Tag: mix

  • Circulating Spray Mix Through a Tank-Rinse Nozzle Maintains Nematode Concentration

    Circulating Spray Mix Through a Tank-Rinse Nozzle Maintains Nematode Concentration

    This article was co-written with Jennifer Llewellyn, former OMAFA Nursery Crop Specialist

    With more and more bio-rational products on the market, crop protection methods may require reassessment. Certain products require exacting water quality, cannot tolerate residues, and have half-lives that are both time- and temperature-critical. We’ve been getting questions about sprayer compatibility with some of these new products, so it seemed like a good opportunity to recycle this article from 2013.

    Many horticultural commodities, such as turfgrass and nursery crops, include the application of live nematodes as part of their annual IPM program. We performed preliminary research into the claim that a grower’s nematode applications were becoming less effective. In the course of the investigation it was discovered that the nematode concentration (i.e. dose) sampled from the spray nozzle was diminishing over the course of the application.

    (A) Tank-rinse assembly mounted through tank lid with a flow-regulating valve. (B) Close up of tank-rinse nozzle.
    (A) Tank-rinse assembly mounted through tank lid with a flow-regulating valve. (B) Close up of tank-rinse nozzle.

    After eliminating potential sinks in the sprayer’s plumbing (e.g. filters, strainers, etc.) it was hypothesized that the nematodes were adhering to the interior of the poly tank. If this was the case, the concentration would drop as the level of spray mix dropped. To test the hypothesis, we installed a tank-rinse nozzle to sparge the inner walls of the tank throughout the application and to re-suspend any stranded nematodes.

    A high capacity roller pump (Pentair series 1700C) was installed to operate the tank-rinse nozzle (Pentair Proclean Tankwash) during spraying. It was installed through a bulkhead fitting in the tank fill lid. During testing it was discovered that the tank-rinse nozzle shunted too much flow and pressure to maintain flow to the spray gun. A valve was installed behind the tank-rinse nozzle to restrict flow to the point where it gently rinsed the inner walls of the tank, restoring flow and pressure to the spray gun.

    (A) Installing a high-capacity roller pump. (B) Tank-rinse nozzle, with valve, installed through tank lid. (C) Control manifold installed to plumb the return, the tank-rinse nozzle, spray gun and boom. (D) The entire installed system.
    (A) Installing a high-capacity roller pump. (B) Tank-rinse nozzle, with valve, installed through tank lid. (C) Control manifold installed to plumb the return, the tank-rinse nozzle, spray gun and boom. (D) The entire installed system.
    (A) Nematodes, as-shipped, in a sponge. (B) Suspending nematodes for tank mixing.  (C) Counting nematodes. (D) Undiluted, healthy nematodes in a stock solution via microscope ocular.
    (A) Nematodes, as-shipped, in a sponge. (B) Suspending nematodes for tank mixing.
    (C) Counting nematodes. (D) Undiluted, healthy nematodes in a stock solution via microscope ocular.

    The 200 L tank was inoculated with a stock solution containing 25 million nematodes (125 nematodes / ml). 20 L of the spray solution was sprayed into a bucket every 10 minutes, whereupon 1 L of spray solution was immediately removed and 1 ml volumes were sub-sampled for counting.

    In the first trial, nematode counts continued over a period of 2 hours and viability dropped by ~40%. It was assumed the damage was caused by prolonged circulation through the roller pump. In subsequent trials, the sampling duration reduced to 10 minutes (more realistically reflecting the time it took the grower to apply 200 L in the field). The tank was rinsed and re-inoculated for each trial. 1 ml samples were drawn from the spray gun, which operated continuously, with and without the tank rinse nozzle in operation.

    Univariate analysis confirmed data normality and a GLM procedure was conducted for analysis of variance. Results indicate that nematode concentration dropped by ~15% without tank-rinse with minimal nematode damage observed. With the tank-rinse nozzle engaged, the concentration still declined slightly, but significantly less (<5%) (see graph below).

    Nematode concentration over time for each condition.
    Nematode concentration over time for each condition.

    The results suggest that a tank-rinse system that sparges the tank walls preserves nematode concentration throughout an application and may lead to more efficacious applications.

    Horticultural Crops Ontario, Ground Covers Unlimited, Pentair (Hypro) and Nemapro are gratefully acknowledged for making this research possible.

  • Tank Mix Compatibility

    Tank Mix Compatibility

    Tank mixing is the practice of combining multiple registered agricultural products in the sprayer tank for application in a single pass.

    The Pros of Tank Mixing

    • Efficiency: If the timing makes sense, a single pass saves time and reduces trample/compaction. E.g. A “weed-and-feed” application of fertilizer and herbicide in corn.
    • Resistance management: Multiple modes of action help prevent resistance development and combat existing problems.
    • Improved performance: Labels may require adjuvants to condition carrier water or reduce drift (utility adjuvants) or to improve the degree of contact between droplets and the plant surface, or enhance product uptake or rainfastness (activator adjuvants).
    Prowl meets Roundup – A beautiful photo by Peter Smith, University of Guelph

    The Cons of Tank Mixing

    Tank mixing requires caution and careful investigation. Should tank mix partners prove to be incompatible, the consequences can be subtle or dramatic, but are always negative. There are two kinds of incompatibility.

