Category: Mixing and Handling

For Basics Category

  • Paint it black – Parody

    Paint it black – Parody

    Never fail, as spring turns to summer we get questions about algal growth in water tanks. There are lots of suggested solutions, but questions about pH antagonism and phytotoxicity seem to linger. In 2021/22 we ran trials to explore how well home-grown algicides like copper, bleach, and ammonia work, and whether they cause antagonistic responses when that carrier water is used on crops. You can see the results here.

    Anticipating those results, we wrote this parody on a Stone’s classic. Not long after it was brought to life by the brilliant minds behind Michigan’s epic podcast “The Vegetable Beet” (Go subscribe right now!). You can hear it in the link below, where Ben Phillips is accompanied by his daughter’s toy tambourine. Crank it up to 11!

    You can even download Ben’s sheet music here.

    I see a white tank and I want it painted black
    No algae anymore, I want my water back
    I see the cart drive up while spraying summer rows
    I have to dump it out until the algae goes

    I see my neighbours’ tanks and they’re all painted black
    With copper sulfate they claim algae won’t come back
    I see them turn their heads and quickly look away
    They see my algae grow in sunlight every day

    I look inside the tank to see if it is black
    I could park it in the shed, or in the shade out back
    Maybe then it’ll fade away and I can face the facts
    It’s not easy filling up when your filters plug with crap

    I wish that my green sea would turn a deeper blue
    If you try chlorine pucks it will clear up for you

    I’ll store my tanks away from that bright summer sun
    Then I’ll spray algae-free before the mornin’ comes

    I see a clean tank ‘cause I had it painted black
    No algae anymore, I got my water back

    I see the cart drive up while spraying summer rows
    Clear water coming out, and no more clogging woes

    Hmm, hmm, hmm
    Hmm, hmm, hmm
    Hmm, hmm, hmm
    Hmm, hmm, hmm

    I want to see your tank painted black!
    Black as night!
    Black as coal!
    I wanna see the bugs, knocked right out of the sky
    I wanna see it painted, painted, painted black, yea!

  • Sprayer Loading and the Jar Test

    Sprayer Loading and the Jar Test

    This article was co-written with Mike Cowbrough, OMAFRA Weed Management Specialist – Field Crops

    The time and attention spent during sprayer loading is a worthy investment. It ensures that the products in the tank perform as intended and reduces the chance of physical incompatibilities.

    The label

    Pesticide labels are always the first point of reference. Labelled mixing instructions should be obeyed even if they contradict conventional practices (see Mixing order, below). Consult this article on tank mix compatibility for more information on how to quickly and easily consult labels for each of your tank mix partners.

    The carrier

    Typically, the carrier is water. Water plays a very important role in tank mixing that is often underappreciated. Take some time to read Les Henry’s 2016 Grainnews article called “The Coles Notes of Water Chemistry“. You can also read about pH and water hardness. It should be noted that pH and the resultant hydrolysis that can affect product half-life is typically an insecticide issue (not fungicide or herbicide). The famous example is Captan, which has a half-life of 32 hours at pH 5, but only 10 minutes at pH 8. Michigan State did a great summary (in 2008 and on US product formulations) which you can find here.

    Finally, learn how to read a water quality report, here.

    Carrier volume

    Products dissolve better in higher volumes. The sprayer tank (vat, inductor, etc.) should be at least ½ full or water before adding the first product. In the case of a fertilizer carrier, it may look like water, but it contains high levels of salts that tie up free water and reduce solubility. For fertilizers, a higher initial volume of ¾ full is required.

    Note the undissolved residue collected on these swatches of red material. Products dissolve faster and better in higher carrier volumes.

    The incomplete dissolution of products can leave hard-to-clean residues, plug fluid lines, and result in a non-uniform application that reduces efficacy. The risk of incompatibility is greater with low carrier volumes and high product rates (especially dry formulations). This is a common problem in regions that use low water volumes to apply multiple tank mix partners.

