Category: Mixing and Handling

For Basics Category

Evaluating Methods for Controlling Algae in Carrier Water Storage Tanks

This work was performed with Mike Cowbrough, OMAFA Field Crop Weed Specialist.

In the early summer months, many field and specialty crop operations collect rainwater (or possibly pump water from holding ponds) into storage tanks for use as a carrier in spray applications. These tanks may be stationary, or they may be part of a nurse or tender truck that delivers both water and chemistry to the field as a means of improving operational efficiency.

Poly tanks. Source: Purdue Extension publication PPP-77 “Poly Tanks for Farms and Businesses“.

In the case of translucent poly tanks, which are commonly used because of their light weight, custom shape, and low price point, light exposure will grow algae. Algal populations multiply exponentially and will clog spray filters and negatively affect filling. In response, growers use home-grown algicides such as copper sulfate, lengths of copper pipe, household bleach, chlorine, bromine, etc. They do so with little or no guidance and therefore little or no consistency. Beyond the obvious questions surrounding efficacy, it is unknown whether these adjuncts create physical or chemical incompatibilities in the tank mix. If so, there is the potential for reduced efficacy and/or crop damage.

We tested popular methods for algae control by inoculating a series of 10 L translucent plastic jugs with an algal population sourced from a southern Ontario holding pond. The population was left to acclimate and generally establish itself (aka colonize) before we introduced some form of control. Each jug was then gently stirred and emptied through a sieve for qualitative assessment.

In a parallel experiment, we introduced the same algicides to fill water and conducted spray trials. 10 L volumes were mixed with a field rate of glyphosate and sprayed on RR soybeans. Weed control was assessed and soybean yield measured for each treatment.

Algicide Efficacy Experiment

In each treatment, tap water was mixed with a micronutrient growth media (from the Canadian Phycological Culture Centre at the University of Waterloo). This was an unsterilized 10% WC(ed) solution intended to provide micronutrients for algal growth while minimizing fungal and bacterial growth.

The source algae were collected from the bottom of a holding pond from a farm in Guelph, Ontario. Algae were homogenized and equal parts added to each jug. The jugs were former 10 L pesticide containers thoroughly rinsed and sprayed with Five Star’s “Star San” non-rinse sterilizer. Tank solutions were gently bubbled (one bubble every 10-15 seconds) with air from an aquarium pump. Air was balanced using a manifold and introduced via diffusion stones at the bottom of each jug.

Algae sourced from a farm’s holding pond near Guelph, Ontario. Algae was homogenized before inoculating treatment jugs with equal parts.

Treatments

Each treatment was tap water plus growth media inoculated with algae and exposed to a natural diurnal/nocturnal cycle unless otherwise indicated.

Control (no algicide)
Left in a shaded area (no direct sunlight)
Household bleach (approximately 5.25% sodium hypochlorite)
Container was spray-painted black to exclude light
Ammonia
“Scotch Bright” copper-coated scour pad. (copper is often introduced as copper sulfate at 1 cup / 1,000 US gal. or a short length of copper pipe)
Bromine (sourced from a local pool supply store)

Treatment Number	Treatment Name	Rate (/US Gal.)	Rate (% v/v)	Rate (/10 L final volume)
1	Control (no algicide)
2	Shaded
3	*Household bleach	1/4 tsp	0.00033	3.3 mL
4	Black container
5	*Ammonia solution	1/4 tsp	0.00033	3.3 mL
6	Copper-coated scour pad
7	Bromine	1/32 ml	0.000004	0.04 g

Table 1. * Bleach and ammonia should never be added together as they produce toxic chloramine gas.

Method

On July 12, jugs were loaded with water and growth media and inoculated with algae. They were bubbled gently for one week to establish a stable algal colony. On July 19, algicides were added, or transferred to shade or black-out conditions. On August 31 (approximately six weeks later), jug contents were gently stirred and filtered through white cloth for qualitative assessment.

