Category: Mixing

Articles about mixing and pesticide in horizontal boom sprayers

  • Operator Safety: How to Avoid Pesticide Hazards

    Operator Safety: How to Avoid Pesticide Hazards

    A Veteran Applicator’s Questions about Pesticide Handling

    Time and again, after years of working with dozens of different chemicals, I would wonder to myself “How dangerous is this chemical?”, “Is glyphosate as safe as they say it is?”, “How do I find out what type of safety gear I need while handling this chemical?”

    Beyond the agrichemical dealer, ag. consultants, and university or government ag. extension specialists, a quick internet search reveals many sources of pesticide information. Collectively they identify the active ingredient(s) in formulated products, they detail which pests are best controlled by the pesticide, and they provide instruction for application. But it’s more difficult to find consistent, practical information about safe pesticide handling. Sometimes it’s excessive to the point of being impractical (try finding actual “chemical proof” gloves), and sometimes it’s minimal and vague – it depends where you look. No matter the level of precaution, pesticide safety is time consuming and involves some fussing, but it is the hallmark of responsible pesticide use. Just as we ensure that we are applying “safe rates” when spraying chemicals, we must also ensure we are respecting our own well-being while handling chemicals.

    In Canada, the Pesticide Regulatory Directorate (PRD) is charged with protecting human health and safety by monitoring pesticides that are sold in this country. According to the Federal Pest Control Products Act all pesticides sold in Canada must be registered with the PRD. There’s a very nice overview of how that process works here. It is during this registration process that pesticide handling precautions are identified for the label. Further classification may take place under provincial acts.

    All pesticides are designed to disrupt, repel, control or kill living organisms, but when it comes to safe handling, insecticides receive the most attention. This is because herbicides and fungicides target biochemical pathways that only exist in plants or fungi. However, most pesticides can be hazardous if they are not handled correctly. The handling precautions that appear on the label are based on five factors.

    Five factors that affect handling precautions:

    1. Pesticide Family

    This factor is the broadest way to categorize potential risk to the handler. Generally, herbicides and fungicides are considered safer than insecticides, but there are notable exceptions. Do not rely solely on the pesticide family when making decisions on pesticide handling.

    2. Pesticide Mode of Action

    The mode of action gives further detail into how a pesticide should be handled. Modes of action that inhibit biochemical pathways that exist in the target pest, but not in mammals (people, in particular), have lower acute toxicities. Examples include herbicides that inhibit enzymes involved in amino acid synthesis or in photosynthesis – these enzymes do not exist in mammals. However, once again, there are always exceptions. Do not rely solely on mode of action when making decisions on pesticide handling.

    3. Pesticide Formulation & Route of Entry

    Pesticide formulation affects how a product can potentially be absorbed into the body. Emulsifiable Concentrates (ECs), for example, have higher rates of absorption than solutions or dry products. When it comes to the route of entry, dermal contact is considered safer than inhalation or ingestion. However, not all parts of your skin are created equal, and the point of dermal contact on the body matters a great deal.

    4. Pesticide Toxicity

    Taken collectively, the first three factors form the overall toxicity of the pesticide. The level of toxicity cannot be predicted – it has to be tested. The LD50 (defined below) values that are reported for a pesticide come from standardized experiments such as animal feeding. Although the chosen species (usually white rats for mammalian endpoints) are known to be similar to humans in their response, there is still the possibility of error. Nevertheless, toxicity forms an important basis for establishing handling precautions.

    5. Operator Exposure

    People handle toxic substances every day. Household bleach, for example is surprisingly toxic, and yet it can be readily found on kitchen shelves in many homes. The risk of being harmed by a toxic product can only be determined by the likelihood of exposure. While it is possible someone might accidentally consume a hazardous dose of bleach, it’s improbable. Exposure does not just refer to a single exposure to a substance – repeated exposures to small doses of a toxic substance can have a cumulative effect. The goal when handling any pesticide is to minimize exposure, but it becomes even more critical when that pesticide is highly toxic. Together, exposure and toxicity form the basis for risk.

    Risk = Hazard x Exposure

    Studies have shown that exposure is greatest for handlers of agricultural pesticides during the mixing and loading phase of spraying. During this phase, the risk to the handler may be increased due to:

    • physical stress
    • the denial of risk
    • a negative opinion of personal protective equipment (PPE)

    The main method of pesticide exposure is dermal, and many of the surfaces on a piece of equipment are already contaminated.

    Health effects of pesticides: Acute and Chronic

    Acute: short term

    High exposure, resulting in immediate reaction due to a high dosage of pesticide exposure. The severity depends on the toxicity of the molecule and entry into the body (dermal, oral, eyes, etc.). The most common acute reaction is skin irritation, although in certain cases respiratory, digestive, and neurological systems may be affected. Organophosphate (e.g. Lorsban, Malathion) and carbamate (e.g. Sevin, Lannate) insecticides inhibit the cholinesterase enzyme, which is found in humans and affects nerve function. Frequent users of these insecticides undergo regular blood tests to ensure their levels are normal.

    Chronic: long term

    Chronic affects are more prolonged as they are usually due to lower doses of pesticide exposure over a longer period of time. Although some rare cancers and disruption of the reproductive system have shown to be related to this type of exposure, when the general population and farming population have been compared in studies, the farming population has shown an under-representation in the majority of cancers. In the cases were reproductive malfunctions were observed, a different cause of the malfunction, such as genetic offset, was most often observed in these situations. However, cancer types such as skin cancer and brain cancer were overrepresented in the farming community. A study in France has shown that the onset of neurological disorders in Agriculture communities shows a strong connection between Parkinson’s disease and exposure to pesticides.