    1. Biological or Chemical Incompatibility

    This form of incompatibility may not be immediately apparent following an application. Some level of crop damage or impaired efficacy occurs, which may impact yield or warrant an additional “clean-up” application. This is the result of product synergism or antagonism.

    Synergism (Crop damage)

    When products synergize, the application becomes too potent. For example, an adjuvant could affect crop retention or uptake, exposing it to more active ingredient or overwhelming crop metabolism. The result is damage to the crop we are trying to protect.

    Antagonism (Reduced efficacy)

    When products antagonize, the application becomes less potent. There are several examples:

    • pH adjusters in one product may reduce the half-life of another product (e.g. The fungicide Captan has a half-life of 3 hours at a pH of 7.1 and only 10 minutes at a pH of 8.2.)
    • Active ingredients may get tied-up on the clay-based adjuvants in other products (e.g. glyphosate tied up by Metribuzin).
    • One product changes the uptake/retention of another. For example, a contact herbicide burns weed foliage beyond its ability to take up a lethal dose of systemic herbicide.

    2. Physical Incompatibility

    Physical incompatibility affects work rate and efficacy. Products form solids that interfere with, or halt, spraying. It can also make sprayer clean-up more difficult. For example, weak-acid herbicides lower the pH of the spray mix, reducing the solubility of Group 2 herbicides (i.e. imidazolinones, sulfonylureas, sulfonanilides). The oily formulation then adheres to plastic and rubber surfaces in tanks, connectors and hoses.

    There are many forms of physical incompatibility:

    • Liquids can curdle into pastes and gels that clog plumbing to such an extent that flushing cannot clear it and a manual tear down is required.
    Clogged screens
    • Dry formulations don’t hydrate or disperse, becoming sediment that clogs screens and nozzles. Even if they are small enough to spray, they reduce coverage uniformity. For example, a dry product added behind an oil gets coated, preventing it from hydrating.
    • Certain product combinations may cause settling, or one partner is more prone to settling. If the sprayer sits without agitation, settled products may or may not resuspend. Even if they do resuspend in the tank, they may remain as sediment in lines.
    Residue in hoses – Photo courtesy of Fred Whitford, Purdue University
    Clay-based products may or may not resuspend easily in a tank. Even then, they may not resuspend in plumbing lines.
    • Certain product combinations may cause foaming, or one partner may be prone to foaming, causing overflows or breaking pump suction. When products foam, dry products added through the foam may swell, preventing hydration.
    The Foamover Blues
    • Phase separation occurs when products layer in the tank. Consider oil and water. Even with agitation, the active ingredients may not be uniformly suspended in the tank and coverage uniformity will be reduced during spraying.
    Salad dressing left to rest is a great example of separation and stratification (left). Agitation helps emulsify it (right)

    Due Diligence – Preventing Tank Mixing Errors

    Incompatibility is often a function of the inert ingredients in pesticide formulations (e.g. thickeners, adjuvants, defoamers, stabilizers, solvents, etc.) and not the active ingredients. The more products you add to the tank, the more likely you’ll encounter an issue. It is prudent to perform a jar test to confirm physical compatibility. Remember, even if registered tank mix partners support mixing, your pace, mixing order, and water quality/temperature could cause issues.

    Do not decide to try a new-to-you registered tank mix during loading. Even if you’ve used these products successfully in the past, formulations change without notice. Plan as much as possible off season when there is time to do the following:

    Consult the pesticide labels

    Pesticide labels are always the first point of reference. They should be obeyed even if they contradict conventional practices. Booklet-style labels that come with the products are long, difficult to search and may not be up-to-date.

    In Canada, it is faster and easier to go to the PMRA Label Search website and search labels in PDF format. In other countries, consult the manufacturer’s website for label information. For each tank mix partner, use <CTRL>+F to find the following keywords:

    • Do Not Mix
    • Mix
    • Hours
    • Agitation
    • Fertilizers

    Consult manufacturer and crop advisors

    You’re likely not the first to consider a certain tank mix. Learn from those that have been there already:

    • Consult your chemical sales representative. They know their products best and want to see you succeed. They may have insight that is not found on the product label.
    • Consult local government or academic extension programs for an unbiased opinion.
    • Enlist the help of a professional crop advisor.

    It is a good practice to get tank mix recommendations in writing. If something should go wrong, liability is an important concern.

    If you’ve made a mess – The Reverse Jar Test

    It happens. We’ll use this real-world situation as an example:

    “I mixed up a batch of MCPA 500 A and Glyphosate at ¾ recommended label rate, but then got delayed on application with a stuck drill. I came back to the sprayer and found a nasty chemical precipitate – like waxy chunks. Agitation didn’t break them down. I dumped the tank out as I didn’t want to pump it through the booms. How do I clean up the chunks in the system?”

    We forwarded this question to ag chemists Dr. Eric Spandl (Land of Lakes) and Dr. Jim Reiss (Precision Laboratories) and developed this response:

    “Wearing appropriate personal protective equipment, physically remove the “chunky” material. A lot of time can be wasted (and rinsate water created) by experimenting with various concoctions, but if you do choose to try a compatibility agent, first try it in a mason jar. If it works to dissolve the material, it can be added to the tank with water and agitated. If not, you are down to manual cleaning: hot water under pressure.”