    Carrier and product temperature

    Both carrier and product temperature affect mixing. Imagine mixing sugar in hot tea versus iced tea – more sugar dissolves more quickly in hot liquid. Here are three common temperature-related issues:

    • Dry formulations and liquid flowables take more time to disperse (consider using a pre-mixed slurry).
    • Emulsified concentrates and oil might form gels rather than milky blooms.
    • Water soluble packages might not dissolve completely and could plug filters and nozzles – or clog the pump intake.
    Note the undissolved residue collected on these swatches of red material. Products dissolve faster and better when carrier and products are warmer.

    Note: Water and fertilizer are very different carriers. Beware of carrier-specific incompatibilities

    Agitation

    Agitation should be on-going during mixing and spraying. When agitation is too low, products may not disperse or suspend and can settle out. In the case of leaving a sprayer overnight without agitation, settled product may or may not resuspend. See this article.

    When agitation is too aggressive (e.g. full agitation when tank is less than half full) product can foam, causing overflows or breaking pump suction during spraying. Over agitation can also cause dispersed products (e.g. emulsifiable concentrates) to separate and cause clumping that looks like curds.

    Note: When agitating, the surface of the carrier should be closer to a simmer than a rolling boil.

    Pace

    Products may require more than five minutes between additions. This is especially important when carrier or product is cold, or when adding dry products. When products are added too quickly, they will not entirely disperse or suspend, which could result in a physical incompatibility with subsequent additions. Learn more about the importance of time and patience during loading.

    While efficient sprayer loading is an excellent opportunity to improve your work rate, complicated tank mixes still require time between additions. To save some time, sprayer operators pre-hydrate dry products in a smaller tank or use an extra tank to pre-mix whole loads and simply transfer them over.

    Note: Even when dry products appear to be dissolved, they may not be. Be patient

    Product formulation

    Product formulation is a complicated science. In the 1950’s a formulation might have three active ingredients and an inert filler. See the historic formulation index card shared by Dr. M Doug Baumann (formally with Syngenta, Honeywood). Today, a product can include ~40 ingredients with formulation testing lasting two to four years! The more products you add to the tank, the higher the risk of antagonism.

    Note: If you experience physical incompatibility during loading, don’t blame the last product you put in the tank!

    Mixing order

    The order in which you add tank mix partners is critical. There are several acronyms around to help you decide on your mixing order. Here are the top three:

    • W.A.L.E.S. (Wettable powders, Agitate, Liquid flowables, Emulsifiable concentrates, Surfactants).
    • BASF’s W.A.M.L.E.G.S. (Wettable powders, Agitate, Microencapsulated suspensions Liquid flowables, Emulsifiable concentrates, high-load Glyphosates, Surfactants)
    • A.P.P.L.E.S. (Agitate, Powders soluble, Powders dry, Liquid flowables and suspensions, Emulsifiable concentrates, Solutions)

    W.A.L.E.S. is not broken. In fact, formulation chemists expect it to work ~95% of time. Generally, soluble liquids are forgiving and can be added early or late. It’s the dry formulations and emulsifiable concentrates that require more care. When there are exceptions to the order, they are clearly indicated on the pesticide label.

    W.A.L.E.S. is, perhaps, a bit simplistic. Products that fall within each “letter” have their own preferred mixing order that isn’t specified by the acronym. What follows is an expanded generic mixing order.

    • Water-Soluble Bags (WSB) – Allow them to fully dissolve and disperse.
    • Wettable Powders (WP)
    • Water Dispersible Granules (WDG, WG, SG)
    • Agitation to allow dry products to mix and disperse.
    • Liquid Flowables (F, FL): Including, in order, Suspension Concentrates (SC), Suspo-emulsions (SE), Capsule Suspensions (CS/ZC), Dispersible Concentrates (DC), Emulsions in water (EW).
    • In order: Emulsifiable Concentrates (EC): Microemulsifiable Concentrates (MEC) and Oil Dispersions (OD).
    • In order: Solutions (SN), Soluble Liquids (SL), Liquid Fertilizers and Micronurients (when not already premixed with fertilizer).
    • NOTE: Regarding adjuvants, always follow the label. If the label is silent, most water conditioning utility modifiers (e.g. compatibility agents, anti-foamers) should be added before pesticides. However, drift retardant utility modifiers are added dead last. Activator adjuvants like Non-Ionic Surfactants (NIS) and Crop Oil Concentrates (COC) tend to be added after pesticides, but are sometimes added based on their formulation, falling into order just like pesticides. Again, read the label.

