Tag: drift

The Most Important Developments in Spraying
Some things have improved a lot. Others have lost ground.
Some years ago, a few of us weed scientists sat around a table and debated the most important developments in agriculture in our lifetimes. It was a great discussion, and we arrived at a few that included direct seeding (for its soil and moisture conservation as well as improved fertilizer placement), GMO crops (for slowing Group 1 and 2 herbicide resistance), and the abandonment of summer fallow in much of western Canada. Let’s apply this exercise to spray application to see what we come up with.
What follows are my version of the most important spray technology developments in the last 50 years.
1. Low-drift Nozzles. Spray drift is the biggest time management challenge and also perhaps the biggest public relations battle. These nozzles reduce drift, making more time available for spraying and doing it safely and effectively.
2. Rate Controllers. I both love and hate these things. On the one hand, a rate controller matches sprayer output to travel speed. On the other, it has allowed spray pressures to go wherever they need, even beyond the optimum, to match travel speed, and that can lead to nozzle performance issues.
3. Pulse Width Modulation. The pulsing nozzle fixes the rate controller problem mentioned above. Now, travel speed and pressure are independent. Plus, of course, a whole host of other flow management options, such as turn compensation and rate boosting, become available.
4. Optical Spot Spraying. Once you see these in action, you can’t go back. Why would you spray a whole field when weeds only cover 10% of it? Products like WEEDit and WeedSeeker are proven green-on-brown performers after years of field success around the world.
5. GPS Guidance. Some of us grew up with foam or disk markers, others learned to aim for brave family members perched on headlands. Achieving accuracy was stressful, overlap was insurance, and misses were common. The importance of this development is probably under-estimated.
6. Sectional Control. The ability to adjust the spray width in individual nozzle steps makes sense, and this can come with or without PWM. In fact, that alone can save 5% of an annual chemical bill compared to conventional sections measuring about 10 to 15 feet. And it’s definitely better than the left boom or right boom options from the 70 and 80s.
7. Operator Comfort and Safety. The refuge of the cab makes longer days bearable for all equipment, but for spraying it dramatically improves safety as well.
But we’re far from done. We still need work in these areas.
1. Cleaning and Waste Management. I can’t imagine another industry where managing potentially hazardous leftover materials are left to the discretion and circumstances of the applicator. Let’s make it easy and fast to thoroughly clean the sprayer and safely dispose of leftovers. Step 1 is smarter and simpler plumbing.
2. Boom Stability. Booms are too high, resulting in more drift and poorer nozzle performance, and adding to operator stress. The sole reason is unsatisfactory levelling. It’s possible to solve this, but it seems to not be a priority.
3. Weight. The road to productivity seems to be paved with larger, heavier machines. The side effects are fuel consumption, compaction, getting stuck. Let’s get smarter with frame design and logistics and talk acres/h rather than tank capacity and power.
4. Cost. All farm equipment has seen cost increases that far outstrip inflation or any reasonable accounting of productivity and features. Sprayers lead the way. Yes, it’s possible to spins this as a value proposition. But it shouldn’t be necessary.
5. Drift Management. Sprayer design continues to ignore drift management. We need sprayers that produce less drift by design, and this requires consideration of tractor unit, wheel, and boom aerodynamics. It’s more than a droplet size issue.
6. Direct Injection. Although very handy for single product application, the plethora of product formulations and mixes has limited the success of direct injection systems. The complexity of injecting at the nozzle, and the resulting lack of available systems, has stymied some very attractive options, such as site-specific rate or product use.
7. Ergonomics. If you need training, or to call someone before using your new sprayer for the first time, something’s wrong. Interfaces need to be intuitive and simple. The golden age of spray monitors was the 1980s. Those featured a main power toggle switch, a pump power switch, boom section switches, an agitation switch, and a simple way to enter the important information which was basically desired application volume. The screen can still be pretty, and you can still paint and monitor or tweak all the functions if you like that. But let’s at least have different tiers so beginners can also use the machine. Make interfaces using the philosophy Steve Jobs instilled in his trusted designer Jony Ive with the first iPod: no more than three clicks to achieve any desired outcome.
A few areas show promise and may suit certain niches.
1. In-Crop Weed Sensing. The green-on-green sensing that has been made possible by machine learning has shown some encouraging early success. Continuing improvements will eventually bring its reliability to within commercially acceptable standards. There is significant activity below the radar in this area, as all players recognize the enormous upside of a breakthrough.
2. Autonomy. While dispensing a pesticide adjacent to sensitive areas isn’t exactly the low-hanging fruit of autonomy, such field sprayers will have a fit in the temperate plains of North and South America, Australia, and Asia and may help solve the cost and weight problem.
3. Drone Application. The rapid pace of advancement in remotely piloted aerial systems, along with a seemingly low barrier to entry of new companies, will put pressure on the industry to make a decision on this alternate application method. If it can be done safely, it will have a dramatic impact.