    We dubbed this process “The Reverse Jar Test”. Do not add hot water, cleaners or compatibility agents until the reverse jar test confirms success. You may create a larger problem. Of course, the best advice is to not put yourself in this position to begin with. Once again, don’t make mixing decisions at the inductor bowl – make them before ordering product.

    Tank mixing regulations in Canada (January, 2025 update)

    The following legislative framework is specific to Canada, so readers in other countries should consult their own regulatory authorities.

    Paragraph 6(5)(b) of the Pest Control Products Act (PCPA) states that no person shall use a pest control product in a way that is inconsistent with the directions on the label. In 2020, a public consultation was held to consolidate and clarify tank mixing requirements. This led to Regulatory Proposal PRO2020-01 (Streamlined Category B Submissions and Tank Mix Labelling – July 3, 2020). Essentially, it stated that tank mixing would be allowed if there was text on the product label that specifically permitted it. This could be a specific tank mix combination, a general statement permitting mixing, or both.

    A new general label statement that permits tank mixing was proposed to consolidate tank mixing information in one place on the label and allow greater flexibility in terms of tank mixing options. The prohibition against tank mixing products with the same mode of action was removed, and the reference to tank mixing with a fertilizer is now an optional component of that statement. The general label statement reads as follows:

    “This product may be tank mixed with (a fertilizer, a supplement, or with) registered pest control products, whose labels also allow tank mixing, provided the entirety of both labels, including Directions For Use, Precautions, Restrictions, Environmental Precautions, and Spray Buffer Zones are followed for each product. In cases where these requirements differ between the tank mix partner labels, the most restrictive label must be followed. Do not tank mix products containing the same active ingredient unless specifically listed on this label.

    In December of 2022, Health Canada released a guidance document describing the federal tank mixing policy. This document is not part of the PCPA, but is an administrative document intended to facilitate compliance by all stakeholders. Registrants have until December, 2025 to update their extension material to align with amended product labels and guidance documents. Similarly, users of pest control products will be provided the same transitional period to adjust their purchasing and production practices to align with the provisions of this document. This means the policy will be in full effect on December , 2025. After that, applicators in Canada can only apply tank mixes that appear specifically on a product label, or tank mixes of products whose labels include the new general tank mixing statement.

    Summary of the guidance document

    Tank mixing is not permitted when a potential tank mix partner’s label has some exclusionary statement, such as:

    • Forbidding mixing. E.g. “Do not mix or apply this product with any other additive, pesticide or fertilizer except as specifically recommended on this label.”
    • Limiting tank mixes to only those specifically listed on the product label.

    During the label transition, guidance relating to tank mixing may be found under a section specific to tank mixing, and/or under other sections as in the following examples:

    • Directions for use: E.g. “When tank-mixes are permitted, read and observe all label directions, including rates and restrictions for each product used in the tank-mix. Follow the more stringent label precautionary measures for mixing, loading and applying stated on both product labels.”
    • Buffer Zones: E.g. “When tank mixes are permitted, consult the labels of the tank-mix partners and observe the largest (most restrictive) spray buffer zone of the products involved in the tank mixture and apply using the coarsest spray (ASABE) category indicated on the labels for those tank mix partners.”
    • Resistance Management: E.g. “Use tank mixtures with [fungicide/bactericides/insecticides/acaricides] from a different group that is effective on the target [pathogen/pest] when such use is permitted.”

    If there are no directions on the labels, don’t tank mix them.

    If your situation does not fit these examples, the following table (Appendix A at the bottom of the Guidance Document), lists several other examples examples of different tank mix wording scenarios for registered pest control products.

    Table 1: Permissibility of tank mixing based on various combinations of label statements related to tank mixing

    Product X label saysProduct Y label saysCan I tank mix? (Y/N)
    Nothing (silent on tank mixing)Nothing (silent on tank mixing)N
    General tank mix statementNothing
    (silent on tank mixing)
    N
    Nothing (silent on tank mixing)General tank mix statementN
    General tank mix statementGeneral tank mix statementY
    General tank mix statementTank mix with Product XY
    Tank mix with Product YGeneral tank mix statementY
    Tank mix with Product YNothing (silent on tank mixing)Y
    Nothing (silent on tank mixing)Tank mix with Product XY
    Tank mix with Product YTank mix with Product XY
    Tank mix with Product YExclusionary statement (and label does not include a specific Product X tank mix)N*
    Exclusionary statement (and label does not include a specific Product Y tank mix)Tank mix with Product XN*
    *There may be registered labels that have tank mix scenarios like this. Note that this is not allowed for new tank mix label amendments. Further, any product labels that have tank mix scenarios like this must be amended to alleviate the contradictory scenario. To do this, using the last scenario in Table 1 as an example, one of the following must occur: 1) remove the Product X tank mix from the Product Y label, 2) remove the exclusionary statement from the Product X label, or 3) add a specific tank mix for Product Y on the Product X label. Source: PMRA Guidance Document Tank Mix Labelling 2023

    Tank mixing adjuvants

    According to the PMRA, the rules surrounding the tank mixing of adjuvants remain the same as they have been since 2009, and are not included under the new guidance document. While the PCPA does not reference adjuvants specifically, they are prescribed to be pest control products in the regulations (Pest Control Products Regulations s.2(b)). The general reference in the PCPA that applies is s.6(5)(b).

