Tag: weather

  • Spraying Weather

    Spraying Weather

    It’s time to spray and what’s the first thing you do? Check the weather forecast, of course. More often than not, the suitability of the weather is the main factor in the decision to spray. Let’s have a closer look at what each weather component contributes to the decision.

    Wind:

    Everyone knows that small droplets can drift if it’s windy, and the windier, the worse it is. But that’s hardly the whole story.  Here’s how can we improve our understanding of wind and its impact.

    • Look beyond the wind forecast. It’s standard practice to look a day or two ahead for wind forecasts. At any instant, the wind speed and direction may be acceptable for our planned spray job, but we know that it will change. Consider wind speed sites such as Windfinder, Ventusky, or Windy for added insight. These services show trends over time in a great visual interface, allowing users to anticipate changes in wind speed and direction for better planning. While they aren’t forecasts per se, visualizing wind patterns over a larger region allows a better understanding of what’s coming your way.
    Figure 1: Sites such as Windy.com offer powerful visualizations of current and future wind conditions.
    • Use wind as an ally. We’re conditioned to think of wind as having a negative effect on spray drift. The less the better. Yes, droplet displacement increases with wind speed. But the “negative-only” perspective is being re-evaluated in light of dangers associated with wind-free conditions that often occur during temperature inversions (see “Temperature”, below). In fact, wind provides several advantages over calm conditions:
      1. Directional certainty. We can assess the risk to downwind sensitive areas. This is not possible with calm conditions because inversion air flow may follow terrain, and as inversions dissipate, the first daily winds can be changeable and unpredictable in direction.
      2. Turbulence. Wind creates mechanical turbulence which helps sprays deposit and disperse.  Both of these effects have value. In a calm environment, such turbulent eddies don’t exist.
      3. Low drift options. If it’s windy, we have options to respond. We can lower the boom or lower the spray pressure. We can mix the next tank in higher water volume, forcing either a larger nozzle (larger flow rates of the same model nozzle usually produce coarser sprays) or slower travel speeds. All these practices reduce drift when it’s windy. In comparison, nothing (except not spraying) can be done to reduce risk during inversion conditions. This is because even low-drift spray contain enough fine droplets to cause damage if they linger.
    • Know your wind speed. The international standard for wind speed measurement is 10 m above ground level. When 25 km/h wind speeds are reported, they are at 10 m, not the 1 m height where the boom is located. Within the surface boundary layer, the part of the atmosphere closest to the ground, wind speeds typically increase linearly with the natural log of the height above the canopy. The slope of that line depends on atmospheric stability and roughness length. Very close to the ground, the wind speed reaches zero, and that height is a function of the roughness of the surrounding terrain.

      As a rule of thumb, over a short crop canopy, expect the wind speed at 1 m above ground to be about 0.67x of the speed at 10 m. So if the weather reports 25 km/h, the actual wind speed at boom height is closer to 17 km/h. Remember that weather stations can be far away, and local conditions will vary. Always measure your local wind speed and direction with your own weather station or handheld device, and keep a record.
    Figure 2: Relationship of wind speed and height, for three roughness conditions (Source: Oke et al, 2017)
    Figure 3: Hand-held wind meters or weather stations are an essential part of a spray operation and record keeping.

    Wind and Mode of Action. Coarser sprays are a common way to reduce drift in windy conditions. But some modes of action aren’t well suited to coarser sprays. We can schedule our spray jobs throughout the day to correspond to spray quality tolerance. Apply the products that require the finest sprays (contact products, grassy herbicides, insecticides) when conditions are best, and save the sprays that tolerate the coarser sprays (systemic products, broadleaf targets) for less certain conditions later in the day. Or treat the fields whose downwind edges border a sensitive crop during better conditions. Here’s a rough guide to spray quality and herbicide mode of action.

    Temperature

    Like wind, air temperature is more complex than it appears at first sight. Here are some other aspects to consider:

    • Understand temperature inversions. Temperature matters. But perhaps the most important aspect of temperature when it comes to spraying isn’t the temperature per se, but how it changes with height. The temperature change with height is used to identify dangerous temperature inversions.

      Here’s how temperature profiles work (for a quick Sprayers101 overview, here, for the best in-depth explanation (NDSU), here): Due to atmospheric pressure, there is always a slight temperature decrease with height, about 1 ºC per 100 m (the dry adiabatic lapse rate). This temperature profile describes a “neutral” atmosphere, i.e., no thermal effects.

      When it’s sunny, solar radiation heats the earth, which in turn warms the air near it. As a result, the rate of cooling with height is greater than the adiabatic lapse rate, and we have “unstable” conditions that are characterized by thermal turbulence (warm air rising, cold air falling) that actively mixes air parcels. Thermal turbulence is very good at dispersing anything in the air, including spray droplets.

      When solar radiation is low or absent, the earth cools and this mostly affects the air near it. As a result, air temperature rises with height, and the daytime temperature / height profile is inverted. Air parcels no longer move up or down, in fact they return to their original location if displaced. This results in a “stable” atmosphere, also called an inversion.

      Inversions are dangerous because they are associated with very low dispersion, and a spray cloud will remain concentrated and may linger over the ground for a long time, like ground fog.

      Most weather services do not actively measure inversions. Instead, their presence has to be inferred by clues. For example, inversions:
      (a) occur primarily when solar radiation is low, from early evening, overnight, to early morning;
      (b) are more likely on clear nights, when soils cool more;
      (c) can be seen when ground fog is present, or when dust hangs, moving slowly;
      (d) are associated with low ground temperatures that also cause dew. 