If you want to improve your sprayer, don’t ignore the small things you can do in your operation. Although we’re conditioned to look for game-changing technology, the most sustained improvements don’t come from a single innovation, but from a period of persistent evolution. A lot of small improvements add up. Spray application is no different.
October 7, 2020
We Need Better Drift Control Technologies
Sprayer manufacturers have all but offloaded the entire responsibility for drift management to the sprayer nozzle. It’s asking too much.
Sprayers have changed a lot over the past 25 years. They have become larger, with more tank capacity, boom width, and, if self-propelled, horsepower. They are more comfortable and ergonomic, with more sophisticated swath control and guidance systems. But every year, a very important deficiency in their design becomes obvious. Drift control.
The changes described above are intended to improve productivity and fight operator fatigue. Today’s sprayer can cover more ground than ever before. But the demand to cover ground, through a combination of growth in farm size and frequency of treatment, has outpaced machine productivity. As a result, operators find themselves ever further in a time deficit, with acres on the to do list and no time to get the work done.
Spray drift remains the single most limiting factor to the safe application of pesticides. Spraying cannot happen when it’s too windy or during inversions because all agricultural nozzles produce fine droplets whose movement in the atmosphere cannot be controlled . This has been an issue since spraying began.
Simply put, pesticides belong in one place only, and that is on the treated swath. Applicators have some tools to make this happen, such as using coarser sprays, lowering the booms, choosing very specific weather conditions, and the like. But when winds are incessant, and crops and pests are quickly growing out of the treatable stages, what is an applicator to do? There is only one thing they can do: lower their standards. Either miss the treatment and suffer the yield loss, or spray in the wind and hope nothing bad happens.
Neither of these options are acceptable.
There isn’t an easy fix. Spraying is a game of tight margins. The spray liquid in the tank must be atomized in droplets that can make their way to the target and provide adequate coverage when they get there. The total liquid volume to achieve that task must also be practical. The global ag industry has determined, over the past 100 years, that about 100 to 200 L/ha, 10 to 20 gallons per acre, is the ballpark amount that allows reasonable work rates with sprays that are just coarse enough to resist displacement in modest winds. If it gets windier and we need even coarser sprays, we need to add more water to maintain an acceptable droplet density on the targets. And of course, the droplets need to stick to those targets, so there is a limit how coarse we can spray.
Over the past 20 years, we’ve been asking the low-drift nozzle to do the heavy lifting in drift management, and it has served us well. But with a return to more contact modes of action for resistance management, there’s a need to retain good coverage for product performance.
What ag needs is a drift-reducing technology that is better than the low-drift nozzle. We need a technology that maintains a practical water volume limit and combines this with intermediate spray qualities that generate good pesticide efficacy without allowing drift under windy conditions.
These technologies need to do just one of three things: (a) Protect the driftable droplets from exposure to moving air with a physical barrier, (b) make driftable droplets less drift-prone by increasing their velocity, or (c) eliminate the driftable droplets altogether.
Let’s have a look at some options, and explore the pros and cons.
- Shields and Cones. A shroud surrounding the boom was first proposed and built in the 1950s in the UK by Dr. Walter Ripper. Although never commercial, his “Nodrif” boom inspired an entire industry that took hold in western Canada in the 1980s and 1990s. Shrouding worked. In studies conducted at Ag Canada, shrouds produced by Flexi-Coil, Rogers Engineering, AgShield, and Brandt reduced drift by up to 80%. But shrouds disappeared in the 90s, partly because of the advent of tight-folding suspended booms where they posed a problem, but also because of crop contamination from the shrouds and poor nozzle visibility in case of plugs.
  
  The advent of the air-induced low-drift nozzle offered an alternative, but coarseness has been taken to its practical limit. What about a newly engineered version of shrouds that addresses its shortcomings? Willmar Fabrication has created the Redball Buffer Sprayer, for example. We see hooded sprayers in row crops. But there may be other ideas. The simple device called the PatternMaster introduced by KB Industries a few years back was also a step in that direction. Let’s keep working on this.
Figure 1: Shrouded booms, once common on the prairies and proven effective (Brandt cones, top), are still used on research sprayers (bottom).
- Air Assist. Small drops don’t drift just because they’re small. They drift because they have very little kinetic energy, and they get blown off course easily. Speed them up, and that problem is solved. Introducing an air stream at the nozzle can do just that. Furthermore, air assist also enhances canopy penetration, a problem that we currently attempt to address with the addition of more water. Again, this idea is not new. Hardi, once the world’s largest sprayer manufacturer, has had the TwinForce boom available for decades. An inflatable bag is positioned over the boom. Openings along the bottom direct the air down. The operator turns a knob in the cab to control fan speed, and another for forward or backward angle, until the combination is suited to the canopy and the travel speed. The SprayAir, out of Carseland, AB (purchased by Miller and still available) was a less elegant version because they chose an air-shear atomizer that sometimes required more air than was prudent. Too much air rebounds off the ground, increasing the drift issue. Their Trident boom, allowing a hydraulic nozzle to be used with air assist, continues to have potential. Air bag type air assist systems were also available from other manufacturers, but none were ever commercially successful.