    Label Information

    The majority of information needed to safely handle pesticides is found on the label. Pesticide labels are legal documents, meaning they can be enforced by the federal government. The problem is that most sprayer operators rarely look at the label as they are not very reader friendly and easy to skim through. Most pesticide boxes even have the recommended rate, or acres/case on the side of the box now, so there is even less reason to look at the label.

    LD50– the dose of pesticide in mg per kg of the test animals body weight that is lethal to 50 percent of the group of test animals.  For example, if the pesticide has an acute oral LD50 value of 1000 mg/kg, and the test animals each weigh 1 kg, then 50 percent of the animals would die if they each ate 1000 mg of pesticide at once.  A 100 kg animal would need to ingest 100,000 mg (100 g) of the pesticide for the same effect.  LD50 is often expressed by the route of entry – dermal, inhalation, acute oral (ingestion) are the main examples.

    Degree of Risk and Hazard Symbols
    Degree of Risk and Hazard Symbols

    Two Factors that Determine the Appropriate Level of PPE

    1. The Hazard Rating (above) incorporates the minimum protection generally required for a substance with the rating.
    2. The Label Recommendations will usually give the additional specific protective clothing and equipment needs for an applicator.

    Degree of Exposure

    This increases as the length of each pesticide application increases. As the number of pesticide applications increases, the time between exposures decreases. If an operator becomes exposed to spray, dust or fumes the degree of exposure increases. Essentially, more protective wear is needed as the degree of exposure becomes greater.

    Knowledge

    This encompasses all of the above information. In order for a pesticide applicator to avoid injury or the chances of adverse effects on the body, a pesticide applicator must be knowledgeable about pesticides. It can be overwhelming for an applicator to sort through all of the information on the label or on-line regarding pesticides. So much so, that most often applicators avoid the information altogether. Ongoing training and learning will ensure that they are effective in their work. Many aspects of pest control change continuously, as new studies are conducted on the effects of pesticide exposure.

    A Safety Data Sheet (SDS) is available for each pesticides registered, and these are usually linked on manufacturers’ websites. It can be eye-opening what types of toxicity tests are done, and what the results are.

    Denial that pesticides can potentially cause harm is also a major flaw in the behaviour of applicators. Maintaining a safe work environment and practicing personal safety will reduce the chances of an applicator experiencing serious injury throughout their farming career.

    Unknowns

    There is very little certainty in toxicology. For one, most testing is done using acute oral and dermal dosing. Basically, toxicologists expose test animals to the neat active ingredient and watch what happens. There is a lot of missing information – what about formulant like solvents, and surfactants? What about synergies in tank mixes? Some, but not all of these, undergo testing. We also have much less information on chronic (long-term) effects, and can only simulate these in quasi long-range tests. In addition, toxicological methodologies and statistical approaches can vary, and we should not be surprised that some reports disagree, and that there are outright conflicts between toxicologists and epidemiologists (scientists that study patterns of health in populations). Regulators are aware of these shortcomings and often use safety factors to account for them. But those of us that use these products regularly, the message is simple: be cautious, and protect yourself.

    Avoid Cross-Contamination

    Disposable nitrile gloves are the product of choice for handling pesticides. But one of the most common problems with the use of gloves is cross-contamination. You’re handling product with your gloves on, touching containers, hoses, valves, and couplers. When you’re done, you climb back into the cab where you take off your gloves. Later, someone climbs up into the cab to talk to you, using the railing and operating the door handle without gloves. Guess what’s on their hands? Even later, you put away the hose without gloves and return to the sprayer. Now it’s on the steering wheel and all the levers. There are a few solutions:

    • Double-glove so you can take the dirty outside glove off and still be protected.
    • Wipe down surfaces that you might touch with gloved or bare hands daily.
    • If using non-disposable gloves, avoid lined gloves and rinse the insides out daily.

    Learn More

    If you would like to learn more about pesticide safety, or to obtain pesticide application training, the Pesticide Applicator License can be obtained from the Ministry of Agriculture. This course offers in depth, valuable safety information for applicators, as well as general knowledge for pesticide applicators. The Pesticide Regulatory Directorate provides workers, employers, and the general public with a wide range of pesticide information. The PRD can be contacted from anywhere in Canada toll free at: 1-800-267-6315

    Download this Quick Reference Guide for commonly used herbicides. Print, laminate and post it at the fill station or pesticide storage area for easy reference. Also, grab a copy of Health Canada’s “Stay Safe when using Pesticides” factsheet.

    Sources

  • Sprayer Loading and the Jar Test

    Sprayer Loading and the Jar Test

    The time and attention spent during sprayer loading is a worthy investment. It ensures that the products in the tank perform as intended and reduces the chance of incompatibilities.

    The label

    Pesticide labels are always the first point of reference. Labelled mixing instructions should be obeyed even if they contradict conventional practices (see Mixing order, below). Consult this article on tank mix compatibility for more information on how to quickly and easily consult labels for each of your tank mix partners.

    The carrier

    Typically, the carrier is water, and understanding its role in pesticide performance is another article (or several). We’ve provided some links here for further reading.