    Therefore, in the case of activator adjuvants, the label for at least one tank mix partner must specify the use of an adjuvant, and only registered adjuvants labeled for the crop and for tank mixing are permitted. For example, tank mixing the herbicide Reflex with a registered soybean oil adjuvant not labelled for the use, or with an unregistered food grade activator adjuvant, would not be acceptable. Utility adjuvants have registration numbers, but their use is not prescribed or specified on pesticide labels, leaving their use to the discretion of the operator.

    For more information on Canada’s Tank Mixing Policy

    For more information, please contact Health Canada’s Pest Management Information Service.

    Academic Resources

    Even when products are potentially compatible, issues can arise from errors in mixing order, pace, carrier volume, carrier quality and agitation. These are discussed in our article on sprayer loading and jar testing.

    In 2018, Purdue University published “Avoid Tank Mixing Errors”. It is an excellent reference.

    In late 2022, Australia’s GRDC released a comprehensive guide on pesticide mixing and batching (within the context of the Australian agronomic environment, of course), which can be downloaded for free, here.

    Finally, you can watch a 2021 presentation on tank mixing (below). It was delivered to a grape growing audience, but much of the content applies across agriculture. There are a few “oops” moments where I didn’t say quite what I meant. I misread the Sencor dissolution / filtration work. And, I really didn’t answer the last question about mixing herbicides. The answer should have been to consult labels and local resources, such as OMAFRA’s Crop Protection Hub. Note that any discussion of Canadian regulatory policy may have changed in light of the new 2022 Guidance Document.

    This article was co-written with Mike Cowbrough, OMAFRA Weed Management Specialist – Field Crops

  • Loading a Sprayer? Add Time and Patience!

    Loading a Sprayer? Add Time and Patience!

    What’s the most underused active ingredient when creating a proper tank mixture in a sprayer?

    Patience.

    Spray season is never long enough. The days which are most conducive to spraying are hard to come by. Therefore, the ingredient we need the most when spraying as well as tankmixing is patience. Without it, we are setting ourselves up for failure.

    Successful bakers will tell you that patience mattered when perfecting their most decadent creations. By taking their time, adding ingredients slowly and mixing them carefully, those professionals create stunning masterpieces.

    We can achieve a masterpiece as well, if we remember to slow down and apply the same principles.

     1. Take your time

    • Take 7-10 minutes between product additions to a spray mixture (especially dry formulations). Have a mini-vacation after each addition! This time allows each product to dissolve into solution and you can complete your spray records!
    • Extra time allows pesticides to be fully integrated into the spray solution before another product is added, which could impede either formulation from mixing successfully.
    • Each ingredient must be uniformly mixed before adding the next component. E.g. A soluble powder must be completely dissolved before adding the next item.

    2. Add ingredients slowly

    • Add products, one at a time, in the mix cone or inductor. If you’re adding product directly via shuttles and dedicated lines, the same principle applies.
    • Rinse mix cone or inductor and lines with clean water between product additions.
    Tank, cone or inductor, mix products one at a time and rinse between additions.
    Anything resembling cottage cheese in your spray mixture is not a spray masterpiece.
    • Never “stack” ingredients on top of each other in the mix cone or inductor. Much like oil and water don’t mix, chem-on-chem doesn’t mix either. Active ingredients need water in order transition into solution. It’s vital to not pile products into a mix cone or inductor where they can form cottage cheese instead of a liquid solution.
    • In my neighborhood, 3″ fill lines are not uncommon. They are a source of time savings when filling but they also bring additional cautions. Be aware of the problems over agitation can bring to what might have been a successful tankmix.

    3. Mix carefully

    • Start with sprayer tank 1/3-1/2 full to allow enough water to create a great solution.
    • Pre-slurry dry flowables in warm water whenever possible. Yes, it takes additional time and effort but it can prevent having to wash out individual nozzles and strainers later. Or worse, there’s the possibility that the tiny grains of an active ingredient that did not blend into the solution may cause injury to a off target crop.
    • Mix ingredients in the right order! Typically, crop protection products have a mixing order specified on their labels. Read the label and be familiar with the correct formulations you are currently spraying.
    • Adjuvants are added in the same sequence as pesticides, e.g., ammonium sulfate is a soluble powder, oil adjuvants are emulsifiable concentrates; and most surfactants are solutions.
    • Within each group, it is common practice to add the pesticide before the adjuvant, e.g., a soluble-powder pesticide before ammonium sulfate.

    Final thoughts

    Taking the extra 30 minutes now to load the sprayer carefully will save you the potential of 4 hours of having to clean out an entire tank later!

  • Sprayer Loading and the Jar Test

    Sprayer Loading and the Jar Test

    This article was co-written with Mike Cowbrough, OMAFRA Weed Management Specialist – Field Crops

    The time and attention spent during sprayer loading is a worthy investment. It ensures that the products in the tank perform as intended and reduces the chance of physical incompatibilities.

    The label

    Pesticide labels are always the first point of reference. Labelled mixing instructions should be obeyed even if they contradict conventional practices (see Mixing order, below). Consult this article on tank mix compatibility for more information on how to quickly and easily consult labels for each of your tank mix partners.