Figure 2: Air assisted booms such as this Hardi TwinForce accelerate small droplets, reducing their drift-potential and improving canopy penetration (Source: Hardi Sprayers)
- Low Booms. How low can booms go? It depends on the nozzle spacing and fan angle. Horsch claims that with a good boom package, this is an option. They are offering 10” spacing, and with wide fan angles, booms as low as 15” would still provide good overlap. Hands up who will try this at 18 mph. Wingssprayer has an interesting design where the boom rests on backswept plastic sheets, providing a physical barrier and a low height.
Figure 3: Low booms can significantly reduce drift, but their success depends on superior stability and height control (Top, Source: Horsch Sprayers; Bottom, Source: Wingssprayer)
- Twin Fluid Atomizer. In this atomizer type, both air and liquid are forced out through the same nozzle. The ratio of air and liquid determines the liquid flow rate and the degree of atomization. First introduced by Cleanacres in the UK as the Airtec, improved by Harry Combellack in Australia over many years, and making a re-appearance with the Dutch manufacturer Agrifac, it’s been one of my favourite atomizers, mostly in theory. The small amount of air moving through each nozzle is not enough for serious air-assist, but the idea is good and perhaps it can be improved.
- Electrostatics. Forget about it for drift control. The attractive force is so weak that it only works for very small droplets over short distances. It needs air-assist to work properly. See point #2.
- Rotary Atomizer. These are all the rage on aircraft these days, offering a more consistent droplet size range that eliminates the largest, water-wasting droplets, and curtails many of the smallest droplets produced by hydraulic atomizers. These attributes are powerful and address the fundamental problem: If the small droplets drift, then let’s not produce them. In reality, rotary atomizers are used mainly to produce smaller droplets to save water in the aerial business, not really solving the drift problem. In the 1970s and 80s, the concept was advanced by Micron Corporation, led by Ed Bals and later by his son Tom. Although very successful in forestry and hand-held applications in arid regions where water posed a serious limitation, the transition to boom spraying never happened.
Figure 4: Rotary atomizers can eliminate larger droplets and sharply reduced the smallest ones, leaving a more uniform sized distribution (insert). They are used on aircraft to save water, but have not been adopted on ground equipment to control drift.
- A new Atomizer. This is my Hail Mary. All hydraulic nozzles produce a wide variety of droplet sizes, and that is a problem. Even the venerable dicamba nozzles that create Extremely Coarse and Ultra Coarse sprays produce some fines that drift in inversions. The idea put forth by Ed Bals, to eliminate the problematic size ranges, is sound. But the rotary atomizer is hard to implement on a boom sprayer. Can there be an innovation that maintains a simple overall design, produces a narrow, but low-drift droplet size range, and mates it to a bit of air assist to get the spray where it belongs? Absolutely.
Figure 5: Current hydraulic atomizers tend to produce a wide range of droplet sizes. The distribution on the left results in significant drift (droplets <150 µm). The one on the right wastes the larger droplets (droplets >600 µm. The narrower span in the centre distribution avoids these problem areas and delivers the spray in an efficacious portion.
To create value for farmers you first need to understand farmers’ priorities and problems. Getting the spraying job completed on time often means squeezing the work into ever narrower time frame, between rains, between winds in the afternoons and inversions that same evening, between too much dew and too dry, between too early and too late. I am looking forward to the day when engineering resources are allocated to address these issues better, protecting both the environment and the stress levels on the farm.
July 30, 2020
What’s the Relationship Between Vapour Drift and Inversions?
Drift symptoms can take a few weeks to be discovered, and to figure out the cause, people need to reconstruct the conditions during the application in question. Wind direction is the easiest. But when we consider factors like inversions, volatility, calm conditions, and others used to explain the movement of pesticides, it can quickly become quite confusing.
Let’s review how and why pesticides move.
There are about six main ways that pesticides can move off-target.
1. Droplet drift at the time of application;
2. Vapour drift at or after the time of application;
3. Pesticide movement in water (precipitation or runoff) after application;
4. Dislodgeable residues from plant surfaces after application;
5. Pesticide-containing soil movement after application;
6. Pesticide residue in sprayers applied to another site.
Whenever we find pesticides in a place where they do not belong, usually first indicated by plant symptoms specific to that herbicide, we need to find out the possible reasons and take steps to prevent that from happening again. We’ll focus on the first two items from the above list because those two are the most common.
Droplet Drift: Sprayer nozzles produce droplet sizes ranging from 5 to 1000 µm, some up to 2500 µm. All nozzles, even the venerable low-drift tips recommended for dicamba application, will have a fraction of their volume in driftable droplets, say, less than 150 to 200 µm. For the low-drift sprays, that fraction is indeed very low, only a few percent of the total spray volume. For conventional nozzles, the driftable fraction may be 10 to 20% or more if high pressures are used.