    • Take some time to read Les Henry’s 2016 Grainnews article called “The Coles Notes of Water Chemistry“.
    • You can also read about pH and water hardness. It should be noted that pH and the resultant hydrolysis that can affect product half-life is typically an insecticide issue (not fungicide or herbicide). The famous fungicide example is Captan, which has a half-life of 32 hours at pH 5, but only 10 minutes at pH 8. Michigan State did a great summary (in 2008 and on US product formulations) which you can find here.
    • Finally, learn how to read a water quality report, here.

    Carrier volume

    Products dissolve better in higher volumes. The sprayer tank (vat, inductor, etc.) should be at least ½ full or water before adding the first product. In the case of a fertilizer carrier, it may look like water, but it contains high levels of salts that tie up free water and reduce solubility. For fertilizers, a higher initial volume of ¾ full is required.

    Note the undissolved residue collected on these swatches of red filter material. Products dissolve faster and better in higher carrier volumes.

    The incomplete dissolution of products can leave hard-to-clean residues, plug fluid lines, and result in a non-uniform application that reduces efficacy. The risk of incompatibility is greater with low carrier volumes and high product rates (especially dry formulations). This is a common problem in regions that use low water volumes to apply multiple tank mix partners.

    Carrier and product temperature

    Both carrier and product temperature affect mixing. Imagine mixing sugar in hot tea versus iced tea – more sugar dissolves more quickly in hot liquid. Here are three common temperature-related issues:

    • Dry formulations and liquid flowables take more time to disperse (consider using a pre-mixed slurry).
    • Emulsified concentrates and oil might form gels rather than milky blooms.
    • Water soluble packages might not dissolve completely and could plug filters and nozzles – or clog the pump intake.
    Note the undissolved residue collected on these swatches of red filter material. Products dissolve faster and better when carrier and products are warmer.

    Note: Water and fertilizer are very different carriers. Beware of carrier-specific incompatibilities

    Agitation

    Keep agitation running throughout mixing and spraying. Aim for a “simmer” on the liquid surface rather than a “rolling boil.”

    Low agitation can cause products to settle, making them difficult or impossible to resuspend later. Conversely, aggressive agitation (especially in half-full tanks) can cause foaming, pump suction loss, or product separation / clumping.

    Pace

    Adding products too quickly can cause product separation / clumping or poor suspension, leading to tank mix incompatibilities. While loading quickly improves operational efficiency, complex mixes require patience; Sometimes over five minutes between additions, especially in cold water or when using dry products.

    To save time without sacrificing quality, consider pre-hydrating dry products or using a separate nurse tank to pre-mix loads for quick transfer. Remember: even if dry products look dissolved, they may still need more time.

    Product formulation

    Product formulation is a complicated science. In the 1950s a formulation might have three active ingredients and an inert filler. See the historic formulation index card shared by Dr. M Doug Baumann (formally with Syngenta, Honeywood).

    Today, a product can include as many as 40 ingredients with formulation testing lasting two to four years! Generally, only 25% of the volume is water, 50% is active ingredients and the remaining 25% is co-formulants. This is why the more products you add to the tank, the higher the risk of antagonism. This is also why operators should carefully consider the cost benefit of generics, which may include the active ingredient, but do not tend to include the co-formulants.

    Illustration based on a slide by Dr. Samantha Francis, Formulation & Application Technology Lead at the Syngenta Honeywood Research Facility.

    Mixing order

    Tank mixing order is critical for chemical compatibility. While common acronyms like w.w.w.W.A.L.E.S., W.A.M.L.E.G.S., and A.P.P.L.E.S. serve as reliable guides 95% of the time, always defer to the pesticide label for specific instructions.

    Expanded generic mixing order:

    1. Water: Fill tank 1/2 full (or 3/4 if fertilizer carrier).
    2. Agitation
    3. Water-Soluble Bags (WSB): Allow to fully dissolve.
    4. Wettable Powders (WP)
    5. Water Dispersible Granules (WDG, WG, SG)
    6. Liquid Flowables (F, FL, SC, SE, CS, DC, EW)
    7. Emulsifiable Concentrates (EC, MEC, OD)
    8. Solutions (SN, SL, Liquid Fertilizers/Micronutrients)

    Adjuvants:

    1. Water Conditioners (e.g. anti-foamers, compatibility agents): Add before pesticides.
    2. Activator Surfactants (e.g. NIS, COC): Add after pesticides or by formulation type along with pesticides.
    3. Drift Retardants: Add last.

    Examples of mixing errors

    Micronutrients like sulfur (e.g. ATS) added to nitrogen-based formulations (e.g. UAN) can cause physical incompatibilities. This became a problem during “weed-and-feed” applications in Ontario corn in the late 2010s, and working with the registrants, we found a solution.

    What follows is not only a good example of why mixing order is critical, but why growers should get into the habit of performing jar tests. Learn more about a real-world ATS example here.

    Left: ATS and UAN premixed, followed by Primextra created curds.
    Centre: UAN, followed by low-load ATS followed by Primextra worked.
    Right: UAN followed by Primextra followed by high-load ATS worked.

    Mixing errors are just as likely in small plot work as in commercial sprayers. Watch this short video by Mike Cowbrough describing his experience with mixing order for Elevore and glyphosate.

    The jar test

    A jar test is a small-scale version of tank mixing used to check for physical incompatibility. Always wear PPE and work in a well-ventilated area away from ignition sources.