    Recent findings about inversion in Missouri were summed up in this excellent webinar by Dr. Mandy Bish, Extension Weed Specialist at the University of Missouri. Her studies showed that inversions can begin hours before sunset, their presence and duration are dependent on local conditions such as topography and windbreaks, and recognition of telltale signs of inversions such as lack of windspeed are important for accurate local assessments.

    Figure 4: Morning ground fog in Australia (picture provided to author).
    • Use Mesonets if you have them. Mesonets are networks of weather stations, and they can add valuable information. For example, North Dakota has an extensive network of about 130 weather stations that, among other things, measures and reports temperature inversions. NDAWN (ndawn.ndsu.nodak.edu) reports temperatures at 3 m and 1 m, and issues warnings of temperature inversions as they develop at a specific location. NDAWN information is available as an app. North Dakota isn’t the only place to have a public mesonet, check to see what’s available in your area. The added information is worth subscribing to.
    • Know the volatility of the product. Some pesticide active ingredients are volatile. This means they can evaporate from a wet or dry deposit during and after application (more here). Dicamba is a prominent example, but there are others, like trifluralin and ethalfluralin, 2,4-D and MCPA ester, and clomazone. Formulation can affect volatility, and the use of lower volatile esters of 2,4-D and better salts of dicamba have helped. Microencapsulation has been used to reduce the problem with clomazone. Volatility is strongly affected by surface temperature, and volatile products should not be sprayed on hot days or when the forecast calls for hot days following application. Volatile products have been found to evaporate from dry deposits for several days after application, and their vapours move under inversion conditions, causing widespread damage.

    Sun

    The sun plays a large role in spraying. Plants’ active growth improves herbicide translocation as well as activity in the photosystem, or in amino acid or fatty acid synthesis. The activity of herbicides has been shown to improve under sunny conditions for that reason.

    Some herbicides, most notably diquat (Reglone), work too quickly when it’s sunny, and improved performance can be gained by spraying under cloudy or low-light conditions. The lack of photosynthesis allows for some passive translocation before the product causes tissue necrosis.

    Sunny conditions also increase thermal turbulence we mentioned earlier, which is useful for burning off morning inversions. But what usually follows a sunny day is a strong inversion as the sun sets and the clear sky facilitates the earth’s rapid cooling. It would be possible to spray a bit later into the evening when it’s cloudy.

    Humidity

    Since about 99% of the spray volume is comprised of water, evaporation of this water can have strong effects on droplet behaviour. Droplets begin to evaporate as soon as they leave the nozzle, becoming smaller and more drift-prone while still in flight. Higher booms and finer sprays increase the flight-time of droplets, and this increases the sensitivity to evaporation.

    The most common measure of water in air is relative humidity (RH). RH doesn’t tell the whole story, though, because the same RH at different temperatures results in two different rates of water evaporation. A better measure is wet bulb depression. Wet bulb depression is defines as the difference in temperature reported by a dry bulb vs. a wet bulb thermometer. Wet bulb depression has more recently been coined as “Delta T” in Australia. The Delta T value is directly related to water evaporation, and charts have been published showing acceptable values for spraying. A Delta T of >10 ºC is considered too high.

    Figure 5: Delta T, also known as wet bulb depression, provides an indication of water evaporation rate.

    After they deposit on a leaf, droplets can evaporate to dryness within seconds, and a dry atmosphere can result in rapid drying that reduces herbicide uptake. In one study, a Group 2 herbicide was applied to weeds in a normal sized spray, and also as a fine mist, both under very dry conditions. The normal spray showed the expected herbicide efficacy. The finely misted herbicide had no effect on the weeds, likely because the rapid drying prevented uptake. Interestingly, the product began to work again when the plants were later placed in a humid environment.

    High humidity can also work against an application. Since humidity is often high during temperature inversions, droplets remain potent while they linger and drift over sensitive terrain. It would be better if they had evaporated and lost their effectiveness.

    Some proponents of low water volumes and fine sprays have suggested oily formulations or adjuvants prevent evaporation. While this may slow evaporation, it also creates a dangerous condition in which many small droplets remain aloft and liquid for a long time, with high activity on any target they may encounter. The bottom line: Don’t spray low volumes with oily adjuvants.

    The Perfect Day

    We know that the ideal spray day is sunny, starts a few hours after sunrise once the dew has mostly burned off, and has consistent winds away from sensitive areas. Spraying should end well before before sunset, before calm conditions signal the onset of the inversion.

    But what to do when that day never happens? All too often, high winds persist day after day, and night spraying is the only alternative. In that case, do what you can to minimize potential damage. Survey downwind areas. Choose cloudy skies that suppress inversions. Incoming weather systems are usually associated with consistent winds, and these may reduce inversion risk. If drift is a possibility, apply more water and use the coarser nozzles at your disposal to minimize it. Any investments made to boost productivity will pay dividends, allowing you to get a greater proportion of your work done when conditions are better.

    Additional Resource

    If you want an excellent resource for spray weather best practices, grab a free copy of Graeme Tepper’s “Weather Essentials for Pesticide Application” published by Australia’s GRDC.

  • Ten Tips for Spraying in the Wind

    Ten Tips for Spraying in the Wind

    Choosing the right time to spray can be tricky. Our gut tells us that spraying when it’s windy is wrong.  The experts tell us that spraying when it’s calm is wrong. So when can you actually spray?

    I’ve always advised my clients to spray in some wind, because it has a few advantages. The main one is that wind helps disperse the spray upward and downward, diluting the spray cloud fairly rapidly. Another advantage is that winds tend to be reasonably steady in their direction and velocity (or at least that can be forecast), so downwind areas can be identified and potential impacts are known or predictable. It helps if it’s sunny, because that improves the dispersion of the cloud even more.