Tiny droplets have no energy of their own and move with the air mass they’re released into. If it’s windy, they move downwind. If the air is turbulent, they move up and down. If the atmosphere is stable, the buoyant fraction stays aloft and concentrated. So in order to understand their movement, we need to understand the atmosphere.
Vapour Drift: Some chemicals are inherently volatile. This means they convert from the liquid or solid phase to a vapour phase on their own in accordance with temperature. Water is a great example, it is highly volatile. It is also able to sublimate, which means it can convert from a solid directly to a vapour without going through the liquid phase. An example of that is freezer burn, in which ice cubes shrink due to water escaping as a vapour.
Volatile pesticides can also sublimate. On landing on a leaf or soil, a significant portion of a droplet is absorbed or adsorbed. Some fraction may dry on the leaf surface. This remaining solid can volatilize (form a vapour) for hours or days after application. The rate of evaporation is driven by two factors, (a) the background vapour pressure of the substance in the atmosphere, and (b) the surface temperature of the object the chemical is resting on. For water, the atmospheric vapour pressure can be expressed as relative humidity. Droplets evaporate slower when the atmosphere is already full of water.
Pesticide evaporation is driven primarily by surface temperature. The background concentration of pesticide in the air is much lower than saturation, and has no effect. Pesticide evaporation is not directly affected by relative humidity because vapour pressures are independent of each other. In other words, most active ingredients will evaporate at the same rate whether the RH is 30% or 100% (it’s actually a bit more complicated than that. See the Note on Evaporation at the bottom of this article). This will be on the test, kids.
Vapour losses can be minimized by choosing low-volatile pesticides and also by making the application on cooler days. We also need to watch the forecast and avoid spraying when tomorrow or the day after is forecast to be hot.
Sometimes a rainfall can affect vapour losses, prompting a release of pesticide into the atmosphere. This behaviour can be predicted by the Henry’s Law Constant of a chemical.
Inversions: There are two types of turbulence, mechanical and thermal. Mechanical turbulence results from air encountering friction as it moves across a landscape. Taller objects and stronger winds result in greater mechanical turbulence. This turbulence creates small eddies that allow different layers of the atmosphere to communicate with each other and transfer momentum and contents up and down. More mechanical turbulence means more mixing and more sedimentation and dilution of a contaminant. In other words, the downwind impact of drift particles is reduced with greater mechanical turbulence. Mechanical turbulence happens whenever it’s windy, day or night, and it tends to counteract thermal turbulence.
Thermal turbulence is more powerful than mechanical turbulence for dispersion of pollutants. Driven by the solar heating of the earth’s surface, that causes the lower atmosphere to be much warmer than the air higher up. The atmosphere normally cools the higher you go (at about 1°C/100 m, called the dry adiabatic lapse rate), but when it’s sunny, the gradient is greater. In other words, it cools faster because the air at the ground is warmer.
Thermal effects move large parcels of air up and down, and we call this an unstable or a turbulent atmosphere. When parcels of air rise and fall great distances, we get a powerful diluting effect which is usually associated with a breeze but can also happen under calm conditions. An unstable atmosphere is great at dispersing drift, minimizing its downwind impact. This can only happen during the daytime, is most powerful when it’s sunny, and almost never happens at night.
By the way, a neutral atmosphere occurs when the rate of air cooling with height equals the adiabatic lapse rate described above. A neutral atmosphere can occur on cloudy days just before a rain, or on windy nights. There are no thermal effects in a neutral atmosphere, and the only dispersion occurs due to mechanical turbulence (windy conditions).
A stable atmosphere (inversion) happens when there is no solar heating of the soil. In other words, it can only happen when the sun is low in the sky or at night. In this case, soil cools off and the cold soil cools air near it. As a result, the air temperature rises with elevation. Since it’s normal for air to cool with elevation (at the dry adiabatic laps rate mentioned earlier), the temperature profile is now…inverted. Hence the name “inversion”. To be clear (write this down kids, it’s on the test), an inversion describes an atmospheric condition in which (potential) temperature rises with elevation. That’s it. It rarely happens during the day, but is common on clear calm nights. (btw, “potential temperature is the temperature adjusted by its normal rate of cooling with height. To have thermal effects, the rate of cooling needs to be different from this rate.)
The atmosphere is called stable because there is no thermal mixing. Air parcels stay put. Suspended particles such as tiny droplets stay put. Drift clouds stay concentrated, potent. If you make a fire, smoke hangs around. Cool, dense air is near the ground, and moves laterally very slowly, and might run downhill, like water, in a sloped setting. This situation is dangerous because it can move pesticide particles or vapours great distances without them becoming diluted or dispersed. An additional danger is that relative humidity is higher at night, delaying evaporation of water from the droplets. They stay potent.
