for field work. I opted to try three battery powered versions instead. Again, I won’t list prices, but they weren’t unreasonable.
UV flashlight number
Name of light
Manufacturer
Wavelength / wattage
Batteries
1
Super Tac
Risk Reactor
395 NM / 850 µW/cm2 at 5 inches
Rechargeable battery provided
2
Mini Zoom
Risk Reactor
395 NM / 1 watt
1 AAA
3
V3 UV Flashlight with 68 LEDs
Amazon.ca
395 NM / 10 watts
3 AA
Regarding the recipes, one of my criteria was that the dyes could be mixed in relatively small batches. I chose 50 L as the high end because the airblast sprayer we were using (Turbo-Mist 30P) could still prime when only 50 L was added to the tank. This allowed us to mix as small a batch as possible, while still having enough to spray a row of berries from both sides. We left three rows between treatments to serve as buffers.
Turbo-Mist Model 30P before the dye-job.
I also had to consider the nature of the dyes. The Eco Pigment (Dye 3) is a hydrophobic powder and two colleagues warned me that it was notorious for plugging filters. So, it had to be mixed with a non-ionic surfactant (NIS) to help “wet” the powder prior to adding it to the tank. In fact, NIS seemed like a good idea for all my dye candidates, so I included Activate Plus (Sollio Agriculture, Winfield Solutions) in each recipe.
The candidates.
I added the dye, NIS, and a small amount of water to a Pyrex measuring cup on a digital scale, then rinsed the cup into a final volume of 50 L while filling the tank. I didn’t always follow the advice I received, so I’ll show you the ratios I was told and (right or wrong) what I ultimately did.
Dye number
Manufacturer- or colleague-suggested ratio
Amount of dye
Amount of NIS
Amount of water
1
1 part dye : 10,000 parts water
125 mL
65 mL
310 mL
2
1 part dye : 10,000 parts water
125 mL
65 mL
310 mL
3
1 gram dye : 1 mL NIS : 200 L water
65 grams
65 mL
425 mL
4
1 part paint : 100 parts water
500 mL
65 mL
0 mL
5
1 gram dye : 1.25 L water
65 grams
65 mL
425 mL
It took roughly 15 minutes to fill, prime, spray, and rinse out each dye. We started at 5:00 p.m., were done at 6:15, and then waited for sunset at 7:30.
50 L tank mixes going through circulation and paddle agitation.Draining the remains and rinsing the tank. It looks terrible, but these dyes are intended for environmental projects like tracing water courses.
We used a smartphone (Google Pixel 9a – 48 megapixel camera) to photograph each combination of dye and flashlight. It was tricky to find an angle where the black light illuminated the residue, but didn’t wash out the photo. In those cases where the dye was evident, it was always far more vibrant in person than through the lens of a camera. As for the results?
Lets start with the lights. We found that the high wattage of Light 3 showed dye more easily. This also happened to be the cheapest light, which was a pleasant surprise.
Dye 1 and 2 were disappointing. We couldn’t see anything on the plants. This dye is intended for monitoring plumbing and water courses, and the manufacturer states that the colour will disappear if the solution is mixed with chlorine. Perhaps mixing it with city water caused it to fade, but that’s likely to happen, so these dyes failed.
Dye 1 – Light 1, 2 and 3. A sad, single drop showed up for Light 3.Dye 2 – Light 1, 2 and 3. Again, a solitary deposit illuminated under Light 3.
Dye 3 was spectacular. Not only was it evident with every light source (including day light to some extent), but we were able to find it several rows downwind, on the sprayer nozzles, all over the tires and on the floor of the cab (which surprised the operator). I may have mixed this one too strong; It seemed to clump on the leaves, but perhaps that’s because they were exceptionally waxy.
Dye 3 – Light 1, 2 and 3.Dye 3 showed up everywhere… whether we wanted it there or not.A nice close up of Dye 3 on a leaf.A close up of Dye 3 on the boom.
Dye 4 came in second place. It wasn’t amazing, but it was visible. This is children’s tempera paint, used in daycares for finger painting and at universities for raves. I’ve used it in the past with mixed results, not only to spray canopies, but in classroom demos on cabbage leaves and as a surrogate tracer to hunt down where pesticide hides in sprayer plumbing. It’s OK in a pinch if you mix it at least 2x more concentrated than I did here.
Dye 4 – Light 1, 2 and 3.A nice close up of Dye 4 on a leaf.
Dye 5, like dyes 1 and 2, was a disappointment. I’ve seen it used in powder-form to demonstrate how dermal exposure can spread as you touch clothing, doorknobs, your face, and places where the occasional adjustment is required. But in a liquid solution, it wasn’t any good at all.
Dye 5 – Light 1, 2 and 3
Persistence
We followed up after the application to see if the dyes would persist. Twenty four hours after application, Dye 4 (our runner-up) was gone. This was no surprise given it was a water soluble paint and wasn’t terribly showy to begin with. However, Dye 3 (our winner) was still clearly in evidence. This is a hydrophobic, micro ground powder (~0.1 micron). That’s one reason it had to be mixed with a non-ionic surfactant. The following photos shows little or no change after 24 hours and a respectable dew:
Dye 3 after 24 hours.
Three days after application (DAA), we had a rain event. Four DAA this (blurry, sorry) image was taken:
Dye 3 after 96 hours and a heavy rain.
We see that the deposits did redistribute to drip points and the overall coverage was reduced, but it was still holding on. This means it likely shouldn’t be used on any horticultural crop that isn’t going to be washed. Or at least used long before any fruit, leafy green or vegetable contacted by the powder will be harvested. Not because it is unsafe (see safety data sheet) but because of the optics to buyers.
Conclusion
And so, I hope you have been inspired by this process. I’ve learned that the use of dyes for education and research is potentially powerful, relatively cheap, and more accessible than I originally thought. Certainly the growers were impressed by what they could suddenly see and it’s led them to reassess some of their practices. Just bear in mind the possible persistence, and remember to wear gloves when mixing.
Wear gloves. Trust me.
Thanks to Mark Ledebuhr, Helmut Spieser, David Manktelow, and Ben Werling for the helpful advice. Thanks to Brandon and Jordan Falcon for use of their spray equipment and their blueberry operation.