    Jar test steps:

    1. Prepare: Read all labels for formulation details, water quality requirements (pH/hardness), and mixing order. Shake liquid containers to ensure consistency.
    2. Initial Carrier: Fill a 1-litre glass jar with 250 ml of water (or 375 ml if using oil/fertilizer).
    3. Add Products in Order: Add chemicals following the standard mixing sequence, stirring constantly. Scale rates to match your tank concentration (e.g., 1 kg per 1,000 L equals 0.5 g in a 500 ml test).
    4. Wait and Observe: Allow 3–5 minutes between additions—especially for dry products—to ensure full dispersion. If testing water-soluble bags, include a small piece of the film.
    5. Final Volume & pH: Top the jar up to 500 ml with your carrier. Check the pH with a digital meter and add adjusters if required by the label.
    6. Evaluate: Let the jar stand for 15 minutes.

    The mix is likely incompatible if it generates heat, forms gels or scum, or if solids settle out (excluding wettable powders). Note: Jar tests only identify physical issues; they do not guarantee biological efficacy or crop safety.

    Compatibility kits

    When performing a jar test you must maintain the same product-to-carrier ratio as in a full-sized sprayer tank. This math is made easier with commercial compatibility kits such as the one from Precision Laboratories (below).

    Compatibility Test Kit: Five pipettes, three bottles, gloves, instructions. ~$10.00. (Photo: Precision Laboratories)

    Such kits contain a few plastic “jars” and disposable micropipettes. By following the instructions included with the kit, you can easily reduce large labelled volumes (e.g. 1 kg of product in 1,000 litres) of multiple products to small volumes at the same ratio. In this case we assume the final volume would have been 1,000 L, and so we reduce all the quantities accordingly to get 500 ml. The following mixing order is provided as an example.

    OrderIngredientQuantity for 500 ml or 500 g of product labeled for 1,000 L of final spray volume
    1Compatibility agents5 ml (1 teaspoon)
    2Water soluble packets, wettable powders and dry flowables. Include a 1cm2 cutting of PVA packaging.15 g (1 tablespoon)
    3Liquid drift retardants5 ml (1 teaspoon)
    4Liquid concentrates, micro-emulsions and suspension concentrates5 ml (1 teaspoon)
    5Emulsifiable concentrates5 ml (1 teaspoon)
    6Water-soluble concentrates or solutions5 ml (1 teaspoon)
    7Remaining adjuvants and surfactants5 ml (1 teaspoon)

    Records and delayed reactions

    Maintain detailed mixing records for traceability and to track performance. These records help you replicate successes and avoid future failures.

    Labelled jar tests are also valuable; by leaving them in the chemical shed overnight, you can see if products separate or solidify over time. This indicates whether a mix can safely sit in the sprayer or if it requires immediate rinsing. For example, one grower’s Enlist and Manzinphos mix appeared fine until it sat during a rain delay. It turned into “lard,” clogging the entire system and requiring a manual teardown. They even had to dig some of the substance out with screwdrivers (see the picture of the filter below). An overnight jar test likely would have predicted this problem.

    Some physical incompatibilities are not immediately apparent. This occurred overnight while the partially-full sprayer waited out a rain event.

    Closed transfer

    As a brief mention, an expansion of closed transfers systems for loading pesticides is on the horizon in North America. They have great potential to make loading more efficient, reduce operator exposure and reduce point-source contamination. Depending on the design, however, the operator may not be able to open pesticide containers to obtain samples for jar testing. This would be a great loss.

    For more information

    Learn more about physical and chemical incompatibility in our article on Tank mix compatibility. Be sure to download a copy of Purdue University’s 2018 “Avoid Tank Mixing Errors”. Finally, if you have questions about a specific product, contact the manufacturer, who have likely already performed the testing with common tank mix partners and can advise you.

    This article was co-written with Mike Cowbrough, OMAFA Weed Management Specialist – Field Crops

  • Cleaning Your Sprayer

    Cleaning Your Sprayer

    We all know the importance of cleaning out a sprayer. It protects a sensitive crop. It protects people working with the sprayer. It protects the sprayer and its components. But cleaning the sprayer is a pain. Here are some tips to make it easier.

    Some herbicide label instructions are cumbersome, requiring many flushes with full tanks of water. Many applicators look for shortcuts and hope they get away with it. It doesn’t have to be guesswork. The following is a checklist that may help.

    Be Prepared

    A few supplies can help ensure a clean sprayer tank.

    • A defoaming agent saves water and time
    • A cleaning agent (commercial products, or simple household ammonia) is useful, and recommended, for Group 2 products except the imidazolinones.
    • A supply of clean water, preferably with its own pump, and a pressurized spray hose helps clean the sprayer inside and out.
    • A wash-down nozzle (whose flow requirements can be met by the clean water pump) can automate the tank wash-down.
    • A bucket and brush for rinsing screens is very useful.

    Products to Watch:

    The products most frequently implicated in sprayer contamination are two members of the Group 2 modes of action: the sulfonyl ureas (e.g., thifensulfuron (Refine) and tribenuron (Express)), and the triazolopyrimidines (e.g., florasulam (Frontline, PrePass) and pyroxsulam (Simplicity)). Since these herbicides dissolve better at higher pH, proper cleanout usually requires ammonia, a weak base that raises the solution pH. The third member of Group 2 products, the imidazolinones (imazethapyr (Pursuit), imazamox (Solo, Odyssey), imazamethabenz (Assert), imazamox (Ares,  Adrenalin, Altitude or Viper)), tend not be implicated in as many residue issues, and don’t require ammonia for cleanout.