Building up algal population for each jug. Note air lines through lids for slow, intermittent bubbling. Algae was not moved to black container or to the shade until after the first week of acclimation.

Almost six weeks after algicide was added, jug contents were gently stirred and poured through white cloth to collect algae and establish how easily the liquid passed through.

Observations

The results of all seven treatments, plus photos of the copper-coated scour pad.

(1) Control. Liquid poured slowly through cloth. Algae was still alive and healthy. It formed some clumps but was not as thick as other treatments.

(2) Shaded. Liquid poured fast and easily through cloth. Was particulate in texture rather than clumpy or gelatinous. Very little mass and entirely brown, suggesting it was dead.

(3) Household bleach. Liquid poured easily through cloth until the clump of algae sitting at the bottom of the jug came out (i.e., most algae were not suspended). Thick mat of healthy-looking algae (note profile photo #3 below). Much greener and thicker than the control (1).

(4) Black container. Liquid poured fast and easily through cloth. Algae retained a little green coloration (more than the shaded condition (2)) but was particulate and not as healthy as the control (1). We intended for this treatment to exclude all light, but it was still able to enter at the bottom where the jug wasn’t completely painted. This may have kept the algae alive.

In an oversight, the jug was not completely painted. This left a source of light at the bottom edge that may have helped sustain algae.

(5) Ammonia. Very difficult to pour liquid through the cloth (note profile photo #5 below). The only condition where a mat of algae was floating at the top of the jug rather than settled at the bottom. It was healthy, green and thick.

(6) Copper. The most gelatinous of all conditions, the liquid took the longest to pass through the cloth filter. While the algae seemed brown and dead, the gel would be very problematic during sprayer filling and spraying. Note that the copper scouring pad (shown unrinsed) has nothing growing on it.

(7) Bromine. Like the household bleach condition, liquid poured easily until the healthy mat of algae at the bottom of the jug came out (i.e., most algae were not suspended). Note profile photo #7 below.

Profile shots of treatment 3 (Bleach), 5 (Ammonia), and 7 (Bromine).

Spray Efficacy Experiment

Ideally, adjuncts added to carrier water are inert. That means they don’t reduce a herbicide’s effectiveness on susceptible weeds or increase crop injury. For example, hypochlorite (found in bleach and in chlorinated water) reduces the biological effectiveness of low concentrations of isoxaflutole (the active ingredient in herbicides such as Converge and Corvus). However, when added to higher, agriculturally-relevant concentrations, the reduction in efficacy wasn’t considered significant (Lin et al., 2003). Conversely, bromide has been added to certain herbicides to improve performance (Jeschke, 2009).

There’s precious little information about synergistic or antagonistic effects from adding bleach, ammonia, copper or bromine to herbicide carrier water. To learn more, we added each of these adjuncts to the standard rate of glyphosate (900 gae/ha – 0.67 L/ac). Using a CO₂-pressurized plot sprayer, the solution was applied to <10 cm tall weeds at 150 L/ha (15 g/ac) in glyphosate tolerant soybean at the 2nd trifoliate stage of growth (Elora Research Station, Ontario).

Visual crop injury was evaluated at 7 and 14 days after application. Weed efficacy was evaluated at 14 and 28 days after application. Soybeans yields were collected using a Wintersteiger plot combine and adjusted to a moisture content of 14%.

Weed Control

All treatments provided excellent control (>90%) of the weeds emerged at the time of application. Table 2 (below) presents the % visual control 28 days after application.

Carrier Treatment (glyphosate 540 g/L at 900 gae/ha or 0.67 L/ac)	Lamb’s-quarter	Green pigweed	Witch grass	Green foxtail
1) Control	0	0	0	0
2) Shaded	100	100	100	100
3) Household bleach	100	100	100	100
3a) Household bleach – added prior to mixing	95	97	100	100
4) Black container	100	100	100	100
5) Ammonia	100	100	100	100
6) Copper-coated scour pad	100	100	100	100
7) Bromine	100	100	100	100

Table 2. Visual control of lamb’s-quarter, green pigweed, witch grass and green pigweed at 28 days after the application of glyphosate 540 g/L at 900 gae/ha mixed with various carrier treatments intended to prevent algae growth. Treatment numbers correspond with the soybean injury and yield image below.