    First, let’s define “windy”. The classic wind scale is the Beaufort Scale, intended for the sea, but also used on land. The upper limit for spraying is probably Force 3 or Force 4, with upper limits of 20 – 25 km/h or so.  The Beaufort Scale calls these “Gentle or Moderate Breezes” (they had to save the alarming words for hurricanes), and the scale provides good visual clues such as what wind does to flags, leaves, or dust.

    Beaufort Scale-1

    Spraying under breezy conditions can be done fairly safely if you follow specific steps. The idea is to understand what the risks are and to manage them.

    The cornerstone is to use a low-drift spray and match it to a pesticide that will work well with larger droplets. But there are other important aspects to consider. Below are the top ten to think about:

    • Choose a herbicide that can handle large droplets. Glyphosate products are well suited to coarse droplets. But glyphosate commonly has contact actives in the mix, members of Group 6, 14, and 15, and these are less likely to perform well with big droplets than those that contain Group 2 and 4 mixes. Actives with soil activity also have more tolerance for larger droplets.
    • Use a low-drift nozzle and operate it so it produces a Coarse (C) to Very Coarse (VC) spray quality, as described by the manufacturer. Dicamba labels call for Extremely Coarse (XC) to Ultra-Coarse (UC) sprays, and Enlist requires at least Coarse. To achieve these you may need to purchase new nozzles. Low-pressure air-induced nozzles operated at about 50 – 60 psi will generally be very low-drift, but lower drift models are available. If you need a finer spray, produce it either by increasing the pressure or moving to a finer tip. Do this when the weather improves, for contact modes of action.
    The name, symbol and range of droplet sizes used to describe the median droplet diameter produced by nozzles according to ASABE S572.3
    • Keep your boom low. Lowering the boom ranks as the second-most effective way to reduce drift, after coarser sprays. But there’s a limit. For low-drift sprays, you need at least 100% overlap (more for PWM), which is for the edge of one nozzle pattern to spray into the centre of the adjacent pattern. In other words, the spray pattern should be twice as wide as your nozzle spacing at target height.  For most nozzles, a boom height of close to 20 inches is enough to achieve this overlap. That’s pretty low by current standards from suspended booms on self-propelled sprayers, so being too low for a good pattern will only happen due to boom sway.
    • Maintain reasonably slow travel speeds. These reduce the amount of fine droplets that hang behind the spray boom, reduce turbulence from sprayer wheels, and they also make low booms more practical. An added bonus is less dust generation.
    • Know what’s downwind and what harms it. Survey the fields on all sides of the parcel you’re treating. When you have a choice, avoid spraying fields that have sensitive areas downwind such as water, shelterbelts, pastures, people, etc. If you can’t avoid being upwind of these areas, make sure you check and obey the buffer zone restrictions on the label. These will also give you an idea if the product can cause harm in water or on land, or both.
    • Consider a dicamba tip for special situations, even if you don’t use dicamba. If you’re in a situation where quitting and waiting is a poor option, these tips allow you to finish the job with minimal drift risk and with only slight reductions in product performance due to poor coverage.
    • Use a low-drift adjuvant. Specific products such as Interlock or Valid have been shown to reduce driftable fines (<150 microns) by between 40 – 60%, without adding significant volume in coarser droplets. The response will depend on the nozzle and the tank mix, but can be very noticeable.
    • Study drift and how it forms and moves. It’s about more than wind speed and droplet size. Knowledge in this area can help you work out the best strategies.
    • Invest in productivity. You may not need it every day, but on occasions when you have a small window to avoid bad weather, it pays dividends.
    • If you feel that drift is unavoidable and someone might be impacted by it, talk to those people first. It’s one of the most important things you can do.

    Keeping pesticide sprays on target continues to be one of our top responsibilities.

  • Fundamentals of Spray Drift

    Fundamentals of Spray Drift

    The year 1989 marked my first spray drift trial under the watchful eye of Dr. Raj Grover and John Maybank. We evaluated the performance of several spray shrouds, Flexi-Coil, AgShield, Brandt, and Rogers, and wanted to measure just how effective they were. But in my heart I wasn’t interested in drift. I wanted to study herbicide efficacy. Anyway, I thought, we’ll do this trial and I’m pretty sure we won’t have to revisit the topic.

    It’s now thirty-two years later and spray drift has interwoven itself into all my projects, remains one of the most powerful drivers of regulatory activity, is likely the most visible consequence of poor stewardship, and will stay as one of the dominant creators of public opinion around modern agricultural practice.

    Drift has not gone away. And yet our understanding of it is far from complete.

    Spray drift is defined as the wind-induced movement of the spray cloud away from the treated swath. Droplet drift can occur for all sprays, and it happens within minutes of the spray pass. Its cousin, vapour drift, is limited to active ingredients that are volatile, that is, they can evaporate from dry deposits after application. Vapour drift happens after the spray application is complete and can last several days.

    Droplet Drift

    Droplet drift can be divided into two phases that are separated by about 1 second and that are measured differently. “Initial drift” happens first and refers to the product that leaves the treated area immediately after atomization. It is airborne and can be measured by placing air-samplers (any device that can capture droplets in air) close to the downwind edge of the spray swath.

    Figure 1: Initial vs Secondary drift. Once the drift cloud leaves the treated swath, the relative strengths of turbulence and sedimentation determine the amount that remains airborne and the amount that lands downwind.