    An example

    Micronutrients like sulfur (e.g. ATS) added to nitrogen-based formulations (e.g. UAN) can cause physical incompatibilities. This became a problem during “weed-and-feed” applications in Ontario corn, and thanks to the efforts of the pesticide manufacturer, we worked out a solution.

    What follows is not only a good example of why mixing order is critical, but why growers should get into the habit of performing jar tests. Learn more about a real-world ATS example here.

    Left: ATS and UAN premixed, followed by Primextra created curds.
    Centre: UAN, followed by low-load ATS followed by Primextra worked.
    Right: UAN followed by Primextra followed by high-load ATS worked.

    Small-plot mixing order

    Mixing errors are just as likely in small plot work as in commercial sprayers. Watch this short video case study describing mixing order for Elevore and glyphosate.

    The jar test

    Performing a jar test is like filling a sprayer in miniature. Follow all the same rules as filling your sprayer. Always wear personal protective equipment when performing a jar test. Do so in a safe and ventilated area, away from sources of ignition.

    1. Read all product labels. Know the product formulation (which affects mixing method and order). Look for information about the influence of carrier pH, hardness and any requirement for adjuvants. Defer to label instructions should they differ from these mixing steps.
    2. Shake any liquid products. This ensures the active ingredient and inert ingredients are thoroughly mixed.
    3. If using water as a carrier, add 250 ml to a 1 litre glass jar. For oil or fertilizer, add 375 ml.
    4. Agitate (stir) between additions. In a sprayer, agitation should continue throughout the mixing process.
    5. Add products in order (see Mixing order, above). Scale back the weights/volumes used to match the concentration intended for an actual sprayer tank (e.g. 1 kg product in a 1,000 litre sprayer tank is 0.5 g product in a 500 ml jar test). In a sprayer, you would flush an inductor with water between additions.
    6. Wait and check. Dry products and water-soluble packets must fully disperse and/or dissolve before adding the next product. Several factors affect the duration, but 3-5 minutes is typical. If testing water-soluble packets, include a ~1cm2 cutting of the PVA packaging.
    7. Top up the carrier to 500 ml.
    8. Measure pH using a digital meter (litmus papers may not be readable). This is best done after all products are added to account for their impact on pH and buffering capacity. If required, pH adjusters can be added at the end of mixing to ensure the solution is in the range required by the label.
    9. Let the solution stand in a ventilated area for 15 minutes and observe the results. If the mixture is giving off heat, these ingredients are not compatible. If gel or scum forms or solids settle to the bottom (except for the wettable powders) then the mixture is likely not compatible.

    Note: jar test will only reveal physical incompatibility between products – it will not reveal any other form of antagonism.

    Compatibility kits

    When performing a jar test you must maintain the same product-to-carrier ratio as in a full-sized sprayer tank. This math is made easier with commercial compatibility kits such as the one from Precision Laboratories (below).

    Compatibility Test Kit: Five pipettes, three bottles, gloves, instructions. ~$10.00. (Photo: Precision Laboratories)

    Such kits contain a few plastic “jars” and disposable micropipettes. By following the instructions included with the kit, you can easily reduce large labelled volumes (e.g. 1 kg of product in 1,000 litres) of multiple products to small volumes at the same ratio. In this case we assume the final volume would have been 1,000 L, and so we reduce all the quantities accordingly to get 500 ml. The following mixing order is provided as an example.