Soybean Injury and Yield

There was no noticeable crop injury from any treatment (figure below) and yields were not significantly different from the control treatment (Table 3). However, when bleach was added prior to mixing, we did observe a trend in reduced soybean yield. We’re unable to explain this observation, but suggest it may be an unrelated issue (such as field variability). There were no obvious signs of crop injury, and the treatment provided excellent weed control.

Photographs of each plot 14 days after application. The number/letter in each inset image corresponds to treatments in Tables 2 and 3.

Carrier Treatment (glyphosate 540 g/L at 900 gae/ha or 0.67 L/ac)	Crop Injury (%)*	Avg. Yield (bu/ac)	Significance**
4) Black container	0	40.0	A
7) Bromine	0	39.6	A
2) Shaded	0	38.1	AB
3) Household bleach	0	37.6	AB
1) Control	0	37	ABC
5) Ammonia	0	36.9	ABC
6) Copper-coated scour pad	0	36.1	BC
3a) Household bleach – added prior to mixing	0	34.0	C

Table 3. Visual control of lamb’s-quarter, green pigweed, witch grass and green pigweed at 28 days after the application of glyphosate 540 g/L at 900 gae/ha mixed with various carrier treatments to prevent algae growth. *7 days after application. **Duncan’s multiple range test. Soybean yields that don’t share a letter in common are significantly different.

Discussion

We elected to use an extreme situation where a single application of algicide was applied to an established, healthy colony. It’s possible that regular applications of algicide in a volume of water with little or no algae could maintain that condition.

A treatment was considered effective if it slowed or halted algal growth, especially if it also degraded algal populations, causing them to become brown, thin, and/or particulate. Once in the spray tank, the shear forces created by circulation should disperse any dead or degraded algal masses, making it easier to pass them through filters and nozzles.

The shade treatment appeared to kill algae as well as cause degradation. Second place went to the black-out treatment, where some light was unfortunately allowed in. This would have continued to fuel photosynthesis in the unpainted portion at the bottom of the jug. Conversely, the black exterior likely raised temperatures above >20 °C, which depresses most algal growth and may have contributed to the degradation.

Copper appeared to kill the algae but also created a gel that would pose problems to filters. Unlikely to be bacterial, as copper is known to suppress bacterial growth, it could have been caused by diatoms; certain invasive species are known to form brown jelly-like material endearingly referred to as “brown snot” or “rock snot”. Alternately, and according to work by J. Rodrigues and R. Lagoa, alginate polysaccharide can form viscous aqueous dispersions (such as gels) in the presence of divalent cations (such as copper).

No treatment appeared to reduce herbicide efficacy or affect crop health. However, unexpectedly, the household bleach added prior to mixing may have reduced soybean yield. Given the limited number of replications and the single plot location, we suspect this was a field effect, unrelated to the treatment.

Take Home

Based on these results, a combination of shade and light-excluding materials (e.g. black paint) would be the ideal approach to algae control. It’s cheap, effective, and doesn’t require periodic management. Buying black tanks is a good choice, or you can paint them. What you should paint them with is a matter of debate and there’s a very good Twitter thread on the subject if you’re interested.

An Aside: Algae in Ponds and Dugouts

We didn’t test this, but the question has come up and the best we can do is share some long-standing farmer wisdom. Some have used Aquashade dye to absorb the photosynthetic wavelengths and reduce algae buildup. Reputedly it is moderately successful. Another option is adding aluminum sulfate to the pond, and with a lot of agitation it should clarify in about 48 hours. Still others have added a few square barley straw bales to the water and found it to work surprisingly well (possibly an allelopathic response). Tie a rope to them and float them in the pond.