    Secondary drift describes the airborne spray cloud that continues to move downwind from the swath edge, where it either remains aloft or deposits on the surface below it. It is typically measured using samplers placed on the ground that capture sedimenting spray droplets. The difference in method is important because it goes to the heart of the problem of understanding spray drift.

    Figure 2: Droplet drift occurs when displacement energy exceeds droplet energy. The droplet’s combination of mass and velocity cannot withstand the energy presented by moving air.

    Initial drift is actually quite easy to understand because its creation is intuitive. The displacement of droplets from the spray plume is a function of balancing two types of energy. The first, droplet energy, is the product of droplet diameter and velocity. The more energy in the droplets, the more difficult they are to displace, and that’s why larger, heavier droplets or fast-moving air assist are useful drift reducing tools.  The second, displacement energy, comes from relative air movement, either from forward travel speed or wind and the associated turbulence. More wind or turbulence means more power to displace.

     Figure 3: Initial drift follows an expected response to greater wind speeds and coarser sprays. Data from a pull-type sprayer travelling 13 km/h with 60 cm boom height.

    Because initial drift is easier to understand, our most common advice for reducing drift is based on maximizing droplet energy and minimizing displacement energy. Lower booms, larger droplets, slower travel speeds, shrouds, or properly implemented air assist all help reduce initial drift. It makes sense that creating less initial drift will also reduce downwind deposition arising from secondary drift.

    Figure 4: Management of initial drift is intuitive. We reduce drift by adding energy to the droplet and by protecting the droplet from exposure to moving air.

    Downwind Deposition

    After leaving the spray swath, the moving secondary drift cloud has two main options. It can deposit or it can remain airborne. Basic physics suggest that all objects eventually fall to the ground, and since smaller objects need more time, they drift further. But when atmospheric turbulence and topography are considered, it’s not quite that simple. These two complicating factors control what proportion of the drift cloud remains airborne, and what proportion deposits.

    Drift trials show that about 20% of the initial drift amount returns to the surface within the first 100 m or so of the sprayer. The rest remains and rises in the atmosphere where it evaporates and gets mixed further.

    Figure 5: The majority of secondary drift remains airborne. Data are for Medium spray quality from a pull-type sprayer with 60 cm boom height and 13 km/h travel speed

    It happens quickly. Just 5 m downwind of the spray swath, the cloud is already 4 m tall. At 100 m downwind, we’ve measured its height to be 30 m.

    The proportion of the spray that remains airborne depends on the spray quality and the nature of the atmosphere. If it’s windy and sunny, or if the spray is finer, turbulence sends more into the air. If it’s cloudy and the wind is low, we have little atmospheric mixing. As a result, a smaller proportion will remain airborne and more will sediment, and overall, we may actually have more potential to damage downwind areas.

    When we graph spray drift deposit data from a windy day, the deposit amount decreases exponentially with downwind distance. Usually, drift damage follows the same pattern. The larger droplets that contain the majority of the dose deposit first. The smaller droplets go further and are more likely to mix in the atmosphere and rise with thermals.

    Figure 6: Deposited drift decreases logarithmically with distance. Top, linear axes. Bottom, log axes.

    Under temperature inversion conditions that are common on calm summer evenings, overnight, and early mornings, the damage from the drift cloud does not decrease the same way. The cloud containing the buoyant mist lingers over a large area. Without atmospheric mixing and its resulting dilution with time and distance, large areas can be damaged.

    The Effect of Turbulence on Deposition

    We’ve established that the more atmospheric mixing we have, the less spray will deposit on the ground, at least in the short term. How does this affect our thinking on the role of wind?

    When we evaluated drift data from a number of trials, we always saw more initial drift with higher wind speeds, as expected. However, the downwind deposit did not usually increase significantly. We attributed this observation to turbulence generated by wind which lifted more of the initial drift higher into the atmosphere. To be clear, deposited drift did not go down with higher wind. It just didn’t rise as fast as initial drift.

    Figure 7: The effect of wind speed on airborne drift (top line) vs deposited drift (bottom line) from a high clearance sprayer travelling 23 km/h and emitting a Very Coarse spray.

    The effect of turbulence can be viewed as a good thing because it protects downwind objects. Rapid dilution reduces immediate drift damage. We can use turbulence to protect objects on the ground. It’s certainly better than the alternative, emitting sprays when the atmosphere can’t dilute them, such as in an inversion. In that case, downwind areas remain at risk for a long distance, and for a long time.

    But we have to also consider what happens to airborne spray droplets. Some pesticides degrade in sunlight and stop being a problem. But others are more stable and may persist in the atmosphere for days or longer. During that time, they may move significant distances, ultimately returning to the earth’s surface in precipitation or in dust. Even though the atmosphere has diluted them, these deposits are measurable, and will show up in environmental monitoring of air, soil, and water.  We may not be able to find out where they originate, but the public knows who to blame. Agriculture.

    Vapour Drift

    Vapour drift is another issue altogether. It occurs hours and days after application, as long as the volatile product remains on a surface and conditions that allow formation of vapours persist. Vapour pressure is related to surface temperature, and losses increase with warmer surfaces. Some products enter the vapour phase when in contact with water, and release vapour after a rainfall.

    In situations where vapour is released for several days after application, it becomes impossible to control its subsequent movement. For droplet drift, if we know the wind direction at the time of spraying, we know where the impact is likely to be. But vapour movement depends on conditions that may occur between now and three days from now, and these could include high temperatures, various wind directions, and even inversions in which vapours accumulate. Ultimately, the best way to avoid off-target vapour movement is to avoid using volatile products.