    The carrier

    Typically, the carrier is water. Water plays a very important role in tank mixing that is often underappreciated. Take some time to read Les Henry’s 2016 Grainnews article called “The Coles Notes of Water Chemistry“. You can also read about pH and water hardness. It should be noted that pH and the resultant hydrolysis that can affect product half-life is typically an insecticide issue (not fungicide or herbicide). The famous example is Captan, which has a half-life of 32 hours at pH 5, but only 10 minutes at pH 8. Michigan State did a great summary (in 2008 and on US product formulations) which you can find here.

    Finally, learn how to read a water quality report, here.

    Carrier volume

    Products dissolve better in higher volumes. The sprayer tank (vat, inductor, etc.) should be at least ½ full or water before adding the first product. In the case of a fertilizer carrier, it may look like water, but it contains high levels of salts that tie up free water and reduce solubility. For fertilizers, a higher initial volume of ¾ full is required.

    Note the undissolved residue collected on these swatches of red material. Products dissolve faster and better in higher carrier volumes.

    The incomplete dissolution of products can leave hard-to-clean residues, plug fluid lines, and result in a non-uniform application that reduces efficacy. The risk of incompatibility is greater with low carrier volumes and high product rates (especially dry formulations). This is a common problem in regions that use low water volumes to apply multiple tank mix partners.

    Carrier and product temperature

    Both carrier and product temperature affect mixing. Imagine mixing sugar in hot tea versus iced tea – more sugar dissolves more quickly in hot liquid. Here are three common temperature-related issues:

    • Dry formulations and liquid flowables take more time to disperse (consider using a pre-mixed slurry).
    • Emulsified concentrates and oil might form gels rather than milky blooms.
    • Water soluble packages might not dissolve completely and could plug filters and nozzles – or clog the pump intake.
    Note the undissolved residue collected on these swatches of red material. Products dissolve faster and better when carrier and products are warmer.

    Note: Water and fertilizer are very different carriers. Beware of carrier-specific incompatibilities

    Agitation

    Agitation should be on-going during mixing and spraying. When agitation is too low, products may not disperse or suspend and can settle out. In the case of leaving a sprayer overnight without agitation, settled product may or may not resuspend. See this article.

    When agitation is too aggressive (e.g. full agitation when tank is less than half full) product can foam, causing overflows or breaking pump suction during spraying. Over agitation can also cause dispersed products (e.g. emulsifiable concentrates) to separate and cause clumping that looks like curds.

    Note: When agitating, the surface of the carrier should be closer to a simmer than a rolling boil.

    Pace

    Products may require more than five minutes between additions. This is especially important when carrier or product is cold, or when adding dry products. When products are added too quickly, they will not entirely disperse or suspend, which could result in a physical incompatibility with subsequent additions. Learn more about the importance of time and patience during loading.

    While efficient sprayer loading is an excellent opportunity to improve your work rate, complicated tank mixes still require time between additions. To save some time, sprayer operators pre-hydrate dry products in a smaller tank or use an extra tank to pre-mix whole loads and simply transfer them over.

    Note: Even when dry products appear to be dissolved, they may not be. Be patient

    Product formulation

    Product formulation is a complicated science. In the 1950’s a formulation might have three active ingredients and an inert filler. See the historic formulation index card shared by Dr. M Doug Baumann (formally with Syngenta, Honeywood). Today, a product can include ~40 ingredients with formulation testing lasting two to four years! The more products you add to the tank, the higher the risk of antagonism.

    Note: If you experience physical incompatibility during loading, don’t blame the last product you put in the tank!

    Mixing order

    The order in which you add tank mix partners is critical. There are several acronyms around to help you decide on your mixing order. Here are the top three:

    • W.A.L.E.S. (Wettable powders, Agitate, Liquid flowables, Emulsifiable concentrates, Surfactants).
    • BASF’s W.A.M.L.E.G.S. (Wettable powders, Agitate, Microencapsulated suspensions Liquid flowables, Emulsifiable concentrates, high-load Glyphosates, Surfactants)
    • A.P.P.L.E.S. (Agitate, Powders soluble, Powders dry, Liquid flowables and suspensions, Emulsifiable concentrates, Solutions)

    W.A.L.E.S. is not broken. In fact, formulation chemists expect it to work ~95% of time. Generally, soluble liquids are forgiving and can be added early or late. It’s the dry formulations and emulsifiable concentrates that require more care. When there are exceptions to the order, they are clearly indicated on the pesticide label.

    W.A.L.E.S. is, perhaps, a bit simplistic. Products that fall within each “letter” have their own preferred mixing order that isn’t specified by the acronym. What follows is an expanded generic mixing order.

    • Water-Soluble Bags (WSB) – Allow them to fully dissolve and disperse.
    • Wettable Powders (WP)
    • Water Dispersible Granules (WDG, WG, SG)
    • Agitation to allow dry products to mix and disperse.
    • Liquid Flowables (F, FL): Including, in order, Suspension Concentrates (SC), Suspo-emulsions (SE), Capsule Suspensions (CS/ZC), Dispersible Concentrates (DC), Emulsions in water (EW).
    • In order: Emulsifiable Concentrates (EC): Microemulsifiable Concentrates (MEC) and Oil Dispersions (OD).
    • In order: Solutions (SN), Soluble Liquids (SL), Liquid Fertilizers and Micronurients (when not already premixed with fertilizer).
    • NOTE: Regarding adjuvants, always follow the label. If the label is silent, most water conditioning utility modifiers (e.g. compatibility agents, anti-foamers) should be added before pesticides. However, drift retardant utility modifiers are added dead last. Activator adjuvants like Non-Ionic Surfactants (NIS) and Crop Oil Concentrates (COC) tend to be added after pesticides, but are sometimes added based on their formulation, falling into order just like pesticides. Again, read the label.