In Summary: Pesticides move in the atmosphere and are rapidly diluted by mechanical, and especially thermal, turbulence. That is why we like to see spray applications on sunny days with a nice breeze, which moves the product in a predictable direction and dilutes any drift rapidly along the way. We minimize particle drift through the usual measures such as the use of low booms, protective shields, slow travel speeds, and coarser sprays. We avoid spray application of volatile pesticides on or preceding hot days to minimize the risk of vapour drift. We do not apply pesticides when the atmosphere is stable (inversion), which usually means from just before sunset to just after dawn on a clear night.
OK, that’s the basics. Now let’s explore some common questions.
1. Can all pesticides move as particles and vapours? All pesticides that are atomized through a nozzle can move as particles. Only pesticides that are considered “volatile” can form significant amounts of vapour and move in that form. Dicamba is volatile. New dicamba formulations such as Xtendimax, FeXapan, and Engenia are much less volatile than older formulations, but they’re still capable of moving as vapours. Glyphosate and many other pesticides are not considered volatile and are not known to cause vapour drift.
2. Are inversions only a problem for dicamba? Inversions affect droplet drift from all pesticides equally. The key difference is the amount of harm that any given droplet or vapour cloud can impart. Dicamba can harm conventional soybeans, many vegetable crops, and many trees and shrubs at extremely low doses. That means that even a weak inversion or a small amount of drift can cause great harm for long distances. In comparison, most other products are not as harmful to most of our crops in such small doses (I’m generalizing, forgive me). Tiny amounts may never be noticed, but they are there. Dicamba lets us notice these tiny amounts.
3. Does vapour drift move only by inversions? No, although its movement is more damaging under inversions. Vapour drift clouds form above a recently sprayed canopy on hot days when leaf or soil surfaces contain a volatile product. On a sunny day (no inversion), this vapour will likely disperse rapidly downwind, causing diminishing damage with increased distance in relation to the sensitivity of the non-target plant. But towards evening, the dispersion (caused by thermal turbulence) ends as the sun sets and the atmosphere becomes stable. Now, the residual vapour cloud above the crop is no longer diluted, and may move in an unpredictable direction based on the slope of the land or a very gentle evening breeze. This movement may be significant, extending for miles in some cases, and potentially causing harm along the way.
4. How long after application can vapour drift occur? Under most conditions, vapour losses diminish rapidly and will likely be gone within a few days as the pesticide is taken up by plants, metabolized, converted to a non-volatile form, etc. For some products, a light rainfall event can release a new wave of vapour drift because these products would rather be vapours than be dissolved in water, in accordance with their Henry’s Law Constant.
5. Do some products drift further than others? Yes and no, but mostly no. Spray drift is a physical process governed by the behaviour of droplets in the atmosphere. Droplet diameter determines its mass and this mass controls the time it takes the droplet to sediment to the ground. The substance dissolved or suspended in that droplet has no bearing on this behaviour. But there are two key exceptions to consider. First, we know that some formulations generate more fine droplets than others even when atomized through the same nozzles. The greater abundance of small droplets will create more drift damage at any given distance, and also extend further downwind. And secondly, some formulations change the rate of water evaporation from the droplets. As a result, droplets moving downwind may shrink faster, in effect making them more drift prone and causing them to move further downwind. The same droplet size drifts the same distance, but droplet size changes. Question for the final: If you spray dicamba and glyphosate on the same day using the same nozzle, and the formulation has no impact on droplet size or evaporation, which one drifts further over a soybean crop? The answer is at the bottom of this article.
6. Do calm conditions indicate an inversion? Inversions are defined as a temperature profile, not a wind condition. But the two are associated. An inversion is most pronounced and persists the longest under calm conditions, and because it suppresses atmospheric mixing, an inversion does prevent a windier upper atmosphere from reaching the ground. But it can be calm in the middle of the day with an unstable atmosphere. The calm condition eliminates mechanical turbulence, and therefore reduces the dispersion of the spray cloud. Calm conditions are also undesirable because the winds that follow a calm period are often unpredictable in direction, force, or duration. So it’s not a great idea to spray when it’s completely calm, even on a sunny day.
7. Can inversions occur during the day? Yes, but it’s rare. Sometimes a large cold air mass moves into an area, say from a cool body of water, pushing warm air above it. So technically the air at the ground is cooler than the air above it, suppressing dispersion through that cap. Another situation is an inversion layer that forms at the top of a transpiring plant canopy. The air at ground level is warm, and cools suddenly where the crop evaporates water from its leaves. Air temperature rises with elevation above this transpiring layer, then cools again in accordance with an expected profile. So we have a thin layer in which vertical mixing is suppressed. This is most common in dense, thick canopies with adequate soil moisture on hot days.