Citations

Jeschke, Peter. 2009. The unique role of halogen substituents in the design of modern agrochemicals. Pest Manag Sci, 2010; 66: 10–27

Lin, C.H., Lerch, R.N., Garrett, H.E. and M.F. George. 2003. Degradation of Isoxaflutole (Balance) Herbicide by Hypochlorite in Tap Water. J. Agric. Food Chem. 2003, 51, 8011-8014

November 28, 2022

Paint it black – Parody
Never fail, as spring turns to summer we get questions about algal growth in water tanks. There are lots of suggested solutions, but questions about pH antagonism and phytotoxicity seem to linger. In 2021/22 we ran trials to explore how well home-grown algicides like copper, bleach, and ammonia work, and whether they cause antagonistic responses when that carrier water is used on crops. You can see the results here.
Anticipating those results, we wrote this parody on a Stone’s classic. Not long after it was brought to life by the brilliant minds behind Michigan’s epic podcast “The Vegetable Beet” (Go subscribe right now!). You can hear it in the link below, where Ben Phillips is accompanied by his daughter’s toy tambourine. Crank it up to 11!
You can even download Ben’s sheet music here.
I see a white tank and I want it painted black
No algae anymore, I want my water back
I see the cart drive up while spraying summer rows
I have to dump it out until the algae goes
I see my neighbours’ tanks and they’re all painted black
With copper sulfate they claim algae won’t come back
I see them turn their heads and quickly look away
They see my algae grow in sunlight every day
I look inside the tank to see if it is black
I could park it in the shed, or in the shade out back
Maybe then it’ll fade away and I can face the facts
It’s not easy filling up when your filters plug with crap
I wish that my green sea would turn a deeper blue
If you try chlorine pucks it will clear up for you
I’ll store my tanks away from that bright summer sun
Then I’ll spray algae-free before the mornin’ comes
I see a clean tank ‘cause I had it painted black
No algae anymore, I got my water back
I see the cart drive up while spraying summer rows
Clear water coming out, and no more clogging woes
Hmm, hmm, hmm
Hmm, hmm, hmm
Hmm, hmm, hmm
Hmm, hmm, hmm
I want to see your tank painted black!
Black as night!
Black as coal!
I wanna see the bugs, knocked right out of the sky
I wanna see it painted, painted, painted black, yea!
April 17, 2021
Airblast Agitation and Solubags
Agricultural products are formulated to be as emulsifiable as possible, but many do not mix well in water. They contain elements that do not dissolve (e.g. wettable powders), or they may be petroleum distillates (e.g. emulsifiable concentrates). Other products are heavier than water and form precipitates (e.g. fertilizers and powdered metals like copper). Consequently, good agitation is very important.
Effective agitation requires water to “sweep” the bottom of the tank so that any precipitated material is picked up and re-mixed. Turbulence is often not enough. If there is too little agitation, the pesticide will be applied unevenly and not always at the required rate. If there is too much agitation, the pesticide may foam (which can be controlled using anti-foamers) or cause an invert emulsion (a gel). There are two types of airblast sprayer agitation: Mechanical and Hydraulic (learn about pros and cons here).
Mechanical Agitation
Mechanical Agitation is produced by paddles that are attached to a shaft mounted near the bottom of the spray tank. While effective, this system cannot always sweep the very bottom of the tank, so there is always some material that precipitates out of reach. Are your nozzles and screens plugging frequently, and is there “sludge” left at the bottom of the tank after spraying? You may have an agitation issue.
Note the two paddles set at 90° to one another on the mechanical agitation shaft in this very cool “cutaway” Turbomist sprayer.
Hydraulic Agitation
Hydraulic Agitation is accomplished by returning a portion of the pump output to the tank. Cylindrical and oval tanks are the ideal configuration for the sparging (i.e. rinsing) type of hydraulic return agitation system. This system consists of a tube located longitudinally along the wall of the tank, with volume booster nozzles aimed at the centreline so they sweep across the bottom. Volume booster nozzles take a small amount of water pumped into their venturi chamber and create a vacuum that draws three to four times that volume from the surrounding water and expels it out the end.
For hydraulic agitation to the effective, the agitator nozzle(s) should be fed by a dedicated line from the pressure side of the pump (not the pressure regulator). They should have a valve to throttle the flow or completely shut it off to prevent foaming.