    Be Prompt and Thorough

    Remove pesticide from mixing and spray equipment immediately after spraying – it makes the job easier. The main areas of concern are the tank wall, sump, plumbing (including boom ends), and filters. First, spray the tank completely empty while still in the field. It’s sometimes OK to cover previously sprayed areas – all herbicides must be crop-safe at twice the label rate to be registered by the PMRA. Take care with residual products that may create problems down the road. Reduce the rate or choose a fallow field to be certain. Second, add 10 x the sump’s remnant of clean water, circulate, ensuring agitation is on, and spray it out in the field as well. Repeat. These two rinsing steps will take care of the majority of the cleaning and won’t take very long. The less remaining volume there is in your tank after the pump draws air, the less water is needed to dilute this remainder to an acceptable concentration. Having a clean water tank on the sprayer and a wash-down nozzle makes this job easier.

    Visual Inspection

    Herbicide residue may precipitate out of solution in some parts of the sprayer or plumbing. A thorough visual inspection can identify these problem areas and ensure that they are cleaned properly.

    Tank Wall

    Removal of residues from tank walls is best accomplished with a direct, pressurized spray. Make sure all parts of the wall have been in contact with clean water. Use a wash-down nozzle if it provides complete and vigorous coverage of the interior tank surface.

    Sump

    Empty the sump as completely as possible by spraying it out. Any spray liquid or herbicide concentrate remaining in the sump area will be re-circulated in the sprayer. The only way to remove any remaining herbicide is through dilution by repeatedly adding water, and leaving as small a remainder as possible.

    Plumbing and Boom

    Plumbing can be a significant reservoir of herbicide residue. Removal from plumbing can be achieved by pumping clean water through the boom while ensuring that all return and agitation lines also receive clean water and all residue is flushed out. This may require opening and closing various valves several times, and repeating the process with new batches of clean water. Boom ends can extend up to 6” beyond the last nozzle at each end of each boom section. These ends must be flushed to removed trapped residue. A useful product that does this automatically is the Pentair Hypro Express Nozzle Body End Cap, or better yet, consider recirculating booms.

    Dilution

    The most effective use of a volume of rinse water is to divide it equally across several repeat washes. Assuming a 10 gallon sump remainder, three washes with 30 gal each are as effective as two washes with 70 gallons each, and equal a single 600 gal wash.

    It’s even more efficient to use a separate clean water pump, introducing clean water as the rinsate is sprayed out. This saves water and time, and results in even more dilution.

    Filters

    Nozzle screens and in-line filters can be a significant reservoir for undiluted or undissolved herbicide and are one of the most overlooked parts of sprayer decontamination. Remove all filters and nozzle screens and thoroughly clean these with fresh water. Run clean water through plumbing leading to the screens.

    Nozzle Bodies

    Nozzle bodies can harbour herbicide mixture. When cleaning a spray boom, rotate through all nozzles in a multiple body to ensure clean water reaches all parts of these assemblies. Remove screens that may have been used with herbicide.

    Tank Cleaning Adjuvants

    Adjuvants such as ammonia can assist the tank decontamination process, especially with sulfonyl urea and triazolopyrimidine-containing products. Ammonia does not neutralize herbicides, but it does raise the pH of the cleaning solution which helps sulfonyl urea herbicides dissolve. When decontaminating after an oily (EC) formulation, the use of a wetting agent such as AgSurf will assist in removing oily residue that may trap SU herbicide on tank and hose material. Commercial tank cleaning products that contain ingredients for removing persistent deposits are available.

    Tank and Boom Material

    Both plastic and stainless steel are common tank and wet boom materials, and both can be cleaned using the above procedures.  However, stainless steel is easier to clean, and this means that less time may be required. Consider the choice of materials a productivity factor in your next purchase or upgrade decision.

    Rinsate Disposal

    Always spray out the tank in the field. Do not drain the tank while stationary unless you are certain it is free of pesticide and that you are away from sensitive areas and waterways. Consider a continuous rinse system. Consider building a biobed for safe disposal of dilute pesticide waste.

    Sprayer cleanout will probably never be the easiest job on the farm. But looking at it in a smarter way can prevent frustration and save time.

  • Tank mixing Urease and Nitrification Inhibitors in Corn Weed-and-Feed Applications

    Tank mixing Urease and Nitrification Inhibitors in Corn Weed-and-Feed Applications

    This 2023 article is based on work performed by Mike Schryver, BASF Technical Service Specialist.

    Nitrogen is an essential nutrient required throughout a plant’s lifecycle. It is commonly applied to corn in either a granular form as urea or in a liquid form as urea-ammonium nitrate (UAN). Depending on soil type and precipitation, significant amounts of nitrogen can be lost to leaching, denitrification and volatilization as N2O (a greenhouse gas). Learn more about nitrogen in soil in this excellent overview by University of Minnesota Extension.

    With the 2020 announcement of Canada’s Strengthened Climate Plan, Ontario is committed to a 30% reduction of 2020 N2O emission levels by 2030. Adding urease and nitrification inhibitors (aka stabilizers) to nitrogen fertilizer applications is an environmentally sustainable practice that reduces nitrogen losses and improves yield.

    Another essential plant nutrient, Sulphur, is applied in liquid-form as ammonium thiosulphate (ATS). Primarily used to increase corn yields, high rates (approx. >10% by volume) of ATS can also inhibit urease and nitrification, albeit not as well as other nitrogen stabilizing options.

    In the pursuit of productivity, UAN and ATS are often combined to serve as an herbicide carrier in corn weed-and-feed applications. However, liquid fertilizers are dense solutions that contain charged ions and exhibit a reduced capacity for solubilizing pesticides. This complicates the tank mixing process. When micronutrients like sulfur are added to nitrogen-based formulations, physical incompatibilities can arise that cause uneven applications and can even clog sprayers.