8. Is there an inversion every night? No. Cloud cover suppresses the rapid cooling of the soil, and the air at soil level stays warmer longer. Wind mixes the cold air layer into a warmer air layer, returning a more neutral condition. Inversions are most likely on clear nights with little wind. Recent data in inversion frequency from Missouri and North Dakota shows that inversions occur on the majority of nights, but the frequency depends on the location.
9. Can drift be eliminated? Yes, we can eliminate spray drift by atomizing the spray in droplets (or, for dry soil-active products on carrier particles) large enough to resist movement in wind. We would need to be sure that absolutely no fine droplets or particles are produced, and that they don’t dislodge after application. That will require different atomizers and significantly more water volume and possibly new adjuvants. Some will argue that drift can also be eliminated by protecting the fine droplets with shields or air assist, but again, the protection would need to be 100%. Drift control has not been a high enough priority for these technologies to be developed and made available to applicators. Vapour drift can be eliminated by not applying volatile products.
Pesticide movement in the atmosphere is complicated. But pesticides don’t just move as a result of vapour or droplet drift. Consider all the options when investigating an affected field. And let’s all work together to better understand pesticide movement and to prevent it.
Answer: Both drift equally. But assuming the beans are susceptible to both herbicides, the dicamba damage will appear further downwind due to the greater sensitivity of the beans to this herbicide. This does not mean it drifted further.
Note on Evaporation: There is some discussion about the role of relative humidity on vapour loss. Although we stated that RH plays no direct role in pesticide volatility, we need to qualify that.
(a) Many pesticides dissolve in water. More water moves to plant or soil surfaces during periods of low RH, and this can carry dissolved pesticide with it. The supply of pesticide that can evaporate is thereby replenished.
(b) Evaporation is driven by temperature and the concentration gradient between the source and the atmosphere. In still air, the air layers closest to the evaporating surface are most concentrated with evaporated pesticide, slowing further evaporation. Air movement will remove these layers, increasing the rate of evaporation.
(c) co-distillation may occur for some pesticides. This means that the pesticide dissolved in water may evaporate with water, liberating it into the atmosphere. When co-distillation occurs, low RH would increase pesticide losses as well.
We still have much to learn about these phenomena, especially as it affects new formulations.
July 14, 2020
Don’t try this tempting shortcut
There’s a call that I’ve been getting for 20 years now. It came again this week. Someone has a twincap with two small air-induced tips, and they’re applying herbicides and fungicides with low water volumes, often 5 gpa, sometimes less. They call because they want to know how much wind they can spray in. Is 30 km/h OK? They want my blessing.
I don’t need to hear much more. Some nozzles are sold entirely on the premise that they provide superior coverage – more droplets per square inch – and that this improved coverage permits the reduction of water volumes. Furthermore, the claim goes, when water is reduced, the spray concentration increases and the whole darn package just works a lot faster and better.
This line of thinking is as old as spraying itself. Applicators seek pesticide performance as well as productivity, and this approach gives them both. The proponents are well aware of their customers’ desires, and sell into it. “Use these tips and cut back on water. Any more than this just runs off anyways. You’ll get better coverage and better performance, get more spraying done.” It’s a convincing argument. Get an edge on your neighbour, the person who’s not in on the secret and is wasting time and water.
Why don’t I embrace it? There are a few reasons.
First, it doesn’t tell the whole story. Invariably it involves a twin nozzle setup. Use two nozzles, get more droplets, right? If that were true, believe me, I’d be advocating for quintuples.
Fact is that the only factors that change droplet numbers are droplet size (spray quality) and water volume. Want more droplets at the same water volume? Make the spray finer. Want to keep spray quality and add droplets? Add water (not nozzles).
The easiest way to improve coverage at the same volume is to use a finer nozzle, or to increase spray pressure. Depending on how far you go, you could make the spray finer and cut water, and still have more droplets per square inch.
The hardest way to improve coverage is to purchase a twincap and buy two nozzles, each of them half the size. True, within any given nozzle type, smaller sized tips usually generate finer sprays. But why bother with two tips? They’re more expensive and plug more.
If someone asks me how to improve coverage without changing water volume, I usually tell them to speed up a few mph. The rate controller will increase pressure and the spray gets finer. If speeding up is not possible, get one size smaller nozzle and run at higher pressure, same speed. Or keep nozzle and speed, and add some gpa, pressure will go up. It’s that easy. No twins necessary.
Second, the twin nozzle/low volume approach exaggerates the value of the twin nozzle for herbicides. With small plants and relatively open canopies in the early season, plus our high booms and travel speeds, the twin tips are not adding a lot, if anything at all, to coverage. It remains a sum of droplet size and water volume, the angle is not important at this stage. Deposit is by turbulence and wind, most of the time.
Third, low volume believers ignore a few potential problems. Drift is a big one. Low volume, fine spray operators are surrounded by nervous neighbours. They have fewer hours per day during which drift is acceptably low. And they definitely should not be on the field when wind is at 30 km/h. Basically, they’re a bit uncomfortable (at least they should be) and get less done per day.