    An example

    Micronutrients like sulfur (e.g. ATS) added to nitrogen-based formulations (e.g. UAN) can cause physical incompatibilities. This became a problem during “weed-and-feed” applications in Ontario corn, and thanks to the efforts of the pesticide manufacturer, we worked out a solution.

    What follows is not only a good example of why mixing order is critical, but why growers should get into the habit of performing jar tests. Learn more about a real-world ATS example here.

    Left: ATS and UAN premixed, followed by Primextra created curds.
    Centre: UAN, followed by low-load ATS followed by Primextra worked.
    Right: UAN followed by Primextra followed by high-load ATS worked.

    Small-plot mixing order

    Mixing errors are just as likely in small plot work as in commercial sprayers. Watch this short video case study describing mixing order for Elevore and glyphosate.

    The jar test

    Performing a jar test is like filling a sprayer in miniature. Follow all the same rules as filling your sprayer. Always wear personal protective equipment when performing a jar test. Do so in a safe and ventilated area, away from sources of ignition.

    1. Read all product labels. Know the product formulation (which affects mixing method and order). Look for information about the influence of carrier pH, hardness and any requirement for adjuvants. Defer to label instructions should they differ from these mixing steps.
    2. Shake any liquid products. This ensures the active ingredient and inert ingredients are thoroughly mixed.
    3. If using water as a carrier, add 250 ml to a 1 litre glass jar. For oil or fertilizer, add 375 ml.
    4. Agitate (stir) between additions. In a sprayer, agitation should continue throughout the mixing process.
    5. Add products in order (see Mixing order, above). Scale back the weights/volumes used to match the concentration intended for an actual sprayer tank (e.g. 1 kg product in a 1,000 litre sprayer tank is 0.5 g product in a 500 ml jar test). In a sprayer, you would flush an inductor with water between additions.
    6. Wait and check. Dry products and water-soluble packets must fully disperse and/or dissolve before adding the next product. Several factors affect the duration, but 3-5 minutes is typical. If testing water-soluble packets, include a ~1cm2 cutting of the PVA packaging.
    7. Top up the carrier to 500 ml.
    8. Measure pH using a digital meter (litmus papers may not be readable). This is best done after all products are added to account for their impact on pH and buffering capacity. If required, pH adjusters can be added at the end of mixing to ensure the solution is in the range required by the label.
    9. Let the solution stand in a ventilated area for 15 minutes and observe the results. If the mixture is giving off heat, these ingredients are not compatible. If gel or scum forms or solids settle to the bottom (except for the wettable powders) then the mixture is likely not compatible.

    Note: jar test will only reveal physical incompatibility between products – it will not reveal any other form of antagonism.

    Compatibility kits

    When performing a jar test you must maintain the same product-to-carrier ratio as in a full-sized sprayer tank. This math is made easier with commercial compatibility kits such as the one from Precision Laboratories (below).

    Compatibility Test Kit: Five pipettes, three bottles, gloves, instructions. ~$10.00. (Photo: Precision Laboratories)

    Such kits contain a few plastic “jars” and disposable micropipettes. By following the instructions included with the kit, you can easily reduce large labelled volumes (e.g. 1 kg of product in 1,000 litres) of multiple products to small volumes at the same ratio. In this case we assume the final volume would have been 1,000 L, and so we reduce all the quantities accordingly to get 500 ml. The following mixing order is provided as an example.

    OrderIngredientQuantity for 500 ml or 500 g of product labeled for 1,000 L of final spray volume
    1Compatibility agents5 ml (1 teaspoon)
    2Water soluble packets, wettable powders and dry flowables. Include a 1cm2 cutting of PVA packaging.15 g (1 tablespoon)
    3Liquid drift retardants5 ml (1 teaspoon)
    4Liquid concentrates, micro-emulsions and suspension concentrates5 ml (1 teaspoon)
    5Emulsifiable concentrates5 ml (1 teaspoon)
    6Water-soluble concentrates or solutions5 ml (1 teaspoon)
    7Remaining adjuvants and surfactants5 ml (1 teaspoon)

    Records and delayed reactions

    Keep detailed records of what you mixed and how you mixed it. This is important for traceability (e.g. CanadaGAP) and for tracking successes and failures for next year.

    The jar test itself can become a valuable record if it’s labelled and left in the chemical shed. You will see if products separate, precipitate or form residues. This may indicate if you can let a tank mix sit overnight or if it will require special attention during rinsing.

    For example, a grower tank-mixed Enlist with Manzinphos, which seemed to mix and spray with no issues until they were rained out and had to park the sprayer with 100 gallons of tank mix still in the system. The mixture turned to “lard”, plugging up all of the lines, filters, and the pump. They had no choice but to disassemble the sprayer and dig some of the substance out with screwdrivers (see the picture of the filter below). Perhaps if they had run a jar test and left the jar overnight this problem could have been avoided.

    Some physical incompatibilities are not immediately apparent. This occurred overnight while the partially-full sprayer waited out a rain event.