    The Public Good

    Spray drift is one of agriculture’s most important stewardship challenges, and our industry needs to continue to improve its track record. Sprayers have a difficult task of converting a relatively small volume of liquid into a spray that offers good target coverage yet doesn’t move off the treated area. Favourable weather combined with droplet size management are at the heart of making this system work, but there isn’t a lot of wiggle room. Once again, an emphasis on sprayer productivity is one of the most fruitful areas to invest in, as this makes the best of the sometimes rare conditions in which spraying conditions are optimal.

  • What’s the Relationship Between Vapour Drift and Inversions?

    What’s the Relationship Between Vapour Drift and Inversions?

    Drift symptoms can take a few weeks to be discovered, and to figure out the cause, people need to reconstruct the conditions during the application in question. Wind direction is the easiest. But when we consider factors like inversions, volatility, calm conditions, and others used to explain the movement of pesticides, it can quickly become quite confusing.

    Let’s review how and why pesticides move.

    There are about six main ways that pesticides can move off-target.

    1. Droplet drift at the time of application;
    2. Vapour drift at or after the time of application;
    3. Pesticide movement in water (precipitation or runoff) after application;
    4. Dislodgeable residues from plant surfaces after application;
    5. Pesticide-containing soil movement after application;
    6. Pesticide residue in sprayers applied to another site.

    Whenever we find pesticides in a place where they do not belong, usually first indicated by plant symptoms specific to that herbicide, we need to find out the possible reasons and take steps to prevent that from happening again. We’ll focus on the first two items from the above list because those two are the most common.

    Droplet Drift: Sprayer nozzles produce droplet sizes ranging from 5 to 1000 µm, some up to 2500 µm. All nozzles, even the venerable low-drift tips recommended for dicamba application, will have a fraction of their volume in driftable droplets, say, less than 150 to 200 µm. For the low-drift sprays, that fraction is indeed very low, only a few percent of the total spray volume. For conventional nozzles, the driftable fraction may be 10 to 20% or more if high pressures are used.

    Tiny droplets have no energy of their own and move with the air mass they’re released into. If it’s windy, they move downwind. If the air is turbulent, they move up and down. If the atmosphere is stable, the buoyant fraction stays aloft and concentrated. So in order to understand their movement, we need to understand the atmosphere.

    Vapour Drift: Some chemicals are inherently volatile. This means they convert from the liquid or solid phase to a vapour phase on their own in accordance with temperature. Water is a great example, it is highly volatile. It is also able to sublimate, which means it can convert from a solid directly to a vapour without going through the liquid phase. An example of that is freezer burn, in which ice cubes shrink due to water escaping as a vapour.

    Volatile pesticides can also sublimate. On landing on a leaf or soil, a significant portion of a droplet is absorbed or adsorbed. Some fraction may dry on the leaf surface. This remaining solid can volatilize (form a vapour) for hours or days after application. The rate of evaporation is driven by two factors, (a) the background vapour pressure of the substance in the atmosphere, and (b) the surface temperature of the object the chemical is resting on. For water, the atmospheric vapour pressure can be expressed as relative humidity. Droplets evaporate slower when the atmosphere is already full of water.

    Pesticide evaporation is driven primarily by surface temperature. The background concentration of pesticide in the air is much lower than saturation, and has no effect. Pesticide evaporation is not directly affected by relative humidity because vapour pressures are independent of each other. In other words, most active ingredients will evaporate at the same rate whether the RH is 30% or 100% (it’s actually a bit more complicated than that. See the Note on Evaporation at the bottom of this article). This will be on the test, kids.

    Vapour losses can be minimized by choosing low-volatile pesticides and also by making the application on cooler days. We also need to watch the forecast and avoid spraying when tomorrow or the day after is forecast to be hot.

    Sometimes a rainfall can affect vapour losses, prompting a release of pesticide into the atmosphere. This behaviour can be predicted by the Henry’s Law Constant of a chemical.

    Inversions:  There are two types of turbulence, mechanical and thermal. Mechanical turbulence results from air encountering friction as it moves across a landscape. Taller objects and stronger winds result in greater mechanical turbulence. This turbulence creates small eddies that allow different layers of the atmosphere to communicate with each other and transfer momentum and contents up and down. More mechanical turbulence means more mixing and more sedimentation and dilution of a contaminant. In other words, the downwind impact of drift particles is reduced with greater mechanical turbulence. Mechanical turbulence happens whenever it’s windy, day or night, and it tends to counteract thermal turbulence.

    Thermal turbulence is more powerful than mechanical turbulence for dispersion of pollutants. Driven by the solar heating of the earth’s surface, that causes the lower atmosphere to be much warmer than the air higher up. The atmosphere normally cools the higher you go (at about 1°C/100 m, called the dry adiabatic lapse rate), but when it’s sunny, the gradient is greater. In other words, it cools faster because the air at the ground is warmer.

    Thermal effects move large parcels of air up and down, and we call this an unstable  or a turbulent atmosphere. When parcels of air rise and fall great distances, we get a powerful diluting effect which is usually associated with a breeze but can also happen under calm conditions. An unstable atmosphere is great at dispersing drift, minimizing its downwind impact. This can only happen during the daytime, is most powerful when it’s sunny, and almost never happens at night.

    By the way, a neutral atmosphere occurs when the rate of air cooling with height equals the adiabatic lapse rate described above. A neutral atmosphere can occur on cloudy days just before a rain, or on windy nights. There are no thermal effects in a neutral atmosphere, and the only dispersion occurs due to mechanical turbulence (windy conditions).