    OrderIngredientQuantity for 500 ml or 500 g of product labeled for 1,000 L of final spray volume
    1Compatibility agents5 ml (1 teaspoon)
    2Water soluble packets, wettable powders and dry flowables. Include a 1cm2 cutting of PVA packaging.15 g (1 tablespoon)
    3Liquid drift retardants5 ml (1 teaspoon)
    4Liquid concentrates, micro-emulsions and suspension concentrates5 ml (1 teaspoon)
    5Emulsifiable concentrates5 ml (1 teaspoon)
    6Water-soluble concentrates or solutions5 ml (1 teaspoon)
    7Remaining adjuvants and surfactants5 ml (1 teaspoon)

    Records and delayed reactions

    Keep detailed records of what you mixed and how you mixed it. This is important for traceability (e.g. CanadaGAP) and for tracking successes and failures for next year.

    The jar test itself can become a valuable record if it’s labelled and left in the chemical shed. You will see if products separate, precipitate or form residues. This may indicate if you can let a tank mix sit overnight or if it will require special attention during rinsing.

    For example, a grower tank-mixed Enlist with Manzinphos, which seemed to mix and spray with no issues until they were rained out and had to park the sprayer with 100 gallons of tank mix still in the system. The mixture turned to “lard”, plugging up all of the lines, filters, and the pump. They had no choice but to disassemble the sprayer and dig some of the substance out with screwdrivers (see the picture of the filter below). Perhaps if they had run a jar test and left the jar overnight this problem could have been avoided.

    Some physical incompatibilities are not immediately apparent. This occurred overnight while the partially-full sprayer waited out a rain event.

    Closed transfer

    As a brief mention, an expansion of closed transfers systems for loading pesticides is on the horizon in North America. Manufacturers of these systems claim they will make loading more efficient, reduce operator exposure and reduce point-source contamination. Depending on the design, however, the operator may not be able to open pesticide containers to obtain samples for jar testing. This would be a great loss.

    For more information

    Learn more about physical and chemical incompatibility in our article on Tank mix compatibility. Be sure to download a copy of Purdue University’s 2018 “Avoid Tank Mixing Errors”. It is an excellent reference.

  • Airblast Agitation and Solubags

    Airblast Agitation and Solubags

    Agricultural products are formulated to be as emulsifiable as possible, but many do not mix well in water. They contain elements that do not dissolve (e.g. wettable powders), or they may be petroleum distillates (e.g. emulsifiable concentrates). Other products are heavier than water and form precipitates (e.g. fertilizers and powdered metals like copper). Consequently, good agitation is very important.

    Effective agitation requires water to “sweep” the bottom of the tank so that any precipitated material is picked up and re-mixed. Turbulence is often not enough. If there is too little agitation, the pesticide will be applied unevenly and not always at the required rate. If there is too much agitation, the pesticide may foam (which can be controlled using anti-foamers) or cause an invert emulsion (a gel). There are two types of airblast sprayer agitation: Mechanical and Hydraulic (learn about pros and cons here).

    Mechanical Agitation

    Mechanical Agitation is produced by paddles that are attached to a shaft mounted near the bottom of the spray tank. While effective, this system cannot always sweep the very bottom of the tank, so there is always some material that precipitates out of reach. Are your nozzles and screens plugging frequently, and is there “sludge” left at the bottom of the tank after spraying? You may have an agitation issue.

    Note the two paddles set at 90° to one another on the mechanical agitation shaft in this very cool “cutaway” Turbomist sprayer.
    Note the two paddles set at 90° to one another on the mechanical agitation shaft in this very cool “cutaway” Turbomist sprayer.

    Hydraulic Agitation

    Hydraulic Agitation is accomplished by returning a portion of the pump output to the tank. Cylindrical and oval tanks are the ideal configuration for the sparging (i.e. rinsing) type of hydraulic return agitation system. This system consists of a tube located longitudinally along the wall of the tank, with volume booster nozzles aimed at the centreline so they sweep across the bottom. Volume booster nozzles take a small amount of water pumped into their venturi chamber and create a vacuum that draws three to four times that volume from the surrounding water and expels it out the end.