A mixing nozzle in the basket of a Hol sprayer.
With enough pump capacity, a hydraulic return in the tank basket is a great way to agitate as you mix. A return in an older FMC.
Adding Water Soluble Pouches
Adding pesticide to the sprayer may not always be straight-forward. Many airblast operators, for example, place dissolvable pouches in the basket so they can be broken up by the hydraulic return, or the fill water. But fill water often splatters out of the basket, and the bags can burst open, releasing product into the air. This creates unnecessary contamination and both inhalation and dermal exposure concerns.
Photo credit: Mario Lanthier.
Photo credit: Mario Lanthier.
Some elect to temporarily remove the basket and add the pouches to a half-full tank with the agitator on. However, the pump can suck in the partially dissolved bag which then coats the intake screen. This is exacerbated when the fill water is cold. I know of one operator that had to rebuild the pump because the Viton seals burned out. This operator now adds pouches to the basket while standing upwind and away from potential splatter. Or, they mix a pre-slurry.
Mixing a pre-slurry requires the operator cut the bag into a five or 10 gallon bucket filled with water and to incorporate using a paint mixer. However, mixing a pre-slurry increases the chances of dermal exposure, inhalation and point-source contamination. Dissolvable bags were intended as a form of closed transfer, which is a good idea. Mixing a pre-slurry defeats that intent.
And so, for all these reason, I don’t feel dissolvable pouches are a good formulation choice. If possible, select product formulations that do not cause possible filling issues and better match the capabilities of your agitation system. Always choose the safest and most effective filling method for your sprayer design.
January 2, 2020
Storing Pesticide Mix Overnight
Not being able to finish a tank due to weather or any other reason happens to just about everyone. Is it OK to simply leave the sprayer as is, and resume spraying later after some agitation?
In many cases, the answer is yes. Most pesticide mixtures are stable in short term storage. On resuming spraying, an agitation could be all that’s needed to get back to where you started a day or so earlier.
But there are three important exceptions.
When the active ingredient is formulated as a suspension. Suspensions are typically wettable powders and flowables, and rely on a clay carrier to distribute the active in the tank. Because clay is denser than water, these formulations settle out quickly after agitation stops. Sure, they can be brought back into suspension with vigorous agitation. But in lines and booms, boom ends and screens, dislodging a settled clay carrier is much more difficult. It’s also hard to tell if the cleaning has been successful because the problem spots are hidden.
The best solution is to flush the spray boom with water before materials can settle and lodge. A visual inspection where access is possible, such as strainer bowls and boom ends, is part of the process to ensure the formulated product has been removed.
Learn to identify which formulations are suspensions. There’s lots of jargon out there. Look for terms such as DC, DF, DG, DS, F, Gr, SP. Even EC formulations are suspensions (oil in water) and require agitation.
When the active ingredient is chemically unstable. Some pesticides can degrade in the tank, usually due to alkaline (high pH) hydrolysis. The effect is very pesticide specific, but in general, insecticides (particularly organophosphates and carbamates) are more susceptible than other pesticides. This fact sheet by Michigan State University describes the impact of pH on a the half-life of a large number of pesticides.
Note that in the examples in the MSU fact sheets, pesticide half lives are typically days and weeks, and only rarely hours. Also note that while high pH is most often problematic, low pH can lead to faster breakdown in a small number of products.
Ensuring tank mix stability requires a pH meter or paper, and possibly a pH modifier such as citric acid. But do your research first! Here’s an article on pH and water quality.
When the tank previously contained a product known to harm the current crop. This situation is most common and most difficult to address. Some examples from western Canada are Group 2 modes of action sprayed prior to a canola crop. Why are Group 2 products implicated? Many are formulated as dry products on a clay base, and these can settle in boom ends, adhere to tank walls, or get stuck on screens. Their solubility is pH dependent, as we explain in this article.