    Given the known compatibility issues, questions have been raised about the best way to introduce urease and nitrification inhibitors to tank mixes of UAN, ATS and herbicide. Specifically:

    1. Stabilizer Compatibility: What is the impact of adding nitrogen stabilizers to UAN carriers containing leading corn herbicides formulated as emulsifiable concentrates (EC) or suspension concentrates (SC)?
    2. Mixing Order: When UAN and ATS are premixed, does their ratio, or the addition of nitrogen stabilizer affect tank mix compatibility with herbicides?

    To answer these questions, we performed a series of jar tests.

    Method

    300 ml jars with magnetic stir bars were mixed to reflect a 10 gpa application. UAN was chilled to approx. -5°C and herbicides were added at 2x the labelled rate to simulate a worse-case scenario. Nitrogen stabilizer was added at a ratio per manufacturer’s instructions. Products were introduced at 1 minute intervals to provide sufficient time for solubilization. Jars were left to rest for at least 1 hour after mixing, and then agitated to simulate interrupted spray jobs. The solution was then poured through a 100 mesh screen to simulate a worst case scenario for sprayers that typical employ 50 mesh filters.

    HerbicidesFertilizer carriersStabilizers
    Leading EC HerbicideUAN: 28%eNtrench NXTGEN (Corteva)
    Leading SC HerbicideATS: 12-0-0-26% SUAnvol (Koch)
    Tribune (Koch)
    Agrotain (Koch)
    Neon Surface (NexusBioAg)
    SylLock plus (Sylvite)
    Excelis Maxx (Timac)
    Table 1 Herbicides, carriers and stabilizers used in the study

    Results

    Stabilizer Compatibility

    EC herbicides have active ingredients that are soluble in water and include immiscible solvents. When added at 2x label rate to chilled UAN, followed by a stabilizer, agitation created an acceptable suspension (Figure 1). The EC separated to the top of the mixture following an hour rest but was easily reintegrated. There was no appreciable residue left behind when poured through a 100 mesh screen.

    Figure 1 UAN + EC Herbicide + Stabilizer after 1 hour rest. Image A is a control with no stabilizer and image B is the same control after agitation. The arrow indicates where ECs separate at the top of each jar. All products resuspended with agitation.

    SC herbicides have active ingredients that are water insoluble, but stable in an aqueous environment. When added at 2x label rate to chilled UAN, followed by a stabilizer, agitation created an acceptable suspension (Figure 2). The SC flocculated and formed a sediment at the bottom of the mixture following an hour rest but was easily reintegrated. There was no appreciable residue left behind when poured through a 100 mesh screen.

    Figure 2 UAN + SC Herbicide + Stabilizer after 1 hour rest. Image A is control with no stabilizer and image B is the same control after agitation. The arrow indicates where SCs settled, as depicted in the inset images showing the bottoms of each jar. All products resuspended with agitation.

    Best Practices

    • Contact manufacturers and conduct a jar test to confirm compatibility
    • Ensure thorough agitation (with or without a stabilizer, and especially after tank has settled)
    • Components may separate to the top (ECs) or settle on the bottom (SCs)

    Mixing Order

    Mixing order was tested using chilled UAN, ATS, and EC herbicide. It is well known that ATS should be added last in the tank mix order, and mixes that include a higher load of ATS relative to UAN exacerbate tank mix issues.

    This is seen in the following video where we combine 203 ml of chilled UAN, 30 ml of SC corn herbicide and 68 ml of ATS. On the left, UAN, then herbicide, then ATS mixes perfectly. However, when we start with UAN, then add ATS (which represents premixed fertilizer) then the herbicide does not suspend, and prolonged agitation does not improve the situation. The video is shown at 2x speed.

    We then added a nitrogen stabilizer to the series to see if it could correct the tank mix issue arising from adding ATS immediately after UAN. This replicates the situation an operator would face when purchasing UAN and ATS premixed. We also reduced the ratio of UAN to ATS from 3:1, to 5:1 to 8:1 to establish a threshold ratio that alleviated tank mix issues (Figure 3). All solutions were poured through 100 mesh screens to capture residue (Figure 4).

    Figure 3 SC Herbicide and stabilizer added to UAN and ATS premixed at different ratios. Agitated after 1 hour and poured through 100 mesh screens (inset images).
    Figure 4 Pouring EC jar test solutions through 100 mesh screens

    Best Practices

    • Contact manufacturers and conduct a jar test to confirm compatibility
    • ATS must be added after the herbicide (EC or SC). The stabilizer can be added last, but preferably ATS is the last ingredient in the tank.
    • Adding stabilizer will not reverse a tank mix error arising from adding ATS prior to the herbicide.
    • The higher the concentration of ATS, the higher the risk of incompatibility. A 5:1 ratio of UAN to ATS failed while a ratio of 8:1 succeeded. The threshold is likely 7:1.
  • Spray Water pH

    Spray Water pH

    The scuttlebut on coffee row is that acidifying a spray mixture improves its efficacy. There are also claims that pesticides break down in the sprayer tank if the pH is too high.

    But it’s not that simple. Low pH has a strong impact on pesticide solubility, and that means mixing and cleanout are affected. Acidifying the mixture can have profound negative effects for many products.

    It’s important to know what you’re doing.