    Closed transfer

    As a brief mention, an expansion of closed transfers systems for loading pesticides is on the horizon in North America. Manufacturers of these systems claim they will make loading more efficient, reduce operator exposure and reduce point-source contamination. Depending on the design, however, the operator may not be able to open pesticide containers to obtain samples for jar testing. This would be a great loss.

    For more information

    Learn more about physical and chemical incompatibility in our article on Tank mix compatibility. Be sure to download a copy of Purdue University’s 2018 “Avoid Tank Mixing Errors”. It is an excellent reference.

  • Biobeds for Pesticide Waste Disposal

    Biobeds for Pesticide Waste Disposal

    One of the most challenging aspects of a spray operation is the disposal of leftovers or rinsate containing pesticides. Let’s be honest, too much of it is drained onto the ground in a corner of the yard or the field. Nobody’s happy about that, nobody’s proud of it, but what are the alternatives?

    Waste disposal is a skeleton in the closet of the pesticide industry. One of the problems is the time-consuming nature of sprayer cleaning, and the lack of clear guidelines on product labels that pass the buck.  Too often, the applicator is asked to “act in accordance with provincial or state guidelines”, which is essentially a dead end.

    Figure 1: Sprayer fill station

    At Sprayers101.com, we’ve tried to tackle the problem by finding ways to generate less waste (Express End Caps, Accu-Volume), by disposing of the rinsate by spraying it out, or by installing an efficient continuous rinsing system. We’d now like to talk about another component, biobeds.

    What is a biobed?

    Simply put, a biobed is a place where it’s safe and acceptable to dump dilute pesticide waste. First implemented in Sweden about 20 years ago, a biobed typically consists of a 1-m deep pit measuring about 3 m x 6 m or so. The pit is filled with a biomix, a mixture of cereal straw, compost or peat, and soil. The biomix, when properly prepared, acts to absorb a large amount of moisture, adsorb the pesticide molecules, and provide an environment in which microbes break down the residues.

    Figure 2: Canada’s first commercial biobed installation at Indian Head, SK, 2009 (Source: Murray Belyk, Bayer CropScience (retired)).

    The effluent from a properly constructed biobed system contains 90 to 99% less pesticide than what was introduced, depending on the pesticide.

    Biobeds have been extensively studied and are now found throughout Europe and many parts of Central and South America. Canada currently has 6 research biobed sites in the West, and a further 17 in Quebec. The systems have been researched by Agriculture & Agri-Food Canada (AAFC) in recent years, with promising results.

    Figure 3: European biobed installations, 2016 (Source: Jens Husby, Biobeds.org).

    Figure 4: Global biobed installations, 2016 (Source: Jens Husby, Biobeds.org).

    Constructing a biobed

    There are many possible variations of biobeds, some relatively simple and others engineered to address certain specific needs. A great deal of creativity can be used to customize a biobed for any operation.

    A simple biobed

    The following is a variation of the simplest biobeds, and these are the types first tested by AAFC in Saskatoon and Indian Head, Saskatchewan about 10 years ago. This design is based on the biobeds established in Sweden and the UK, and is a good way to learn about the system.

    Note that this biobed has an impermeable liner, so it’s a closed system. Excess water that leaches to the bottom must be removed and cycled back to the top of the biobed.

    • Create the biomix by blending two parts, by volume, chopped cereal straw or wood chips (not cedar), one part mature plant-sourced compost or peat and one part relatively coarse-textured soil (for optimal drainage). Add water as necessary as if making compost. Allow to sit for four to six weeks.

    Figure 5: Biomix preparation.

    • During this waiting time, the biomix will warm and form a white-mold complex. This is the microbial basis for its ability to break down pesticide residues. White mold will be visible on the cellulose portions of the biomix.

    Figure 6: white mold (Source: AAFC).

    • Identify a well-drained site easily accessible by spray equipment. Avoid low spots as water management becomes problematic.

    Figure 7: Site selection and/or biobed covering are essential to avoid waterlogging (Source: Murray Belyk, Bayer CropScience (retired)).

    • Dig a pit sized to suit your requirements. As a rule of thumb, 1 m3 can process about 1000 L of liquid in a season. Rainfall is included in this amount.

    Figure 8: A nice looking pit.

    • Line the pit with a geomembrane liner. 40 mil is plenty thick; any thicker and it gets hard to handle. Include a raised berm at the edge.

    Figure 9: Liner creates a closed system that will require a way to remove leached water.

    • Install weeping tile at bottom of pit, and extend it to ground level. This will be useful to determine water status and remove water if necessary.

    Figure 10: Weeping tile to collect excess water.

    • Cover weeping tile with pea gravel and a silt trap. This serves to make leached water freely available for removal.

    Figure 11: Pea gravel over weeping tile.

    • Fill pit with biomix, anticipating significant settling. Top up as necessary over next few weeks. Use extra biomix to create a slope away from berm.

    Figure 12: Filled biobed.

    • Establish a bromegrass cover by transplanting or sodding. This is an important way to remove excess water via evapotranspiration.

    Figure 13: Early sod growth on biobed at Indian Head, SK.

    • Introduce pesticide waste to biobed, managing moisture content to avoid waterlogging.

    Figure 14:  Pesticide waste entering biobed via drip irrigation.