Canola is particularly sensitive to this mode of action, and the most common canola herbicides, Liberty and glyphosate, are formulated with strong detergents that act as tank cleaners.
Even when applicators think that their tank is clean, they can’t actually be sure and can’t do much about it at that stage. The stripping of tiny amounts of residue off the tank walls, filter screens, or plumbing, can happen during a mid-day stop or an overnight break. Applicators eventually find out that this happened, usually about two weeks after spraying.
Our advice is:
After spraying a herbicide to which a subsequent crop may be sensitive, with the classic case being a Group 2 and moving to canola, be extra diligent with cleaning and pay attention to the tank walls, all screens, and boom ends.
The best way to solve issues is to avoid them in the first place. If the weather looks unsettled and may interrupt your spray operation, consider mixing smaller batches that can be sprayed out completely even if conditions change quickly. This allows you to rinse the tank and spray water through the boom, thus avoiding a contamination problem developing overnight.
If that’s not possible, at least do not let a tank mix sit in the boom overnight. Instead, use your clean water tank to push water through the boom prior to storage and double check the screens. The following day, prime the boom with your tank mix as usual and resume spraying the crop.
If you’re not sure that your sprayer can draw from the clean water tank and push through the booms (the wash-down nozzles are, after all, the intended destination for that water), decipher your system and add the necessary valves that make this possible.
A useful design that helps flush and prime a boom quickly is the recirculating boom offered by some aftermarket boom manufacturers. These booms are also more common on European sprayers. A nice feature of such designs is that the tank contents can be pumped through the entire boom assembly without actually spraying. This ensures that the boom is primed without any soil contamination. It also dilutes whatever residue there may be in the boom plumbing with the entire tank, likely reducing its concentration enough to be of little concern.
An additional feature of recirculating booms is that many offer stainless steel tubing throughout most of their feed and return length, minimizing the black rubber hose products that often adsorb, and later release, herbicide contamination.
Even if a wholesale boom or sprayer change is impractical, consider switching to steel boom lines and tanks tank to minimize residue carryover.
As is often the case in the spraying business, prevention is easier and less costly than solving a big problem later. Spray mix storage is one of those examples where a small amount of extra effort at the beginning can pay big dividends later.
May 26, 2017
Water Quality and Spray Application
Water is one of the main inputs into a spray operation. The amount of water applied per acre is closely related to spray coverage and pesticide performance. But water quality – a term encompassing its cleanliness and chemical composition – is also critical to the performance of pesticides. Ensuring good performance means testing water and understanding the results.
There are four main water quality indicators related to pesticide performance:
1. Water Hardness. Water hardness is caused by positively charged minerals, primarily calcium and magnesium, but also sodium and iron. These cations can bind to some herbicides (glyphosate is the best-known example, also 2,4-D amine), reducing its performance. Hardness is usually named “Total Hardness (calculated)”, based on the concentration of calcium and magnesium in the sample, and is expressed in ppm or mg/L of CaCO3 equivalent. Some tests refer to the older unit “Grains”, which is ppm divided by 17. Bayer suggests that total water hardness should be below 350 ppm (20 grains) for the low rate (1/2 L/acre equivalent) of glyphosate, and below 700 ppm for the higher rates.
2. Bicarbonate. Sometimes referred to as alkalinity, the bicarbonate ion can inhibit herbicide activity, and also make some herbicides more difficult to mix. The most commonly affected herbicides are members of the Group 1 modes of action, products like clethodim, sethoxydim, and others, as well as MCPA amine and 2,4-D amine. Definite guidelines are hard to find because the antagonistic effect of the bicarbonate ion depends on the presence of other ions such as sodium and calcium.