Another potential problem is evaporation. Most sprays, even when applied at lower volumes, are still 90% or more water. The same volume of water evaporates much quicker when atomized into smaller droplets. This has two main downsides: On their way to the canopy, small droplets evaporate and become even more drift prone, and may not impact at all. Those that impact evaporate shortly thereafter. Research has shown that pesticide uptake is better from wet than dry deposits.
When Delta T (dry bulb minus wet bulb temperature) is high, evaporation can be so strong that it reduces pesticide performance or causes solvent burn. Fine sprays make it worse.
I also hear about the use of oily adjuvants to control evaporation from small droplets. This could be even more dangerous. Small droplets drift, and evaporation to dryness is actually helpful in reducing the impact of that drift. How? It makes the small droplets disappear, with their remnants dispersing into the turbulent atmosphere. With oily adjuvants, the small droplets stick around and stay potent and their drift damage is much worse.
Lastly, the practice is possibly off label. Water volume and spray quality label statements are designed to offer good performance and acceptable drift risk. While that part of the label is often a bit dated, it does provide better support from the manufacturer should something go wrong.
If you’re spraying under hot, dry and windy conditions, the low volume, fine spray approach is irresponsible. Use sufficient water (7 to 12 gpa) to allow low-drift sprays, at least Coarse to Very Coarse, in some case, even coarser.
Agronomists provide the best possible information for their clients, based on scientific evidence and experience and in accordance with their professional code of ethics. Sometimes the news we deliver aren’t what the customer wants to hear. But we have to represent the interests of all of us, collectively. I find that pretty important.
June 12, 2020
Thermal Inversions for Sprayer Operators
In April 2014, NDSU extension published an excellent factsheet explaining what thermal inversions are, how to detect them and how they affect pesticide spray drift. That factsheet inspired this article.
The Atmosphere
The Earth is surrounded by a layer of air called the atmosphere. Think of it as a sheet of liquid percolating and flowing over the Earth’s surface. Seems a bit precarious, doesn’t it?
We define “layers” of atmosphere based on their distance from the Earth’s surface (see image below). We’ll focus on the lowest part of the Earth’s atmosphere: the Surface Boundary Layer. As it drags along the Earth’s surface it experiences rapid changes in wind speed, temperature and humidity (on a time scale of an hour or less).
The Earth’s Atmosphere. The illustration of the Earth is to scale, but obviously the landscape is not. Our focus in on the Surface Boundary Layer.
Atmospheric temperature
In relatively calm, clear and dry conditions (e.g. a nice afternoon), air cools with elevation at a rate of about 1°C per 100m. This change is called the Adiabatic Lapse Rate and it’s caused by pressure changing with elevation. If your ears have popped when driving down a steep hill, you’ve experienced pressure change with elevation; there is more atmosphere overhead and the weight pushes down.
With higher elevation, there is less atmosphere overhead. Less weight means less pressure and this gives air room to expand. Expansion takes work and work costs energy, which creates a cooling effect. See how simple thermodynamics are?
In the graph below, the red line shows the Adiabatic Lapse Rate of air cooling with elevation. The blue line indicates wind stirring and homogenizing the atmosphere, reducing the degree of temperature change with elevation (more on that later).
Day and night
When we add the effect of daytime solar heating and nighttime cooling, the rate of temperature change is affected. Let’s consider how this works on a clear, relatively calm day:
Early morning
The morning sun emits short wave radiation, which is absorbed by the Earth’s surface. The surface conducts some of this energy deeper into the ground and also heats the air near the surface. This creates a temperature gradient wherein the surface is warmest and the air gets relatively cooler with elevation (remember the red line in the graph above).
As the air near the surface warms, that energy causes air molecules to vibrate and push away from one another. Parcels of air become less dense and rise just like the gloop in a lava lamp. The cooler air around it falls to fill in the space left behind, and air begins to circulate in a Convection Cell. The rising parcel of air will eventually cool and shrink as it rises through the relatively cooler air above it.
These convection cells create Thermal Turbulence, which is a very effective way for airborne particles, such as pesticide vapour, to be rapidly diluted. This is also how the atmosphere disperses pollution. More on the process of dispersion, later.
Mid to late afternoon
As the sun passes over and the wind starts to rise, the convection cells get disrupted by the wind and experience mechanical turbulence (remember the blue line in the graph above). So, mechanical turbulence also mixes warmer air near the ground with cooler air above it, but suppresses thermal turbulence.
Mid-afternoon to night
As the energy from the sun lessens, the soil begins to cool and so does the air next to it. Once the air cools enough to be colder than the air above it, we have the beginning of a Radiation Inversion, which is a specific kind of Thermal Inversion (see the green line in the graph below). It is called that because we now have the reverse of the typical day-time temperature profile. The height of the inversion (the ceiling) grows with time, and can reach a maximum of about 100m by sunrise. Within the inversion layer (before the green line bends back at 100m), turbulence is suppressed. We have a stable air mass. More on that below.