    What is pH?

    pH is defined as the negative log of the molar concentration of hydrogen ions in a water-based solution. The more abundant the hydrogen, the lower the pH. It’s a log scale, so every unit of pH refers to a 10-fold change in the concentration of hydrogen ions.

    Both very low (acidic) or very high (basic) pH can be caustic. But having a low or high pH doesn’t mean it will burn your skin or clothes right away, it might just be a bit unpleasant. But at the extreme ends, protection is needed.

    Why is pH Important in Spray Mixtures?

    In spraying, the main effect of pH is on the pesticide’s solubility. Solubility matters when mixing and becomes important during cleanout as well.

    A minor effect on pH, at least for herbicides, is on chemical breakdown, usually through hydrolysis, when the pH is too high. The effect on breakdown is rarely meaningful during any given spray day, but may play a role if a spray mix is stored overnight or longer.

    The Basics: Strong vs Weak Acids

    Strong acids like hydrochloric acid (HCl) ionize completely in solution. When added to water, only H+ and Cl– are present, there is no HCl. The water’s pH does not affect solubility of a strong acid.

    But weak acids do not completely ionize. The water pH affects the degree of ionization and therefore solubility.

    Most herbicides are weak acids. A weak acid is one that does not dissociate completely in solution. A typical example of a weak acid functional group is carboxylic acid (-COOH). In solution, compounds with a carboxylic moiety exist in an equilibrium, with some as -COOH (containing the hydrogen, also called “protonated”) and others as -COO– and H+. In the dissociated form, the acid is more water soluble than in its protonated form due to the negative charge that makes it ionic.

    Weak acids have a dissociation constant known as the pKa. When the solution is at the molecule’s pKa, the acid is 50% dissociated. When the solution has a lower pH than the pKa, there is less dissociation and the protonated forms of the molecule dominate. That has two important implications for herbicides.

    • the molecule becomes less water-soluble at lower pH
    • the molecule has fewer opportunities to interact with positively charged items

     pH Dependent Solubility

    Water-solubility is a two-edged sword. On the one hand, having a highly water soluble product makes it easier to dissolve in water. This pays dividends when mixing a batch or cleaning a sprayer because a product formulated as a solution will easily go into a true solution and will stay mixed. Examples are glyphosate, glufosinate, and salts of 2,4-D, MCPA, and dicamba.

    On the other hand, most pesticides need to enter a plant to reach their site of action. And a plant cell, with its waxy cuticle and oily membranes, creates an effective barrier for water, and for water-loving molecules dissolved in it. As a result, a formulation that allows the water-soluble product to interact with an oily barrier is needed.

    The products that can do this are surfactants. Acting like detergents, surfactants have regions in their structure that are oil-loving (lipophilic) and other regions that are water-loving (hydrophilic). Surfactants can therefore bind to both oil and water and provide a bridge for water-soluble products across oily barriers.

    That’s also one of the reason that the most water-soluble products such as glyphosate and glufosinate contain a lot of surfactants in their formulation, reducing the concentration of active ingredient in the jug and possibly leading to foaming with agitation.

    Pesticides have a wide range of solubilities, and for some, water pH will play an important role. Below is a table of some water solubilities of selected herbicides.

             Solubility (ppm)
    Trade NameActive IngredientMode of Action GrouppH ~ 5pH ~ 7pH ~ 9
    Selectclethodim1535,45058,900
    Ally 2metsulfuron25502,800313,000
    Expresstribenuron2482,04018,300
    Pinnaclethifensulfuron22232,2408,830
    Everestflucarbazone244,00044,00044,000
    Simplicitypyroxsulam21632,00013,700
    Frontlineflorasulam20.1694
    Varrothiencarbazone2172436417
    Raptorimazamox2116,000 >626,000>628,000
    Pursuitimazethapyr22,570 12,8707,500
    2,4-D2,4-D salt429,93444,55843,134
    dicambadicamba salt4>250,000>250,000>250,000
    Roundupglyphosate9>500,000>500,000>500,000
    Libertyglufosinate10>500,000>500,000>500,000
    Heatsaflufenacil14302,100 >5000
    Distinctdiflufenzopyr19635,90010,550
    Infinitypyrasulfatole274,20069,10049,000

    Compare the solubility at pH 7 to that at pH 5. For most of these herbicides, water solubility is worse at lower pH. That is because they are more protonated and become more lipophilic.

    I’ve placed a lot of Group 2 products in this table because those products are most often implicated in tank cleanout issues. All Group 2 products in this table, with the exception of Everest (flucarbazone-sodium) have lower solubility at pH 5 than they do at pH 7. For some, like pyroxsulam and floarsulam, it’s a big change. Those products, when acifified, are prime candidates for poor mixability and poor cleanout.

    When it comes to dicamba, low pH has another side-effect. It makes the molecule more volatile, increasing danger to sensitive plants nearby. For that reason, acidification of dicamba in its Xtendimax and Engenia formulations is not permitted.

    Note that the Group 4 examples, 2,4-D salt and dicamba salt, as well as glyphosate and glufosinate, are highly water-soluble and pH has very little effect on that.

    Particularly for glyphosate, the claim that it becomes more oily at low pH and will therefore be taken up more easily, is not supported by these data. Considering that the most acidic pKa for glyphosate (it has four acidic groups) is 0.8, pH would need to be much lower for any noticeable impact on oilyness.

    Tank Mixability

    Given today’s environment of herbicide resistance, applications with multiple mode of action tank mixes are very common. Acidifying a spray mix to benefit one herbicide may create problems for its tank mix partners.