    A stable atmosphere (inversion) happens when there is no solar heating of the soil. In other words, it can only happen when the sun is low in the sky or at night. In this case, soil cools off and the cold soil cools air near it. As a result, the air temperature rises with elevation. Since it’s normal for air to cool with elevation (at the dry adiabatic laps rate mentioned earlier), the temperature profile is now…inverted. Hence the name “inversion”. To be clear (write this down kids, it’s on the test), an inversion describes an atmospheric condition in which (potential) temperature rises with elevation. That’s it. It rarely happens during the day, but is common on clear calm nights. (btw, “potential temperature is the temperature adjusted by its normal rate of cooling with height. To have thermal effects, the rate of cooling needs to be different from this rate.)

    The atmosphere is called stable because there is no thermal mixing. Air parcels stay put. Suspended particles such as tiny droplets stay put. Drift clouds stay concentrated, potent. If you make a fire, smoke hangs around. Cool, dense air is near the ground, and moves laterally very slowly, and might run downhill, like water, in a sloped setting. This situation is dangerous because it can move pesticide particles or vapours great distances without them becoming diluted or dispersed. An additional danger is that relative humidity is higher at night, delaying evaporation of water from the droplets. They stay potent.

    In Summary: Pesticides move in the atmosphere and are rapidly diluted by mechanical, and especially thermal, turbulence. That is why we like to see spray applications on sunny days with a nice breeze, which moves the product in a predictable direction and dilutes any drift rapidly along the way. We minimize particle drift through the usual measures such as the use of low booms, protective shields, slow travel speeds, and coarser sprays. We avoid spray application of volatile pesticides on or preceding hot days to minimize the risk of vapour drift. We do not apply pesticides when the atmosphere is stable (inversion), which usually means from just before sunset to just after dawn on a clear night.

    OK, that’s the basics. Now let’s explore some common questions.

    1. Can all pesticides move as particles and vapours? All pesticides that are atomized through a nozzle can move as particles. Only pesticides that are considered “volatile” can form significant amounts of vapour and move in that form. Dicamba is volatile. New dicamba formulations such as Xtendimax, FeXapan, and Engenia are much less volatile than older formulations, but they’re still capable of moving as vapours. Glyphosate and many other pesticides are not considered volatile and are not known to cause vapour drift.
    2. Are inversions only a problem for dicamba? Inversions affect droplet drift from all pesticides equally. The key difference is the amount of harm that any given droplet or vapour cloud can impart. Dicamba can harm conventional soybeans, many vegetable crops, and many trees and shrubs at extremely low doses. That means that even a weak inversion or a small amount of drift can cause great harm for long distances. In comparison, most other products are not as harmful to most of our crops in such small doses (I’m generalizing, forgive me). Tiny amounts may never be noticed, but they are there. Dicamba lets us notice these tiny amounts.
    3. Does vapour drift move only by inversions? No, although its movement is more damaging under inversions. Vapour drift clouds form above a recently sprayed canopy on hot days when leaf or soil surfaces contain a volatile product. On a sunny day (no inversion), this vapour will likely disperse rapidly downwind, causing diminishing damage with increased distance in relation to the sensitivity of the non-target plant. But towards evening, the dispersion (caused by thermal turbulence) ends as the sun sets and the atmosphere becomes stable. Now, the residual vapour cloud above the crop is no longer diluted, and may move in an unpredictable direction based on the slope of the land or a very gentle evening breeze. This movement may be significant, extending for miles in some cases, and potentially causing harm along the way.
    4. How long after application can vapour drift occur? Under most conditions, vapour losses diminish rapidly and will likely be gone within a few days as the pesticide is taken up by plants, metabolized, converted to a non-volatile form, etc. For some products, a light rainfall event can release a new wave of vapour drift because these products would rather be vapours than be dissolved in water, in accordance with their Henry’s Law Constant.
    5. Do some products drift further than others? Yes and no, but mostly no. Spray drift is a physical process governed by the behaviour of droplets in the atmosphere. Droplet diameter determines its mass and this mass controls the time it takes the droplet to sediment to the ground. The substance dissolved or suspended in that droplet has no bearing on this behaviour. But there are two key exceptions to consider. First, we know that some formulations generate more fine droplets than others even when atomized through the same nozzles. The greater abundance of small droplets will create more drift damage at any given distance, and also extend further downwind. And secondly, some formulations change the rate of water evaporation from the droplets. As a result, droplets moving downwind may shrink faster, in effect making them more drift prone and causing them to move further downwind. The same droplet size drifts the same distance, but droplet size changes. Question for the final: If you spray dicamba and glyphosate on the same day using the same nozzle, and the formulation has no impact on droplet size or evaporation, which one drifts further over a soybean crop? The answer is at the bottom of this article.
    6. Do calm conditions indicate an inversion? Inversions are defined as a temperature profile, not a wind condition. But the two are associated. An inversion is most pronounced and persists the longest under calm conditions, and because it suppresses atmospheric mixing, an inversion does prevent a windier upper atmosphere from reaching the ground. But it can be calm in the middle of the day with an unstable atmosphere. The calm condition eliminates mechanical turbulence, and therefore reduces the dispersion of the spray cloud. Calm conditions are also undesirable because the winds that follow a calm period are often unpredictable in direction, force, or duration. So it’s not a great idea to spray when it’s completely calm, even on a sunny day.
    7. Can inversions occur during the day? Yes, but it’s rare. Sometimes a large cold air mass moves into an area, say from a cool body of water, pushing warm air above it. So technically the air at the ground is cooler than the air above it, suppressing dispersion through that cap. Another situation is an inversion layer that forms at the top of a transpiring plant canopy. The air at ground level is warm, and cools suddenly where the crop evaporates water from its leaves. Air temperature rises with elevation above this transpiring layer, then cools again in accordance with an expected profile. So we have a thin layer in which vertical mixing is suppressed. This is most common in dense, thick canopies with adequate soil moisture on hot days.
    8. Is there an inversion every night? No. Cloud cover suppresses the rapid cooling of the soil, and the air at soil level stays warmer longer. Wind mixes the cold air layer into a warmer air layer, returning a more neutral condition. Inversions are most likely on clear nights with little wind. Recent data in inversion frequency from Missouri and North Dakota shows that inversions occur on the majority of nights, but the frequency depends on the location.
    9. Can drift be eliminated? Yes, we can eliminate spray drift by atomizing the spray in droplets (or, for dry soil-active products on carrier particles) large enough to resist movement in wind. We would need to be sure that absolutely no fine droplets or particles are produced, and that they don’t dislodge after application. That will require different atomizers and significantly more water volume and possibly new adjuvants. Some will argue that drift can also be eliminated by protecting the fine droplets with shields or air assist, but again, the protection would need to be 100%. Drift control has not been a high enough priority for these technologies to be developed and made available to applicators. Vapour drift can be eliminated by not applying volatile products.