    For hydraulic agitation to the effective, the agitator nozzle(s) should be fed by a dedicated line from the pressure side of the pump (not the pressure regulator). They should have a valve to throttle the flow or completely shut it off to prevent foaming.

    A mixing nozzle in the basket of a Hol sprayer.
    A mixing nozzle in the basket of a Hol sprayer.
    With enough pump capacity, a hydraulic return in the tank basket is a great way to agitate as you mix. A return in an old FMC.
    With enough pump capacity, a hydraulic return in the tank basket is a great way to agitate as you mix. A return in an older FMC.

    Adding Water Soluble Pouches

    Adding pesticide to the sprayer may not always be straight-forward. Many airblast operators, for example, place dissolvable pouches in the basket so they can be broken up by the hydraulic return, or the fill water. But fill water often splatters out of the basket, and the bags can burst open, releasing product into the air. This creates unnecessary contamination and both inhalation and dermal exposure concerns.

    Photo credit: Mario Lanthier.
    Photo credit: Mario Lanthier.

    Some elect to temporarily remove the basket and add the pouches to a half-full tank with the agitator on. However, the pump can suck in the partially dissolved bag which then coats the intake screen. This is exacerbated when the fill water is cold. I know of one operator that had to rebuild the pump because the Viton seals burned out. This operator now adds pouches to the basket while standing upwind and away from potential splatter. Or, they mix a pre-slurry.

    Mixing a pre-slurry requires the operator cut the bag into a five or 10 gallon bucket filled with water and to incorporate using a paint mixer. However, mixing a pre-slurry increases the chances of dermal exposure, inhalation and point-source contamination. Dissolvable bags were intended as a form of closed transfer, which is a good idea. Mixing a pre-slurry defeats that intent.

    And so, for all these reason, I don’t feel dissolvable pouches are a good formulation choice. If possible, select product formulations that do not cause possible filling issues and better match the capabilities of your agitation system. Always choose the safest and most effective filling method for your sprayer design.

  • Storing Pesticide Mix Overnight

    Storing Pesticide Mix Overnight

    Not being able to finish a tank due to weather or any other reason happens to just about everyone. Is it OK to simply leave the sprayer as is, and resume spraying later after some agitation?

    In many cases, the answer is yes. Most pesticide mixtures are stable in short term storage. On resuming spraying, an agitation could be all that’s needed to get back to where you started a day or so earlier.

    But there are three important exceptions.

    When the active ingredient is formulated as a suspension. Suspensions are typically wettable powders and flowables, and rely on a clay carrier to distribute the active in the tank. Because clay is denser than water, these formulations settle out quickly after agitation stops. Sure, they can be brought back into suspension with vigorous agitation. But in lines and booms, boom ends and screens, dislodging a settled clay carrier is much more difficult. It’s also hard to tell if the cleaning has been successful because the problem spots are hidden.

    The best solution is to flush the spray boom with water before materials can settle and lodge. A visual inspection where access is possible, such as strainer bowls and boom ends, is part of the process to ensure the formulated product has been removed.

    Learn to identify which formulations are suspensions. There’s lots of jargon out there. Look for terms such as DC, DF, DG, DS, F, Gr, SP. Even EC formulations are suspensions (oil in water) and require agitation.

    When the active ingredient is chemically unstable. Some pesticides can degrade in the tank, usually due to alkaline (high pH) hydrolysis. The effect is very pesticide specific, but in general, insecticides (particularly organophosphates and carbamates) are more susceptible than other pesticides. This fact sheet by Michigan State University describes the impact of pH on a the half-life of a large number of pesticides.

    Note that in the examples in the MSU fact sheets, pesticide half lives are typically days and weeks, and only rarely hours. Also note that while high pH is most often problematic, low pH can lead to faster breakdown in a small number of products.

    Ensuring tank mix stability requires a pH meter or paper, and possibly a pH modifier such as citric acid. But do your research first! Here’s an article on pH and water quality.