How inversions affect dispersion
The rising portion of a convection cell carries whatever particles are in the air with it. Suspended particles become much less concentrated at ground level thanks to the thermal turbulence.
Thermal Turbulence allows particle-laden warm air to rise and clean cool air to fall. This disperses air-borne particles like dust or pollution.
Now let’s imagine we are in a thermal inversion. The cooler, particle laden air near the ground cannot rise and the cleaner air above, which is now relatively warmer, cannot sink. Thermal turbulence is suppressed, and so is any vertical dispersion.
Thermal Turbulence is suppressed during a Temperature Inversion. Particle-laden cool air at the surface cannot rise, and warm, clean air cannot fall. No dispersion occurs, and the concentrated, particle-laden air tends to move downhill or laterally with light winds.
When spraying, the smallest spray droplets fall slowest, staying airborne for long periods of time. If spraying occurs during an inversion, those particles accumulate beneath the inversion layer. Remember we said our atmosphere behaves like a liquid? The colder, denser (pesticide-laden) air drains downhill into low-lying areas. It can also move laterally over great distances, in unpredictable directions, when light winds begin.
Clouds
If the morning were overcast instead of clear, the clouds would intercept much of the sun’s short-wave radiation, absorbing or reflecting it back into space. The Earth’s surface would still warm, but more slowly, suppressing thermal turbulence. As an aside, if clouds form in the evening, they reflect long-wave radiation from the Earth’s surface back down. This Greenhouse Effect is why overcast nights are warmer than clear ones.
Therefore, extended periods of mostly clear skies in the evening or night means a high probability of strong temperature inversions. Conversely, cloud cover usually means a near-neutral atmosphere, so no strong inversion.
Wind
Inversions are only mildly affected by light wind (e.g. 6 to 8 km/h), but as the wind increases and mechanical turbulence mixes the air, the strength of the inversion will be reduced and the atmosphere will approach a neutral condition (see the blue line). In this condition, airborne particles are not dispersed by thermal turbulence, but some mixing will occur. So, there may not be a thermal inversion, but spraying would still be inadvisable if the wind got too high.
Humidity
Inversions form more rapidly when there is less water vapour in the air to absorb radiation. Once humid air has cooled to the dew point, water condensation gives off energy and warms the air a little. This slows the formation of the inversion. Be aware that inversion conditions can exist long before fog, dew or frost forms, so they are not a good indicator for the beginning of an inversion – you’re already in one!
If you see fog, dew or frost, you’re already in an inversion. The air has become cold enough to condense or even freeze water.
Soil conditions and topography
This is a complex issue, but soil conditions that make inversions more intense include low soil moisture, freshly tilled soils, coarse soils, heavy residue and closed crop canopies. Topography matters, too. We’re discussing radiation inversions in arable regions, and the kind that form on mountains or deep valleys. Nevertheless, inversions in shaded areas (e.g., behind windbreaks) start sooner, and last longer. See the NDSU factsheet for more detail.
Spray timing
Inversions, once formed, persist until the sun rises and warms the Earth’s surface, or until winds increase and mix the stationary layers of air together, re-establishing a more neutral temperature profile.
Sunset is not a good indicator of the beginning of an inversion – it can start a few hours before. Therefore, evening spraying may be just as risky as night spraying. Very early mornings (e.g. around sunrise) are not much better. Remember, at sunrise, the inversion will be at its maximum height.
The rising sun will warm the earth and create turbulent conditions, starting near its surface (e.g. a few metres). Most inversions will have dissipated two hours after sunrise, which may be the best choice for spraying.
Detecting an inversion
The only sure way to know if you are in an inversion is to take two air temperature readings: one near the ground and one about three metres higher. If the surface air temperature is cooler, you are in an inversion. The magnitude of the difference indicates how strong the inversion is.
Accurate measurements are difficult to manage with conventional thermometers, but SpotOn now makes a hand-held detection unit. If you have one, be sure to let it acclimate before you use it. Leaving it in a hot, or cold, truck or sprayer cab prior to use means it may give a false reading.
Inversion forecasting is getting better, but it’s still location-specific and not entirely reliable. Sprayer operators should learn to watch for the following environmental cues:
- Large temperature swings between daytime and the previous night.
- Calm (e.g. less than 3 km/h wind) and clear conditions when the sun is low.
- Intense high pressure systems (usually associated with clear skies) and low humidity where you intend to spray.
- Dew or frost indicating cooler air near the ground (fog may be too late).
- Smoke or dust hanging in the air or moving laterally.
- Odours travelling large distances and seeming more intense.
- Daytime cumulus clouds collapse toward the evening.
- Overnight cloud cover is 25% or less.
Note: If you suspect a temperature inversion, don’t spray.
For more information on how weather affects drift, download this pamphlet from the Australian Government Bureau of Meteorology.
March 26, 2020