    Pesticide movement in the atmosphere is complicated. But pesticides don’t just move as a result of vapour or droplet drift. Consider all the options when investigating an affected field. And let’s all work together to better understand pesticide movement and to prevent it.

    Answer: Both drift equally. But assuming the beans are susceptible to both herbicides, the dicamba damage will appear further downwind due to the greater sensitivity of the beans to this herbicide. This does not mean it drifted further.

    Note on Evaporation: There is some discussion about the role of relative humidity on vapour loss. Although we stated that RH plays no direct role in pesticide volatility, we need to qualify that.

    (a) Many pesticides dissolve in water. More water moves to plant or soil surfaces during periods of low RH, and this can carry dissolved pesticide with it. The supply of pesticide that can evaporate is thereby replenished.

    (b) Evaporation is driven by temperature and the concentration gradient between the source and the atmosphere. In still air, the air layers closest to the evaporating surface are most concentrated with evaporated pesticide, slowing further evaporation. Air movement will remove these layers, increasing the rate of evaporation.

    (c) co-distillation may occur for some pesticides. This means that the pesticide dissolved in water may evaporate with water, liberating it into the atmosphere. When co-distillation occurs, low RH would increase pesticide losses as well.

    We still have much to learn about these phenomena, especially as it affects new formulations.

  • Thermal Inversions for Sprayer Operators

    Thermal Inversions for Sprayer Operators

    In April 2014, NDSU extension published an excellent factsheet explaining what thermal inversions are, how to detect them and how they affect pesticide spray drift. That factsheet inspired this article.

    The Atmosphere

    The Earth is surrounded by a layer of air called the atmosphere. Think of it as a sheet of liquid percolating and flowing over the Earth’s surface. Seems a bit precarious, doesn’t it?

    We define “layers” of atmosphere based on their distance from the Earth’s surface (see image below). We’ll focus on the lowest part of the Earth’s atmosphere: the Surface Boundary Layer. As it drags along the Earth’s surface it experiences rapid changes in wind speed, temperature and humidity (on a time scale of an hour or less).

    The Earth’s Atmosphere. The illustration of the Earth is to scale, but the landscape is not. Our focus in on the Surface Boundary Layer.
    The Earth’s Atmosphere. The illustration of the Earth is to scale, but obviously the landscape is not. Our focus in on the Surface Boundary Layer.

    Atmospheric temperature

    In relatively calm, clear and dry conditions (e.g. a nice afternoon), air cools with elevation at a rate of about 1°C per 100m. This change is called the Adiabatic Lapse Rate and it’s caused by pressure changing with elevation. If your ears have popped when driving down a steep hill, you’ve experienced pressure change with elevation; there is more atmosphere overhead and the weight pushes down.

    With higher elevation, there is less atmosphere overhead. Less weight means less pressure and this gives air room to expand. Expansion takes work and work costs energy, which creates a cooling effect. See how simple thermodynamics are?

    In the graph below, the red line shows the Adiabatic Lapse Rate of air cooling with elevation. The blue line indicates wind stirring and homogenizing the atmosphere, reducing the degree of temperature change with elevation (more on that later).

    Day and night

    When we add the effect of daytime solar heating and nighttime cooling, the rate of temperature change is affected. Let’s consider how this works on a clear, relatively calm day:

    Early morning

    The morning sun emits short wave radiation, which is absorbed by the Earth’s surface. The surface conducts some of this energy deeper into the ground and also heats the air near the surface. This creates a temperature gradient wherein the surface is warmest and the air gets relatively cooler with elevation (remember the red line in the graph above).

    As the air near the surface warms, that energy causes air molecules to vibrate and push away from one another. Parcels of air become less dense and rise just like the gloop in a lava lamp. The cooler air around it falls to fill in the space left behind, and air begins to circulate in a Convection Cell. The rising parcel of air will eventually cool and shrink as it rises through the relatively cooler air above it.

    These convection cells create Thermal Turbulence, which is a very effective way for airborne particles, such as pesticide vapour, to be rapidly diluted. This is also how the atmosphere disperses pollution. More on the process of dispersion, later.

    Mid to late afternoon

    As the sun passes over and the wind starts to rise, the convection cells get disrupted by the wind and experience mechanical turbulence (remember the blue line in the graph above). So, mechanical turbulence also mixes warmer air near the ground with cooler air above it, but suppresses thermal turbulence.