    When the tank previously contained a product known to harm the current crop. This situation is most common and most difficult to address. Some examples from western Canada are Group 2 modes of action sprayed prior to a canola crop. Why are Group 2 products implicated?  Many are formulated as dry products on a clay base, and these can settle in boom ends, adhere to tank walls, or get stuck on screens. Their solubility is pH dependent, as we explain in this article.

    Canola is particularly sensitive to this mode of action, and the most common canola herbicides, Liberty and glyphosate, are formulated with strong detergents that act as tank cleaners.

    Even when applicators think that their tank is clean, they can’t actually be sure and can’t do much about it at that stage. The stripping of tiny amounts of residue off the tank walls, filter screens, or plumbing, can happen during a mid-day stop or an overnight break.  Applicators eventually find out that this happened, usually about two weeks after spraying.

    Our advice is:

    After spraying a herbicide to which a subsequent crop may be sensitive, with the classic case being a Group 2 and moving to canola, be extra diligent with cleaning and pay attention to the tank walls, all screens, and boom ends.

    The best way to solve issues is to avoid them in the first place. If the weather looks unsettled and may interrupt your spray operation, consider mixing smaller batches that can be sprayed out completely even if conditions change quickly. This allows you to rinse the tank and spray water through the boom, thus avoiding a contamination problem developing overnight.

    If that’s not possible, at least do not let a tank mix sit in the boom overnight. Instead, use your clean water tank to push water through the boom prior to storage and double check the screens. The following day, prime the boom with your tank mix as usual and resume spraying the crop.

    If you’re not sure that your sprayer can draw from the clean water tank and push through the booms (the wash-down nozzles are, after all, the intended destination for that water), decipher your system and add the necessary valves that make this possible.

    A useful design that helps flush and prime a boom quickly is the recirculating boom offered by some aftermarket boom manufacturers. These booms are also more common on European sprayers. A nice feature of such designs is that the tank contents can be pumped through the entire boom assembly without actually spraying. This ensures that the boom is primed without any soil contamination. It also dilutes whatever residue there may be in the boom plumbing with the entire tank, likely reducing its concentration enough to be of little concern.

    An additional feature of recirculating booms is that many offer stainless steel tubing throughout most of their feed and return length, minimizing the black rubber hose products that often adsorb, and later release, herbicide contamination.

    Even if a wholesale boom or sprayer change is impractical, consider switching to steel boom lines and tanks tank to minimize residue carryover.

    As is often the case in the spraying business, prevention is easier and less costly than solving a big problem later. Spray mix storage is one of those examples where a small amount of extra effort at the beginning can pay big dividends later.

  • Water Quality and Spray Application

    Water Quality and Spray Application

    Water is one of the main inputs into a spray operation. The amount of water applied per acre is closely related to spray coverage and pesticide performance. But water quality – a term encompassing its cleanliness and chemical composition – is also critical to the performance of pesticides. Ensuring good performance means testing water and understanding the results.

    There are four main water quality indicators related to pesticide performance:

    1. Water Hardness. Water hardness is caused by positively charged minerals, primarily calcium and magnesium, but also sodium and iron. These cations can bind to some herbicides (glyphosate is the best-known example, also 2,4-D amine), reducing its performance. Hardness is usually named “Total Hardness (calculated)”, based on the concentration of calcium and magnesium in the sample, and is expressed in ppm or mg/L of CaCO3 equivalent. Some tests refer to the older unit “Grains”, which is ppm divided by 17.  Bayer suggests that total water hardness should be below 350 ppm (20 grains) for the low rate (1/2 L/acre equivalent) of glyphosate, and below 700 ppm for the higher rates.
    2. Bicarbonate.  Sometimes referred to as alkalinity, the bicarbonate ion can inhibit herbicide activity, and also make some herbicides more difficult to mix. The most commonly affected herbicides are members of the Group 1 modes of action, products like clethodim, sethoxydim, and others, as well as MCPA amine and 2,4-D amine. Definite guidelines are hard to find because the antagonistic effect of the bicarbonate ion depends on the presence of other ions such as sodium and calcium.
    3. pH. This is a complex parameter because it is related to pesticide solubility, hard water antagonism, and pesticide degradation. In most cases, pH values between 4 and 7 are considered acceptable. But some herbicides, notably those in the Group 2 modes of action, have specific pH needs to dissolve properly. For example, the sulfonylureas (FMC products such as Refine, Express), triazolopyrimidines (Corteval products such as Frontline, Simplicity), Triazolones (Bayer products such as Varro, Velocity M3) and Sulfonylaminocarbonyltriazolinone (UPL products such as Everest) dissolve better at higher pH, whereas the imidazolinones (Odyssey, Pursuit, Ares) tend to require lower pH. Some Group 14 products such as saflufenacil (BASF products Heat, Eragon) also prefer higher pH values for solubility. Label directions are important, sometimes calling for specific adjuvants to adjust the pH prior to adding the pesticide. Some pesticides, particularly insecticides, can break down rapidly in higher pH water. The rate of breakdown is usually not of importance on a spray day but may matter if a mixed tank needs to be stored for many hours or days.
    4. Cleanliness / turbidity. Water may contain suspended solids such as clay. Glyphosate and diquat (Reglone) are sensitive to this, as these chemicals are readily adsorbed to soil particles, and turbid water can reduce their effectiveness. This is also why dust generated by the sprayer can reduce these herbicides’ performance.

    Ensuring good performance

    Select clean water sources and conduct a water test to identify possible problems. Well water is more likely to be hard than surface water. If a laboratory water test is not available, then some quick home testing can provide the necessary guidance. First, use a conductivity meter to test the electrical conductivity (EC) of the spray water. Although this test does not identify the ions present, it shows if a potential problem exists. EC values less than 500 µS/cm are considered safe. For values above 500, a hardness test is necessary to confirm the presence of antagonizing cations. Paper test strips compared to a colour scale are a quick way to determine hardness.

    If you have done a water test and want to know what all the numbers mean, have a look here.

    If the water is hard, a generally accepted solution is to add ammonium sulphate (AMS) fertilizer at rates between 1 – 3% w/v of 21-0-0-24 to the spray tank, preferably before adding the herbicide. Spray grade liquid concentrate AMS product is available from Bayer CropScience, Winfield United, and some other suppliers.  The sulphate anions tie up the hard water cations, preventing them from antagonizing the herbicide. Liquid urea-ammonium nitrate (UAN, 28-0-0) has also been shown to improve herbicide activity for some products, but because it does not contain the sulphate ion, it is not as effective as AMS.

    Certain weak organic acids can also function as water conditioners. For example, citric acid can chelate hard water ions so long as the pH is not too low, that is, the necessary dissociable groups are ionic. If the pH is very low, these groups will be protonated and the chelating action is suppressed.

    Be careful when lowering pH. It does affect the solubility of many herbicides and possibly the function of some formulations. The outcome may be an unusable tank mix.

    Caution is also advised when adding foliar fertilizer specialty products. Adding a blend of fertilizer salts, combined with associated changes in pH, can result in unpredictable interactions with pesticides and water, resulting in sticky precipitates that may be very difficult to clean out of tanks and plumbing. Ask for compatibility data, and always conduct a jar test to be sure that the planned mixture mixes as expected. A recent study shows the effects of adding herbicides to UAN and ammonium thio-sulphate (ATS) plus nitrate stabilizers, where mixing order is critical.

    Turbidity is a problem with surface waters, especially in areas of clay soils and after surface runoff. If spray water is taken from a pond, its turbidity can be reduced by adding aluminum sulphate at rates between 10 to 60 mg/L of pond water. Thorough agitation is required, and 80 to 95% removal of turbidity is achieved within 24 to 48 h (technical information here).

    Pesticide manufacturers are usually aware of potential problems when their products are used in poor quality water. Consult with your local rep to learn of know issues and solutions before spraying.

    Check out this 2022 Real Agriculture interview with Tom and Greg Dahl of Winfield United. Pan ahead to the 16 minute mark for a discussion on water quality.