    If there is a concern that spray water is too alkaline, it is recommended that the pH of the finished spray mix be measured. Since many herbicides are weak acids, they will lower the pH of the mixture by themselves. For example, the addition of glyphosate to water with pH 7.5 will drop the pH to about 5 or so, depending on the water’s buffering capacity.

    As a result, glyphosate tank mix partners that are pH sensitive may suffer in the presence of glyphosate, and pH may actually need to be raised.

    pH Dependent Half-life

    Herbicides

    There are a lot of claims that pesticides break down rapidly in alkaline spray water. And yet, in my career working primarily with herbicides, I do not recall this ever being a problem in practice.

    Below is a table of herbicides for which I could find half-life information, with the help of this comprehensive list produced by Michigan State University.

    ProductActive ingredientHalf Life
    AtrazineatrazineMore stable at high pH
    BanveldicambaStable at pH 5 – 6
    BromoxynilbromoxynilpH 5 = 34 d; pH 9 = 1.7 d
    Fusiladefluazifop-p-butylpH 4.5 = 455 d; pH 9 = 17 d
    Libertyglufosinate-ammoniumStable over wide range of pH
    GramoxoneparaquatNot stable at pH above 7
    ReglonediquatpH 5 = 178 d; pH 7 = 158 d; pH 9 = 34 d
    MCPAMCPApH 9 = < 5 days
    PoastsethoxydimStable at pH 4.0 to 10
    PrincepsimazinepH 4.5 = 20 d; pH 5 = 96 d; pH 9 = 24 d
    ProwlpendimethalinStable over a wide range of pH values
    RoundupglyphosateStable over a wide range of pH values
    TreflantriflularinStable over a wide range of pH values
    2,4-D2,4-DStable at pH 4.5 to 7

    Note that all of the herbicides are relatively stable. Some are a bit less stable at high pH, but none of the listed herbicides is in danger of breaking down on the day it is being applied. Only one is actually unstable at high pH – paraquat, a herbicide no longer registered in Canada and resticted in many other countries. Those with short half-lives experience them at quite high pH which are rarely seen in practice.

    Insecticides

    Insecticides are a different story. Several are very sensitive to pH. This table is again adapted from a comprehensive list published by Michigan State University, here.

    Trade NameActive IngredientHalf-life
    AdmireImidaclopridGreater than 31 days at pH 5 – 9
    Agri-MekAvermectinStable at pH 5 – 9
    AmbushPermethrinStable at pH 6 – 8
    AssailacetamipridUnstable at pH below 4 and above 7
    AvauntindoxacarbStable for 3 days at pH 5 – 10
    Cygon/LagondimethoatepH 4 = 20 hrs; pH 6 = 12 hrs; pH 9 = 48 min
    CymbushcypermethrinpH 9 = 39 hours
    DiazinonphosphorothioatepH 5 = 2 wks; pH 7 = 10 wks; pH 8 = 3 wks; pH 9 = 29 days
    Dipel/Forayb. thuringiensisUnstable at pH above 8
    DyloxtrichlorfonpH 6 = 3.7 days; pH 7 = 6.5 hrs; pH 8 = 63 min
    Endosulfanendosulfan70% loss after 7 days at pH 7.3 – 8
    FuradancarbofuranpH 6 = 8 days; pH 9 = 78 hrs
    Guthionazinphos-methylpH 5 = 17 days; pH 7 = 10 days; pH 9 = 12 hrs
    KelthanedicofolpH 5 = 20 days; pH 7 = 5 days; pH 9 = 1hr
    LannatemethomylStable at pH below 7
    LorsbanchlorpyrifospH 5 = 63 days; pH 7 = 35 days; pH 8 = 1.5 days
    Malathiondimethyl dithiophosphatepH 6 = 8 days; pH 7 = 3 days; pH 8 = 19 hrs; pH 9 = 5 hrs
    Matadorlambda-cyhalothrinStable at pH 5 – 9
    Mavriktau-fluvalinatepH 6 = 30 days; pH 9 = 1 – 2 days
    MitacamitrazpH 5 = 35 hrs; pH 7 = 15 hrs; pH 9 = 1.5 hrs
    OmitepropargiteEffectiveness reduced at pH above 7
    OrtheneacephatepH 5 = 55 days; pH 7 = 17 days; pH 9 = 3 days
    PouncepermethrinpH 5.7 to 7.7 is optimal
    PyramitepyridabenStable at pH 4 – 9
    Sevin XLRcarbarylpH 6 = 100 days; pH 7 = 24 days; pH 8 = 2.5 days; pH 9 = 1 day  
    SpinTorspinosadStable at pH 5 – 7; pH 9 = 200 days
    Thiodanendosulfan70% loss after 7 days at pH 7.3 to 8
    ZolonephosaloneStable at pH 5 – 7; pH 9 = 9 days

    Among insecticides, dimethoate, amitraz, and malathion stand out as breaking down rapidly in alkaline water. For these products in particular, it may be important to acifify the spray mix if there is any delay in spraying.

    Recommendations

    I’ve never been a fan of messing with solution pH unless recommended on the product label. Even when there is evidence that lower pH improves efficacy, consider the impact on tank mix partners.

    We’ve seen improvements in solubility and tank cleranout of Group 2 products with raised pH, and ammonia is the most cost-effective way to achieve that. But again, following label recommendations is strongly recommended. The consequences of changes in pH, particularly acifification, can be very detrimental. To be safe, consider doing a jar test before committing to a whole tank to a pH adjustment.