    Introduction of pesticide waste to the biobed

    Moving pesticide waste from the sprayer to the biobed should be easy and trouble free. A simple pad built beside biobeds, either sealed with concrete or asphalt, or with a hardy geomembrane liner, works well. The sprayer is cleaned on this pad and rinsate flows into a drain. A sump pump lifts the rinsate to a storage tank from which it is introduced via gravity or pumped drip irrigation.

    Figure 15: Biobed system in Simpson, SK. Rinsate from sprayer is collected in a sump, which is pumped to the black storage tank in background. Rinsate is introduced into biobed (blue tub) as needed (Brian Caldwell in foreground, left, Larry Braul, right).

    When not in use, the sump drains freely to dispose of rain water.

    Others choose to pump or dump rinsate directly into a holding tank, from where it can be pumped onto the biobed.

    Figure 16: Holding tank at biobed in Outlook, SK.

    Some European systems include driving supports on the biobed so the sprayer can be parked directly over top.

    Figure 17: Steel beams can allow (light) sprayer access (Source: Eskil Nilsson via Biobeds.org).

    A two-stage biobed

    The same basic building principles apply as in the original simple biobed. However, instead of reintroducing the effluent to the top of the biomix as it collects on the bottom, it is instead pumped onto a second biobed. This biobed then degrades any remaining product. This system is more efficient at degrading persistent products, and allows for better water management.

    Figure 18: Two-stage biobed system at Outlook, SK.

    The principle has proven effective, helping degrade more difficult pesticides to acceptable levels.

    Above-ground biobeds

    One of the problems with below-ground biobeds in wet climates is the difficulty managing water. Above-ground biobeds can address this issue by eliminating the possibility of surface runoff being added to the biomix. Adding a rain cover would also be easier and more effective.

    Above-ground biobeds can be edged with plywood, or placed entirely into plastic tanks whose tops have been removed.

    Figure 19: Above ground biobed installation with plastic tub.

    One potential problem with above-ground biobeds is the later spring warming of this installation compared to below-ground types. Cold temperature reduces the effectiveness of biobeds due to the reliance on microbial activity. Heat tape has been tested by AAFC and shown to be very effective at warming the biomix and stimulating initial microbial activity. Passive solar systems have also been studied but are more difficult to install.

    Figure 20: Heat tape (Source: AAFC).

    Figure 21: Passive solar biomix heating system.

    Phytobac and Biofilters

    European designs have utilized plastic containers to form of various designs, including the commercial “Phytobac” systems from France and developed with the support of Bayer CropScience.

    Sequential biofilters have also been implemented. The leachate simply migrates through the biomix into the next container below. Eventually, adjacent biofilters containing plants act to remove the moisture.

    Figure 22: Phytobac installation, cross-section.

    Figure 23: Biofilter installation in Belgium (Source: Inge Mestdagh via Biobeds.org).

    Biomix longevity

    Swedish and UK research has suggested that biobeds require minimal maintenance aside from water management in closed systems. Biomix will settle over time and may need to be topped up. After five to eight years of use, it has been recommended to remove biomix and distribute it over a field with a manure spreader.

    Canadian research results

    Extensive analysis of pesticide degradation in five biobeds across Western Canada was conducted as part of a three-year study led by AAFC. Between eight and 51 products were analyzed per site, including herbicides, fungicides, and insecticides. Their results showed that single biobeds could remove about 90% of the introduced pesticide, and two in sequence usually removed more than 98%.

    Pesticides that tended not to degrade rapidly were removed to a greater degree in the second biobed.

    In the AAFC studies, three herbicides were more difficult to remove in the tested biobeds: clopyralid (e.g., Lontrel, Stinger), bentazon (Basagran, Storm) and imazethapyr (Pursuit, Arsenal). For these three, roughly 60% was removed in a two-biobed system.

    Concentrated pesticides should not be introduced to a biobed as this will kill the microbial populations.

    Some fungicides were shown to depress microbial populations but only temporarily. Microbial breakdown still occurred.

    Biobed manual

    AAFC has authored a comprehensive manual on biobed operation and installation based on research experience in Canada and elsewhere. It will be available here in late June 2018.

    The future of biobeds

    Research into biobeds remains active around the world. Different substrates for the biomix are being studied to suit local availabilities. Various systems, ranging from simple to highly engineered are being studied. Degradation effectiveness for various influents remains a topic of significant interest. Producer adoption and implementation are being reported.

    Thanks to funded research projects, biobeds are up and working at Canadian institutional sites such as government research centres, and there are opportunities for county and municipal government sites. For biobeds to be a viable option on North American farms, their design needs to remain simple and their integration into established practices needs to be seamless. Producer experience and feedback are essential

    Learn more

    Valuable information on biobeds can be obtained from these two websites:

    Voluntary Initiative (UK industry)

    Biobeds.org (International research)

    Note: Brian Caldwell and I first learned about biobeds from Eskil Nilsson (website) during a visit to Sweden in 2001, and obtained support for initial studies in Saskatoon and Indian Head from the Pest Management Centre as well as Bayer CropScience. Brian took a lead in our creative and technical efforts over many years. Dean Ngombe, under the co-supervision of Diane Knight at the U of S and myself, produced the first M.Sc. thesis, and with significant input from Allan Cessna, the first scientific publications in Canada on biobeds. Thanks for Larry Braul and many collaborators for leading the most recent AAFC study and generously sharing resources, and Erl Svendsen, Bruce Gossen, and Claudia Sheedy for editorial input.