    Mid-afternoon to night

    As the energy from the sun lessens, the soil begins to cool and so does the air next to it. Once the air cools enough to be colder than the air above it, we have the beginning of a Radiation Inversion, which is a specific kind of Thermal Inversion (see the green line in the graph below). It is called that because we now have the reverse of the typical day-time temperature profile. The height of the inversion (the ceiling) grows with time, and can reach a maximum of about 100m by sunrise. Within the inversion layer (before the green line bends back at 100m), turbulence is suppressed. We have a stable air mass. More on that below.

    How inversions affect dispersion

    The rising portion of a convection cell carries whatever particles are in the air with it. Suspended particles become much less concentrated at ground level thanks to the thermal turbulence.

    Thermal Turbulence allows particle-laden warm air to rise and clean cool air to fall. This disperses air-borne particles like dust or pollution.

    Now let’s imagine we are in a thermal inversion. The cooler, particle laden air near the ground cannot rise and the cleaner air above, which is now relatively warmer, cannot sink. Thermal turbulence is suppressed, and so is any vertical dispersion.

    Thermal Turbulence is suppressed during a Temperature Inversion. Particle-laden cool air at the surface cannot rise, and warm, clean air cannot fall. No dispersion occurs, and the concentrated, particle-laden air tends to move downhill or laterally with light winds.

    When spraying, the smallest spray droplets fall slowest, staying airborne for long periods of time. If spraying occurs during an inversion, those particles accumulate beneath the inversion layer. Remember we said our atmosphere behaves like a liquid? The colder, denser (pesticide-laden) air drains downhill into low-lying areas. It can also move laterally over great distances, in unpredictable directions, when light winds begin.

    Clouds

    If the morning were overcast instead of clear, the clouds would intercept much of the sun’s short-wave radiation, absorbing or reflecting it back into space. The Earth’s surface would still warm, but more slowly, suppressing thermal turbulence. As an aside, if clouds form in the evening, they reflect long-wave radiation from the Earth’s surface back down. This Greenhouse Effect is why overcast nights are warmer than clear ones.

    Therefore, extended periods of mostly clear skies in the evening or night means a high probability of strong temperature inversions. Conversely, cloud cover usually means a near-neutral atmosphere, so no strong inversion.

    Wind

    Inversions are only mildly affected by light wind (e.g. 6 to 8 km/h), but as the wind increases and mechanical turbulence mixes the air, the strength of the inversion will be reduced and the atmosphere will approach a neutral condition (see the blue line). In this condition, airborne particles are not dispersed by thermal turbulence, but some mixing will occur. So, there may not be a thermal inversion, but spraying would still be inadvisable if the wind got too high.

    Humidity

    Inversions form more rapidly when there is less water vapour in the air to absorb radiation. Once humid air has cooled to the dew point, water condensation gives off energy and warms the air a little. This slows the formation of the inversion. Be aware that inversion conditions can exist long before fog, dew or frost forms, so they are not a good indicator for the beginning of an inversion – you’re already in one!

    If you see fog, dew or frost, you’re already in an inversion. The air has become cold enough to condense or even freeze water.
    If you see fog, dew or frost, you’re already in an inversion. The air has become cold enough to condense or even freeze water.

    Soil conditions and topography

    This is a complex issue, but soil conditions that make inversions more intense include low soil moisture, freshly tilled soils, coarse soils, heavy residue and closed crop canopies. Topography matters, too. We’re discussing radiation inversions in arable regions, and the kind that form on mountains or deep valleys. Nevertheless, inversions in shaded areas (e.g., behind windbreaks) start sooner, and last longer. See the NDSU factsheet for more detail.

    Spray timing

    Inversions, once formed, persist until the sun rises and warms the Earth’s surface, or until winds increase and mix the stationary layers of air together, re-establishing a more neutral temperature profile.

    Sunset is not a good indicator of the beginning of an inversion – it can start a few hours before. Therefore, evening spraying may be just as risky as night spraying. Very early mornings (e.g. around sunrise) are not much better. Remember, at sunrise, the inversion will be at its maximum height.

    The rising sun will warm the earth and create turbulent conditions, starting near its surface (e.g. a few metres). Most inversions will have dissipated two hours after sunrise, which may be the best choice for spraying.

    Detecting an inversion

    The only sure way to know if you are in an inversion is to take two air temperature readings: one near the ground and one about three metres higher. If the surface air temperature is cooler, you are in an inversion. The magnitude of the difference indicates how strong the inversion is.

    Accurate measurements are difficult to manage with conventional thermometers, but SpotOn now makes a hand-held detection unit. If you have one, be sure to let it acclimate before you use it. Leaving it in a hot, or cold, truck or sprayer cab prior to use means it may give a false reading.

    Inversion forecasting is getting better, but it’s still location-specific and not entirely reliable. Sprayer operators should learn to watch for the following environmental cues:

    • Large temperature swings between daytime and the previous night.
    • Calm (e.g. less than 3 km/h wind) and clear conditions when the sun is low.
    • Intense high pressure systems (usually associated with clear skies) and low humidity where you intend to spray.
    • Dew or frost indicating cooler air near the ground (fog may be too late).
    • Smoke or dust hanging in the air or moving laterally.
    • Odours travelling large distances and seeming more intense.
    • Daytime cumulus clouds collapse toward the evening.
    • Overnight cloud cover is 25% or less.

    Note: If you suspect a temperature inversion, don’t spray.

    For more information on how weather affects drift, download this pamphlet from the Australian Government Bureau of Meteorology.