3. pH. This is a complex parameter because it is related to pesticide solubility, hard water antagonism, and pesticide degradation. In most cases, pH values between 4 and 7 are considered acceptable. But some herbicides, notably those in the Group 2 modes of action, have specific pH needs to dissolve properly. For example, the sulfonylureas (FMC products such as Refine, Express), triazolopyrimidines (Corteval products such as Frontline, Simplicity), Triazolones (Bayer products such as Varro, Velocity M3) and Sulfonylaminocarbonyltriazolinone (UPL products such as Everest) dissolve better at higher pH, whereas the imidazolinones (Odyssey, Pursuit, Ares) tend to require lower pH. Some Group 14 products such as saflufenacil (BASF products Heat, Eragon) also prefer higher pH values for solubility. Label directions are important, sometimes calling for specific adjuvants to adjust the pH prior to adding the pesticide. Some pesticides, particularly insecticides, can break down rapidly in higher pH water. The rate of breakdown is usually not of importance on a spray day but may matter if a mixed tank needs to be stored for many hours or days.
4. Cleanliness / turbidity. Water may contain suspended solids such as clay. Glyphosate and diquat (Reglone) are sensitive to this, as these chemicals are readily adsorbed to soil particles, and turbid water can reduce their effectiveness. This is also why dust generated by the sprayer can reduce these herbicides’ performance.
Ensuring good performance
Select clean water sources and conduct a water test to identify possible problems. Well water is more likely to be hard than surface water. If a laboratory water test is not available, then some quick home testing can provide the necessary guidance. First, use a conductivity meter to test the electrical conductivity (EC) of the spray water. Although this test does not identify the ions present, it shows if a potential problem exists. EC values less than 500 µS/cm are considered safe. For values above 500, a hardness test is necessary to confirm the presence of antagonizing cations. Paper test strips compared to a colour scale are a quick way to determine hardness.
If you have done a water test and want to know what all the numbers mean, have a look here.
If the water is hard, a generally accepted solution is to add ammonium sulphate (AMS) fertilizer at rates between 1 – 3% w/v of 21-0-0-24 to the spray tank, preferably before adding the herbicide. Spray grade liquid concentrate AMS product is available from Bayer CropScience, Winfield United, and some other suppliers. The sulphate anions tie up the hard water cations, preventing them from antagonizing the herbicide. Liquid urea-ammonium nitrate (UAN, 28-0-0) has also been shown to improve herbicide activity for some products, but because it does not contain the sulphate ion, it is not as effective as AMS.
Certain weak organic acids can also function as water conditioners. For example, citric acid can chelate hard water ions so long as the pH is not too low, that is, the necessary dissociable groups are ionic. If the pH is very low, these groups will be protonated and the chelating action is suppressed.
Be careful when lowering pH. It does affect the solubility of many herbicides and possibly the function of some formulations. The outcome may be an unusable tank mix.
Caution is also advised when adding foliar fertilizer specialty products. Adding a blend of fertilizer salts, combined with associated changes in pH, can result in unpredictable interactions with pesticides and water, resulting in sticky precipitates that may be very difficult to clean out of tanks and plumbing. Ask for compatibility data, and always conduct a jar test to be sure that the planned mixture mixes as expected. A recent study shows the effects of adding herbicides to UAN and ammonium thio-sulphate (ATS) plus nitrate stabilizers, where mixing order is critical.
Turbidity is a problem with surface waters, especially in areas of clay soils and after surface runoff. If spray water is taken from a pond, its turbidity can be reduced by adding aluminum sulphate at rates between 10 to 60 mg/L of pond water. Thorough agitation is required, and 80 to 95% removal of turbidity is achieved within 24 to 48 h (technical information here).
Pesticide manufacturers are usually aware of potential problems when their products are used in poor quality water. Consult with your local rep to learn of know issues and solutions before spraying.
Check out this 2022 Real Agriculture interview with Tom and Greg Dahl of Winfield United. Pan ahead to the 16 minute mark for a discussion on water quality.
May 27, 2015